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Proceedings of the National Academy of Sciences of the United States of America logoLink to Proceedings of the National Academy of Sciences of the United States of America
. 1973 May;70(5):1588–1592. doi: 10.1073/pnas.70.5.1588

Application of the Singular Perturbation Method to Reaction Kinetics

W Richardson *, L Volk *, K H Lau *, S H Lin , H Eyring
PMCID: PMC433548  PMID: 16592088

Abstract

The purpose of this paper is to show how to apply the singular perturbation method to the rate equations in reaction kinetics that involve different time scales. The Lindemann scheme has been chosen for illustration, and the steady-state and equilibrium approximations used in the Lindemann scheme are discussed.

Keywords: Lindemann scheme

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