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. 2014 Sep 26;20(45):14584–14588. doi: 10.1002/chem.201404349

Figure 2.

Figure 2

UV/Vis spectral changes (0–80 s) for the reaction of [MnV(O)(TBP8Cz)(CN)]− (11 μm) (419, 634 nm) with excess DBS (500 equiv) to give [MnIII(TBP8Cz)(CN)]− (443, 492, 694 nm) in toluene at 25 °C. Inset: changes in absorbance versus time for the growth of [MnIII(TBP8Cz)(CN)]− (694 nm) and the decay of [MnV(O)(TBP8Cz)(CN)]− (634 nm).