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Proceedings of the National Academy of Sciences of the United States of America logoLink to Proceedings of the National Academy of Sciences of the United States of America
. 1976 Jun;73(6):1802–1805. doi: 10.1073/pnas.73.6.1802

Kinetic theory and ergodic properties

I Prigogine 1,*, A P Grecos 1, Cl George 1
PMCID: PMC430394  PMID: 16592325

Abstract

It is often assumed that the justification of kinetic theory lies in ergodic theory. From the properties of the collision operator, which plays a basic role in our kinetic description of dynamical systems, we show that this is not the case. We deduce that the asymptotic behavior of a class of states and observables is determined by the collisional invariants, independently of the ergodicity of the system. The relation between our conclusion and the stability concepts for classical Hamiltonian systems, introduced by Moser and others, is briefly indicated.

Keywords: statistical mechanics, ergodic theory, dissipative systems

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