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. 1993 Jun 1;90(11):5204–5208. doi: 10.1073/pnas.90.11.5204

Azamacrolides: a family of alkaloids from the pupal defensive secretion of a ladybird beetle (Epilachna varivestis).

A B Attygalle 1, K D McCormick 1, C L Blankespoor 1, T Eisner 1, J Meinwald 1
PMCID: PMC46684  PMID: 8506367

Abstract

Defensive droplets from glandular hairs of the pupa of the Mexican bean beetle, Epilachna varivestis, contain a group of structurally novel alkaloids, the azamacrolides. The major constituent of this secretion, epilachnene, is shown to be (5Z)-11-propyl-12-azacyclotetradec-5-en-14-olide. The secretion also contains an epilachnadiene and trace amounts of three closely related components.

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Selected References

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