Abstract
Sands from various geographic locations reduce N2 from the air to NH3 and traces of N2H4 on exposure to sunlight. This N2 photofixation occurs under sterile conditions on the surface of finely dispersed titanium minerals such as rutile, utilizing reducing equivalents generated through the photolysis of chemisorbed H2O. Abiological N2 photofixation is suggested to be part of the nitrogen cycle in arid and semiarid regions. It is estimated that about 10 × 105 tons of N2 is photoreduced on the total surface of the earth's deserts per year.
Keywords: physicochemical N2 fixation, photogeochemistry, titanium minerals
Full text
PDF



Selected References
These references are in PubMed. This may not be the complete list of references from this article.
- Fujishima A., Honda K. Electrochemical photolysis of water at a semiconductor electrode. Nature. 1972 Jul 7;238(5358):37–38. doi: 10.1038/238037a0. [DOI] [PubMed] [Google Scholar]