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. 2015 Jun 1;5:10699. doi: 10.1038/srep10699

High-mobility and air-stable single-layer WS2 field-effect transistors sandwiched between chemical vapor deposition-grown hexagonal BN films

M Waqas Iqbal 1, M Zahir Iqbal 1, M Farooq Khan 1, M Arslan Shehzad 2, Yongho Seo 2, Jong Hyun Park 3, Chanyong Hwang 4, Jonghwa Eom 1,a
PMCID: PMC4450543  PMID: 26030008

Abstract

An emerging electronic material as one of transition metal dichalcogenides (TMDCs), tungsten disulfide (WS2) can be exfoliated as an atomically thin layer and can compensate for the drawback of graphene originating from a gapless band structure. A direct bandgap, which is obtainable in single-layer WS2, is an attractive characteristic for developing optoelectronic devices, as well as field-effect transistors. However, its relatively low mobility and electrical characteristics susceptible to environments remain obstacles for the use of device materials. Here, we demonstrate remarkable improvement in the electrical characteristics of single-layer WS2 field-effect transistor (SL-WS2 FET) using chemical vapor deposition (CVD)-grown hexagonal BN (h-BN). SL-WS2 FET sandwiched between CVD-grown h-BN films shows unprecedented high mobility of 214 cm2/Vs at room temperature. The mobility of a SL-WS2 FET has been found to be 486 cm2/Vs at 5 K. The ON/OFF ratio of output current is ~107 at room temperature. Apart from an ideal substrate for WS2 FET, CVD-grown h-BN film also provides a protection layer against unwanted influence by gas environments. The h-BN/SL-WS2/h-BN sandwich structure offers a way to develop high-quality durable single-layer TMDCs electronic devices.

Despite all its advantages as an important material for atomically thin layered electronic device applications, graphene cannot be used as a promising material for active channel in field-effect transistors (FETs) because of the absence of a bandgap. Bandgap in graphene can be introduced by patterning into nanoribbons1, chemical functionalization2, and dual-gated bilayer graphene3, but always at the cost of significant mobility degradation. Moreover, their bandgap size is small, and the ON/OFF ratio is too small to be applicable to FETs. In contrary, several two-dimensional transition metal dichalcogenides (TMDCs) retain considerable bandgap around 1 eV to 2 eV4,5. Tungsten-based TMDCs compounds have shown a compelling thickness-dependent electronic band structure6,7 with relatively high carrier mobility8. As a tungsten based TMDCs compound, WS2 shows the transition of an indirect-to-direct bandgap when cleaved into monolayer9. Bulk WS2 is a semiconductor with an indirect bandgap of 1.4 eV, but monolayer WS2 presented a direct bandgap of 2.1 eV10. WS2 crystal is formed by layers of covalently bonded in-plane S-W-S atoms. These atoms compose two sheets of S and one sheet of W atoms that are hexagonally packed11. Adjacent layers in WS2 crystals are bound together by weak van der Waals forces. Given these weak interlayer interactions12,13, WS2 can be fabricated into single or a few layers by micromechanical cleavage method.

WS2 is currently a focus as next-generation nanoelectronic and optoelectronic materials. The material retains extremely high ON/OFF current ratio, high thermal stability, absence of dangling bonds, and electrostatic integrity14. Atomically thin layer of WS2 is becoming a new competitor to graphene, as well as traditional semiconductors, in a variety of applications, such as low power FETs, optoelectronic devices, memory devices, and chemical sensors. However, WS2 based devices suffer degradation of intrinsic properties and overall permanence because of environmental effects. In previous reports, single-layer (SL)-WS2 on Si/SiO2 substrate showed mobilities ranging between 40 and 60 cm2/Vs at room temperature15,16, because its electrical transport properties were strongly affected by interfacial charged impurities, surface roughness on Si/SiO2 substrates17,18. Suspending geometry19 may offer considerable improvements in intrinsic electrical properties of WS2. However, this kind of geometry imposes severe limitations on device fabrication. The improvement in sample quality in a substrate-supported geometry is necessary for the future progress of WS2 device technology. Efforts have been exerted to develop alternatives to the substrates. An ideal choice for alternative substrate is hexagonal BN (h-BN), which can be used to eliminate problematic surface effects in WS2 samples20, because h-BN has a large bandgap, is comparatively inert, does not possess dangling bonds, possesses low density of charged impurities, and is naturally flat21,22.

In this paper, we have developed high-mobility SL-WS2 FETs using chemical vapor deposition (CVD)-grown h-BN. Metal electrodes to SL-WS2 were constructed of Al and Au to achieve ohmic contact for improvement of device characteristics. The SL-WS2 FET sandwiched between CVD-grown h-BN films showed unprecedented mobilities of 185 cm2/Vs at room temperature and 486 cm2/Vs at 5 K. We also found that another SL-WS2 FET sandwiched between CVD-grown h-BN films showed the mobility of 214 cm2/Vs at room temperature. The ON/OFF ratio of output current is ~107 at room temperature. Whereas hysteresis was found in transfer characteristics for WS2 FETs on Si/SiO2 substrate, this occurrence was absent for WS2 FETs sandwiched between CVD-grown h-BN films. The CVD-grown h-BN film provides a stable platform for WS2 FETs and works as a protection layer against external environments.

Results and Discussion

Characterization of single-layer WS2 by optical and atomic force microscopy

Figure 1a shows the schematic of a WS2 FET device sandwiched between CVD-grown h-BN films. The CVD-grown h-BN film was transferred on Si substrate with 300 nm thick SiO2 top layer, and then a SL-WS2 film was placed on top of the h-BN film by micromechanical cleavage method. The electrical contacts to the SL-WS2 film were constructed by e-beam lithography and thermal evaporation of Al (60 nm) and Au (40 nm) films, where the Au layer was deposited to prevent the deterioration of Al film. As a final cap layer, another CVD-grown h-BN film was transferred on top of the SL-WS2 device. Figure 1b shows the optical image of mechanically exfoliated SL-WS2 on CVD-grown h-BN with Al/Au contacts. Figure 1c shows the optical image of the mechanically exfoliated SL-WS2 device sandwiched between h-BN films.

Figure 1. Optical image.

Figure 1

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(a) Schematic of a h-BN/SL-WS2/h-BN field-effect transistor. (b) Optical image of the mechanically exfoliated single-layer WS2 film on CVD-grown h-BN film. (c) Optical image of the mechanically exfoliated single-layer WS2 sandwiched between h-BN films (h-BN/SL-WS2/h-BN). The electrical contacts to WS2 films were made of Al/Au.

The thickness of CVD-grown h-BN and WS2 flakes were further verified by atomic force microscopy (AFM). The AFM image was obtained in tapping mode under ambient conditions. Figure 2a represents the surface topology and line profile of CVD-grown h-BN by AFM. In Fig. 2b, the thickness of the upper CVD-grown h-BN film is 6.8 nm, which corresponds to nine layers of h-BN. Given that the bottom h-BN film was also transferred from the same batch of CVD-grown h-BN, the number of layers should be same. Figure 2c shows the surface topology of the SL-WS2 film on h-BN obtained by AFM. The surface of WS2 film was uniform with extremely low roughness. In Fig. 2d, the thickness of the SL-WS2 film was measured as 0.77 nm on h-BN substrate.

Figure 2. Atomic force microscopy.

Figure 2

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(a) Atomic force microscopy (AFM) of CVD-grown h-BN film on SiO2 substrate. (b) Thickness profile of CVD-grown h-BN film on SiO2 substrate along the green line in AFM image. The 6.8 nm thickness indicates nine layers of CVD-grown h-BN. (c) AFM image of single-layer WS2 flake on h-BN film. (d) Height profile of the single-layer WS2 along the green line in AFM image. The 0.77 nm thickness indicates one layer of WS2.

Transport properties of SL-WS2 FETs on SiO2 substrate with Al/Au contact

The electrical characteristics of the device were investigated at room temperature under vacuum. The electrical contacts to WS2 films also perform an important function in device performance. Recent studies showed that the electrical device performance of TMDC FETs can be critically influenced by contact resistances23, and the performance was conventionally limited by Schottky barriers at the metal/semiconductor interfaces24. One key factor in improving device performance involves the realization of ohmic contacts on WS2 films25. Prior to evaporation of contact metals in this experiment, we exposed WS2 films by deep ultraviolet light (with a dominant wavelength of λ = 220 nm and an average intensity of 11 mW/cm2) under a continuous N2 gas flow for 5 min to remove any oxygen or oxygen-derived group present at the WS2 surface26,27. After device fabrication, all devices were annealed in a tube furnace at a temperature of 200 °C under Ar/H2 gas flow for 4 h to remove the residues of e-beam or photolithography resists. Output characteristic curves (Ids–Vds) at various back-gate voltages ranging from –30 V to +40 V for the SL-WS2 FET are shown in Fig. 3a. The linear Ids–Vds characteristic was obtained for the Al/Au (60/40 nm) contacts, whereas nonlinear Ids–Vds characteristic was observed for Cr/Au (10/80 nm) contacts as shown in Figure S2b of supplementary information. The Ids–Vds characteristics indicate that the Al/Au contact makes lower Schottky barrier height at the metal-to-WS2 interface in comparison with the case of Cr/Au contact. The lower Schottky barrier height is due to the work function of Al (~4.1 eV) being comparable to the electron affinity of WS2 film on SiO2. On the other hand the work function of Au (~5.1 eV) is much larger than the electron affinity of WS2 film, which yields to a relatively high Schottky barrier height.

Figure 3. Transport properties of SL-WS2 FETs on SiO2 substrate.

Figure 3

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(a) Output characteristics (Ids–Vds) of SL-WS2 FET at different back-gate voltages ranging from –30 V to +40 V in steps of 10 V. (b) Transfer characteristics (Ids–Vbg) of the SL-WS2 FET on SiO2 substrate with Al/Au contacts. ON/OFF ratio of the device is ~107 at room temperature.

Figure 3b represents the transfer characteristics (Ids–Vbg) of SL-WS2 FET on SiO2 substrate at Vds = 0.5 V. The black curve in the graph is plotted in the logarithmic scale for the Ids–Vbg curve. The output current ON/OFF ratio for the SL-WS2 FET is ~107, and the threshold voltage (Vth) was approximately –48 V, indicating n-type doping state. The threshold voltage is defined as the intercept of the Vbg axis obtained by extrapolating the linear portion of the curve of Ids–Vbg curve. The field-effect mobility (μ) of SL-WS2 FET is 80 cm2/Vs. Field-effect mobility was obtained by the equationInline graphic, where L is the channel length, W is the channel width, Inline graphicis the slope of transfer characteristic of the device at Vds = 0.5 V, and Cg is the gate capacitance of ∼105 aF/μm2 for our Si/SiO2 substrate22.

Transport properties of SL-WS2 FETs on CVD-grown h-BN films

Figure 4a represents the transfer characteristics (Ids–Vbg) of SL-WS2 FET on CVD-grown h-BN film at Vds = 0.5 V, where the top h-BN film was absent. Field-effect mobility was 163 cm2/Vs at room temperature. The output current ON/OFF ratio for SL-WS2 FET on CVD-grown h-BN film is ~107, and Vth approximated –58 V. Notably, both μ and ON/OFF ratio were improved by changing the substrate from SiO2 to h-BN film. The characteristics of SL-WS2 FET can be further improved by adding a top layer of h-BN film. Figure 4b represents the transfer characteristics (Ids–Vbg) of SL-WS2 FET sandwiched between CVD-grown h-BN films at Vds = 0.5 V. The output current ON/OFF ratio of the device is ~107, and μ was 185 cm2/Vs. Similar results were reproducibly obtained for other h-BN/SL-WS2/h-BN devices, as shown in Fig. 4c (See also Figure S3 of supplementary information). We demonstrated the mobility of 214 cm2/Vs at room temperature for the h-BN/SL-WS2/h-BN (device #2).

Figure 4. Transport properties of SL-WS2 FETs on CVD h-BN film.

Figure 4

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(a) Transfer characteristics (Ids–Vbg) of the mechanically exfoliated SL-WS2 FET on CVD-grown h-BN film at 300 K. (b) Transfer characteristics (Ids–Vbg) of the mechanically exfoliated SL-WS2 FET enclosed by h-BN at 300 K. ON/OFF ratio of the device is ~107. (c) Transfer characteristics (Ids–Vbg) of the mechanically exfoliated SL-WS2 FET enclosed by h-BN (device #2) at 300 K. (d) Transfer characteristics (Ids–Vbg) of the mechanically exfoliated SL-WS2 FET enclosed by h-BN films at different temperatures. (e) Output current as function of temperature for different values of the back-gate voltage. (f) Electron field-effect mobility of SL-WS2 FETs on different substrates at various temperatures.

Temperature-dependent electrical transport properties of SL-WS2 FETs

We have investigated the temperature-dependent electronic transport properties of SL-WS2 FETs. Figure 4d shows the transfer characteristics (Ids–Vbg) of the SL-WS2 FET sandwiched between CVD-grown h-BN films at Vds = 0.5 V at different temperatures. For Vbg < 10 V the SL-WS2 FET behaves as a traditional semiconductor with conductance decreasing as the temperature is decreased. In comparison, for Vbg ⊠ 10 V, conductance increases as temperature is decreased. Semiconductor-to-metal transition was observed when Vbg is increased to 10 V. This result suggests that a degenerately doped state is realized in SL-WS2 film for Vbg > 10 V. Figure 4e shows the temperature dependence of Ids for different values of Vbg. Here, we can clearly see the critical Vbg of 10 V, at which Ids remains almost independent of temperature. However, the Ids of SL-WS2 FET increases with decreasing temperature for Vbg > 10 V, indicating metallic behavior. For Vbg < 10 V, Ids decreases with decreasing temperature, indicating a semiconducting behavior. Observations of a similar semiconductor-to-metal transition were reported in other TMDCs materials28,29.

We have further investigated the electron filed effect mobility of SL-WS2 FET on different substrates at various temperatures. The temperature dependence of μ of SL-WS2 FETs is compared in Fig. 4f. The electron field-effect motilities of SL-WS2 FETs on SiO2, h-BN, and h-BN/SL-WS2/h-BN were 80, 163, and 185 cm2/Vs, respectively, at T = 300 K, and 180, 408, and 486 cm2/Vs, respectively, at T = 5 K. For the entire temperature range in this experiment, the h-BN/SL-WS2/h-BN device showed the highest mobility. The electron field-effect mobility of SL-WS2 on SiO2 substrate starts to saturate below 70 K, but that of SL-WS2 on h-BN films is saturated below 20 K. This result suggests that scattering factors influencing electron transport in the SL-WS2 film can be significantly reduced using h-BN films as substrate.

Among the scattering factors, charge impurities in substrate may dominantly influence the electron transport in SL-WS2 film. One of advantages for h-BN substrate includes its capability to provide charge impurity-free environment. To verify the role of our CVD-grown h-BN films, we investigated the existence of hysteresis in the transfer characteristics of SL-WS2 FETs by sweeping Vbg18. Figure S5a in supplementary information shows a hysteresis curve, which is typically observed in SL-WS2 FET on SiO2 substrate. However, transfer characteristics of SL-WS2 FET sandwiched between CVD-grown h-BN (h-BN/SL-WS2/h-BN) shows virtually no hysteresis (Figure S5b in supplementary information). The hysteresis indicates that a number of charge impurities exist in the SiO2 substrate, whereas extremely few charge impurities are present in CVD-grown h-BN.

Raman spectra of SL-WS2 FETs on different substrates

Structural characterizations of SL-WS2 films in the devices on different substrates (SiO2 and h-BN) were performed by Raman spectroscopy. Figure 5a shows a Raman shift for SL-WS2 film on SiO2 and h-BN/SL-WS2/h-BN. The Raman spectra of SL-WS2 films exhibited strong signals of in-plane E12g, out-of-plane A1g, and vibration second-order 2LA(M) modes9. The first-order E12g and A1g optical modes were considered to explain the properties of two-dimensional material, such as MoS2 in the previous report30. However, the intensity of the 2LA(M) mode at 352 cm–1 was distinctly predominant for WS2. Although the 2LA(M) mode overlapped with the first-order E12g mode at 355.4 cm–1, multi-peak Lorentzian fitting can clarify their individual contributions as seen in Fig. 5b10. The Raman peak positions of E12g and A1g for SL-WS2 are 355.4 and 417.7 cm–1, respectively. The frequency difference between Raman A1g and E12g modes (Δ = A1g – E12g) is about 62.3 cm–1, which indicates a single-layer WS2 film. The wave number difference between 2LA(M) and A1g modes can also be used to identify the layer number of a WS2 film9,10,13. The wave number differences between 2LA(M) and A1g modes are 65.3 cm–1 for SL-WS2 films in the devices. Figures 5c shows statistical distribution of the Raman intensity ratio (I2LA(M)/IA1g) for SL-WS2 on SiO2 substrate and h-BN/SL-WS2/h-BN. Statistical distribution was taken for the area of 5 × 5 μm2 in SL-WS2 on different substrates. The normalized number of observations shows the distribution of Raman shift observations in the scanned area. The most probable ratio of I2LA(M)/IA1g was 2.0 for SL-WS2 on SiO2 and 3.1 for h-BN/SL-WS2/h-BN. Figure 5c also indicates the homogeneity of SL-WS2 quality on different substrates. Larger standard deviation of intensity ratio of I2LA(M)/IA1g was found for SL-WS2 on the SiO2 substrate, whereas smaller standard deviation was found for h-BN/SL-WS2/h-BN. This finding indicates that a higher uniformity of SL-WS2 quality can be achieved by enclosing the SL-WS2 with h-BN films.

Figure 5. Raman spectra of WS2 films on different substrates.

Figure 5

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(a) Raman spectra for SL-WS2 on SiO2 and h-BN/SL-WS2/h-BN. (b) Lorentzian fitting for E2g and 2LA(M) peaks. Red circles represent experimental data, while blue, black, and green lines represent E2g, 2LA(M), and combined peak fitting, respectively. (c) Statistical distribution of the Raman intensity ratio (I2LA(M)/IA1g) for SL-WS2 on SiO2 substrate, h-BN/SL-WS2/h-BN. The mean value of I2LA(M)/IA1g was 2.0 for SL-WS2 on SiO2 and 3.1 for h-BN/SL-WS2/h-BN.

Conclusion

In summary, a SL-WS2 FET of unprecedented high quality has been achieved by CVD-grown h-BN films as substrate and capping layer. Electrical transport measurements revealed that SL-WS2 FET on h-BN film exhibited high-mobility and transfer characteristics that are free of charged impurities in comparison with SL-WS2 FET on SiO2. The field-effect mobility of h-BN/SL-WS2/h-BN was 185 cm2/Vs at 300 K and 486 cm2/Vs at 5 K. The highest mobility was found to be 214 cm2/Vs for a h-BN/SL-WS2/h-BN device at room temperature. Semiconductor-to-metal transition was also observed when Vbg was increased over 10 V. Apart from providing an ideal substrate for WS2, CVD-grown h-BN film also imparted a protection layer preventing unwanted environmental effects. The h-BN/SL-WS2/h-BN structure offered considerable advantages in fabricating stable WS2 electronic devices. This work has demonstrated the potential application of large-area growth of h-BN and the simplified fabrication of h-BN/SL-WS2/h-BN devices to enhance transport characteristics.

Experimental section

Transfer method

For the transfer of CVD-grown h-BN film, polymethyl methacrylate (PMMA) was spin-coated on CVD-grown h-BN film on Cu foil. Next, the Cu foil was etched out by soaking in an ammonium persulfate solution for 24 h. Finally, the h-BN/PMMA film was transferred onto a Si substrate. After the PMMA film was removed by soaking in acetone, CVD-grown h-BN film on the Si substrate with a 300 nm-thick SiO2 capping layer was obtained. Then, the CVD-grown h-BN film on SiO2 substrate was placed in an oxygen plasma etching system to remove the remaining PMMA residue for 2 min. Exfoliated single-layer WS2 films were obtained from natural bulk crystals of WS2 by subsequent transfer of the h-BN films on 300 nm-thick SiO2 substrate using standard Scotch tape method. Structural morphology, thickness, and topography of single-layer WS2 films were examined using optical microscopy, Raman spectroscopy, and AFM, respectively. The laser wavelength of the Raman micro-spectrometer was 514 nm, and the power was maintained at below 1.0 mW to prevent laser-induced heating. The laser spot size of Raman spectroscopy was 0.7 μm for the wavelength of 514 nm.

Device Fabrication and Characterizations

We fabricated single-layer WS2 devices by photolithography, e-beam lithography, and O2 plasma etching. Large electrode patterns with Cr/Au (6/30 nm) film were deposited using a thermal evaporator after standard photolithography. E-beam lithography was then employed to pattern source and drain contacts, from which the film was made by evaporation of Al/Au (60/40 nm). Prior to the evaporation of contact metals, we exposed the WS2 films by deep ultraviolet light with a dominant wavelength of λ = 220 nm and an average intensity of 11 mW/cm2 in a continuous N2 gas flow for 5 min. This process aimed to remove any oxygen or oxygen-derived group present at the WS2 surface. After device fabrication, all devices were annealed in a tube furnace at a temperature of 200 °C under Ar/H2 (97.5% Ar/2.5% H2) gas flow for 4 h. Electrical transport measurements were carried out at room temperature under vacuum.

Synthesis of h-BN

The growth of h-BN film was performed on 25-μm-thick Cu foil (Alfa Aesar, 99.8% pure) using thermal CVD. To remove the impurities and obtain the flatness of the Cu foil, we applied a mechanical polishing process followed by a short electro-polishing. The Cu foil was annealed at 990 °C for 30 min with H2 gas at a flow rate of 5 standard cubic centimeters per minute (sccm) to remove the oxide layer. Ammonia borane (Sigma-Aldrich, 97% pure) was thermally decomposed to hydrogen, aminoborane, and borazine at a temperature range from 80 to 120 °C. After the thermal cleaning, h-BN was synthesized with borazine gas and hydrogen at 997 °C for 30 min. The furnace was cooled from 997 to 500 °C at a rate of ~35 °C/min after the synthesis of h-BN films.

Additional Information

How to cite this article: Iqbal, M. W. et al. High-mobility and air-stable single-layer WS2 field-effect transistors sandwiched between chemical vapor deposition-grown hexagonal BN films. Sci. Rep. 5, 10699; doi: 10.1038/srep10699 (2015).

Supplementary Material

Supplementary Information
srep10699-s1.doc (2.9MB, doc)

Acknowledgments

This research was supported by Nano-Material Technology Development Program (2012M3A7B4049888) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning. This research was also supported by Priority Research Center Program (2010-0020207) and the Basic Science Research Program (2013R1A1A2061396) through NRF funded by the Ministry of Education.

Footnotes

Author Contributions M.W.I. and J.E. wrote the manuscript. M.W.I. worked on device characteristics, data collection, analysis, and interpretation of results. M.W.I. performed device fabrication, and M.Z.I. and M.F.K helped during device fabrication process. J.H.P and C.H. performed the synthesis of h-BN films. M.A.S and Y.S helped in obtaining AFM images. J.E. planned the project. All authors discussed the progress of research and reviewed the manuscript.

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Supplementary Materials

Supplementary Information
srep10699-s1.doc (2.9MB, doc)

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