Skip to main content
PMC home page
Scientific Reports logoLink to Scientific Reports
. 2015 Dec 18;5:18273. doi: 10.1038/srep18273

High-temperature superconductivity from fine-tuning of Fermi-surface singularities in iron oxypnictides

A Charnukha 1,2,a, D V Evtushinsky 1, C E Matt 3,4, N Xu 3,5, M Shi 3, B Büchner 1, N D Zhigadlo 4, B Batlogg 4, S V Borisenko 1
PMCID: PMC4683369  PMID: 26678565

Abstract

In the family of the iron-based superconductors, the REFeAsO-type compounds (with RE being a rare-earth metal) exhibit the highest bulk superconducting transition temperatures (Tc) up to 55 K and thus hold the key to the elusive pairing mechanism. Recently, it has been demonstrated that the intrinsic electronic structure of SmFe0.92Co0.08AsO (Tc = 18 K) is highly nontrivial and consists of multiple band-edge singularities in close proximity to the Fermi level. However, it remains unclear whether these singularities are generic to the REFeAsO-type materials and if so, whether their exact topology is responsible for the aforementioned record Tc. In this work, we use angle-resolved photoemission spectroscopy (ARPES) to investigate the inherent electronic structure of the NdFeAsO0.6F0.4 compound with a twice higher Tc = 38 K. We find a similarly singular Fermi surface and further demonstrate that the dramatic enhancement of superconductivity in this compound correlates closely with the fine-tuning of one of the band-edge singularities to within a fraction of the superconducting energy gap Δ below the Fermi level. Our results provide compelling evidence that the band-structure singularities near the Fermi level in the iron-based superconductors must be explicitly accounted for in any attempt to understand the mechanism of superconducting pairing in these materials.

After seven years of intensive research, the mechanism of superconductivity in the iron-based superconductors remains unknown. The observation of the Fermi-surface topology drastically different from the early predictions of the ab initio calculations in some compounds1,2,3,4 has cast doubt on the theoretical description of superconductivity based on this simplified picture and necessitates the adoption of the true Fermi surface, a paradigm shift that is now beginning to occur5,6. In this view, the identification of essential electronic features bearing directly on the superconducting pairing mechanism is of vital importance. Recent observation of a highly nontrivial electronic structure in SmFe0.92Co0.08AsO shaped by multiple band-edge singularities in the vicinity of the Fermi level (EF) implies, should it prove to be generic for the 1111-type compounds, that very small changes on the order of tens of meV can potentially lead to drastic changes in the Fermi-surface topology and strongly affect the superconducting state. We employ ARPES to show that the bulk electronic structure of NdFeAsO0.6F0.4 is, at first sight, virtually identical to that of sister SmFe0.92Co0.08AsO with a twice lower Tc, with one essential difference: the top of the hole band located at ≈6 meV above the Fermi level in SmFe0.92Co0.08AsO (ref. 4) sinks to 2.3 meV below the Fermi level, entirely eliminating the Fermi surface at the center of the Brillouin zone. And yet this band remains within the reach of superconducting pairing interaction and, intriguingly, hosts a superconducting energy gap of 10.5 meV — almost 10 times larger than that in SmFe0.92Co0.08AsO (ref. 4). This observation suggests that the “fine-tuning” of the aforementioned hole band dramatically enhances superconductivity in NdFeAsO0.6F0.4.

A typical photoemission intensity distribution at the Fermi level in NdFeAsO0.6F0.4 is shown in Fig. 1a,b. It is dominated by two large circular sheets of the Fermi surface at the Γ point of the Brillouin zone and a complex propellerlike structure surrounded by another circular sheet at the M point. It has been shown in several works7,8,9,10,11,12,13,14,15,16, particularly in ref. 4, that all large circular features (two at the Γ and one at the M point) are extrinsic and can be traced back to the polar cleaved surface of the crystal. Below we provide additional compelling evidence that this is indeed the case.

Figure 1.

Figure 1

Open in a new tab

(a,b) Constant-energy maps obtained by integrating the photoemission intensity within 15 meV around EF, recorded at T = 1 K using 60 eV photons with linear horizontal (a) and circular (b) polarization. White dotted square shows the 2-Fe Brillouin zone. (c) Energy-momentum cut (EMC) along the line shown in (a). White arrows in panels (c,g–i) indicate the surface-related bands giving rise to the large circular features around Γ and M in (a,b). (d) Schematic illustration of the effect of high-energy electronic correlations on the ab initio band structure, as reported in ref. 4. (e–i) EMCs along the lines shown in (a,b). (e) The intensity distribution near Γ shows the bulk electronic structure more clearly: a hole band terminating near EF together with another broad holelike dispersive feature at 56 meV below EF (see panels (h,i)). The expected connection between the bulk-related features at Γ and M (d) is clearly seen and indicated with a dashed line and black arrows. (f,g) EMCs near the M point. Dashed lines in (f) show the prediction of ab initio calculations renormalized by a factor of 1.8 and shifted towards EF, see panel (d) and ref. 4. White line and arrows in (g) indicate an additional electron band distinct from the complex structure in (f) and producing the circular feature around M in (a,b). (h,i) EMCs near Γ at 1 K and 50 K, respectively. In (h) a hole band just below EF (upper dashed line) and two more bands terminating at 56 meV binding energy (lower dashed lines; see supplementary information for conclusive evidence for the two-band character of this feature) are indicated. Panel (i) shows the normal-state dispersion of the upper bulk hole band extracted from the fit of momentum-distribution curves (white circles) and a parabolic fit to this dispersion (black solid line). The latter provides the location of the band edge at 2.3 meV below EF. All dashed and solid lines are schematic unless stated otherwise.

With the large circular features eliminated the electronic landscape that remains is clearly nontrivial. To examine it in detail, we show several energy-momentum cuts (EMCs) obtained along the dashed lines in Fig. 1a,b. Figure 1c reveals the photoemission intensity distribution along the high-symmetry M–Γ–M direction. The surface-related bands that generate the large circular features in Fig. 1a,b are shown with white arrows here and in subsequent panels of this figure. At the Γ point, another hole band at higher binding energies is evident and is part of the bulk electronic structure, as will be substantiated in what follows. At the M point, a very heavy hole band is clearly visible. This band gives rise to the blades of the propellerlike structure in Fig. 1a,b, as has been shown in some of the earlier studies4,13. Below, a weak electron band is visible with additional bands underneath it. In ref. 4 it has been argued that this entire intensity distribution is present already in the ab initio LDA calculations at much higher binding energies than found in experiment and is pulled to the Fermi level by electronic interactions, as is shown schematically in Fig. 1d.

It is well-known that the photoemission matrix elements depend strongly on the polarization of incident light. Therefore, we show an energy-momentum cut along the same high-symmetry direction but obtained with the circular polarization in Fig. 1e. Indeed, this figure reveals additional key features: the electron bands at the M point are much more prominent and an additional intensity spot just below the Fermi level is visible, which comes from a higher-lying electron band, consistent with the band structure in Fig. 1d. The photoemission intensity at the Γ point now reveals a hole band just below the Fermi level as well as the additional intensity distribution with holelike dispersion at higher binding energies, already pointed out in Fig. 1c. We show that the latter intensity distribution comprises two different bands degenerate at the Γ point (see supplementary information), consistent with the theoretically predicted bulk electronic structure renormalized by a factor of about 1.8 as illustrated schematically in Fig. 1d. One can clearly see that the upper band is connected to the heavy hole band at the M point (as shown with black arrows and a dashed curve, displaced upwards not to conceal the weak photoemission signal). This observation is essential as it proves that the three hole bands at the Γ point and the propeller structure at the M point are part of the same electronic structure and are entirely distinct from the surface related bands mentioned above. Figure 1f further shows that the band structure at the M point agrees remarkably well with the prediction of ab initio calculations provided that the latter is renormalized by the same factor of 1.8 as the band structure around the Γ point. It also indicates that albeit the hole bands giving rise to the blades of the propellerlike structure in the intensity maps in Fig. 1a,b (integrated in a window of ±15 meV around the Fermi level) terminate in the immediate vicinity of the Fermi level, they do not cross it and, therefore, do not contribute to the Fermi surface of NdFeAsO0.6F0.4.

By taking an energy-momentum cut at 45° with respect to the orientation of the blades, as shown in Fig. 1g, we reveal the electron band that gives rise to the large circular feature at the M point in Fig. 1a,b. It can be seen that this electron band is much heavier than that shown in Fig. 1f. In ref. 4 it has been shown that the electronic structure producing the propellerlike construct at the M point does not have any intensity in this direction and thus this heavy electron band is not a part of it and must be extrinsic. Therefore, the only bulk band in NdFeAsO0.6F0.4 that does clearly cross the Fermi level and generates a well-defined Fermi surface is the shallow electron band at the M point of the Brillouin zone, consistent with the predominantly electron, as opposed to hole, transport observed in this material17. We thus arrive at the inherent electronic structure of NdFeAsO0.6F0.4 fully consistent with that shown in Fig. 1d and surprisingly similar to that of SmFe0.92Co0.08AsO (ref. 4).

To determine the fine differences between these two compounds with very different superconducting transition temperatures we investigate the electronic structure more closely. Figure 1h shows an energy-momentum cut at an angle to the Γ–M direction, as indicated in Fig. 1a. All the relevant features discussed above are now more immediately evident. The white arrows indicate the extrinsic surface states. The dashed lines, on the other hand, show the bulk hole bands identified above. One can clearly see the upper hole band in the immediate vicinity of the Fermi level crossing the inner surface-related band as well as the intensity distribution due to the lower two bands terminating at ~50 meV below the Fermi level. The band edges of these three bands do not show any observable dispersion in the out-of-plane direction of the Brillouin zone (see supplementary information), confirming the highly two-dimensional character of the electronic structure of the 1111-type compounds predicted theoretically18,19. To determine the precise location of the band edge closest to the Fermi level (and thus directly affecting the itinerant properties) we extract the dispersion of the corresponding band in the normal state (at 50 K) in Fig. 1i from a fit of the momentum-distribution curves. A parabolic fit to the determined dispersion shows that this band terminates at only 2.3 meV below the Fermi level and thus does not generate a Fermi surface.

Given that the overall bulk electronic structure of NdFeAsO0.6F0.4 is so strikingly similar to that of SmFe0.92Co0.08AsO, and yet their superconducting transition temperatures differ by a factor of 2, it is crucial to compare the effect of the fine differences on the superconducting pairing. To that end, we have studied the temperature dependence of the electronic structure around the Γ and M points of the Brillouin zone. Three representative energy-momentum cuts in the directions shown with dashed lines in Fig. 2a are displayed in Fig. 2b–d. In order to determine the superconducting energy gap accurately by accounting for the finite experimental resolution we use the expression derived in ref. 3. The value of the superconducting energy gap is extracted by fitting the momentum-integrated EDCs in the momentum windows indicated in Fig. 2b–d as white dashed rectangles with the Dynes function multiplied by the Fermi function and convolved with the resolution function:

Figure 2.

Figure 2

Open in a new tab

(a) Crop of Fig. 1a. (b–d) EMCs along the dashed lines in panel (a). All data were recorded at 1 K using a linear polarization and 30 eV (b,d) or 60 eV (c) photon energy. Normal-state (at 50 K) counterpart of the EMC in (d), obtained under the same conditions, is shown in Fig. 1i. (e–h) Normalized EDCs integrated in the momentum windows shown as dashed rectangles in panels (b–d). All fits were obtained using the Dynes–like model for integrated EDCs, as described in the text. (i,j) Temperature dependence of the normalized EDCs in (e,g). The dashed lines in (j) indicate (left to right) the location of the quasiparticle coherence peak E0, leading edge of the superconducting component at 1 K, and EF. (k) Ratio (blue open circles) of the normalized EDCs obtained in the superconducting (1 K) and normal (50 K) state in (g), and its first derivative (black solid line; shifted up by 0.7 and multiplied by 5 for clarity). Vertical dashed lines (left to right) mark the location of E0 and EF. The former is further clearly visible as the zero of the first derivative (intersection of the left vertical and lower horizontal dashed lines). The normal component shown in panel (g) produces an inflection point in the derivative and has its leading edge (minimum of the derivative) located at EF. It could originate in a finite contribution to the photoemission signal from outside the sample surface, given the small size of the single crystals (see Methods). (l,m) Temperature dependence of Inline graphic and ΔIpeak defined in panel (k) (blue circles) and of the M-point superconducting gap Δ (extracted from the data in (b,e,i)) (red circles). Black solid line is the temperature dependence expected in the Bardeen-Cooper-Schrieffer theory of superconductivity for Δ = 5 meV and Tc = 38 K. An accurate description of the temperature dependence of these superconducting features would require consistently taking into account the existence of multiple coupled bands and the proximity of their edges to the Fermi level.

graphic file with name srep18273-m1.jpg

where Inline graphic, ω is the binding energy with reversed sign, T is the temperature, Σ″ is the imaginary part of the self-energy, Δ is the superconducting energy gap, and δE is the experimental resolution. The momentum resolution drops out from this expression due to momentum integration. The results of the fit are shown in Fig. 2e–h for the middle and one of the blades of the propellerlike structure at the M point, hole band terminating in the vicinity of the Fermi level at the Γ point, as well as the outer surface-related band at the Γ point, respectively. The superconducting energy gap at the center of the propellerlike structure amounts to 5 meV and thus has a gap ratio 2Δ/kBTc of about 3.2, comparable to that on the corresponding feature of SmFe0.92Co0.08AsO (≈3.3) (ref. 4) and close to the BCS value 3.52. The detailed temperature dependence of this superconducting gap, extracted by fitting the data in Fig. 2i, is shown with red open circles in Fig. 2m and appears to deviate from the behavior expected from the conventional Bardeen-Cooper-Schrieffer theory of superconductivity (black solid line).

Unlike the energy-distribution curves recorded in the middle of the propellerlike structure, those obtained on one of the blades (Fig. 2c,f) exhibit pronounced finite-band effects, manifested in the strong deviation of the normal-state data in Fig. 2f from the Fermi-Dirac distribution. In such a case Eq. 1 cannot be used and the full modeling of a finite band must be employed3. The corresponding finite-band fits of the experimental data (open circles) in the normal and superconducting state (solid lines) are shown in Fig. 2f and suggest the absence of the superconducting gap on this feature of the electronic structure, which, as has been argued above, does not produce any Fermi surface.

Quite surprisingly, the hole band terminating at 2.3 meV below the Fermi level and thus likewise not producing any Fermi surface, is found to host a superconducting energy gap of 10.5 meV, with a gap ratio of 6.65, significantly larger than the corresponding ratio in SmFe0.92Co0.08AsO (≈2.1). Interestingly, this value is very close to the largest gap ratio of ~6.8 observed in the optimally doped Ba1−xKxFe2As2 compound with the same Tc ≈ 38 K as NdFeAsO0.6F0.4 3,20. Even though the extraction of the superconducting gap on this feature is somewhat complicated by the presence of a sizable non-superconducting (normal) component, as shown by the shaded area in Fig. 2g and further substantiated in Fig. 2k, the presence of a large superconducting gap is directly evident in the raw data presented in Fig. 2d,g,j: the superconductivity-induced coherence peak is located at 13 meV below the Fermi level and the leading edge of the superconducting component — at about 7 meV below the Fermi level (it is well-known that the leading-edge shift tends to underestimate the value of the superconducting gap). Both features vanish at the superconducting transition temperature, as can be seen in Fig. 2j. The temperature dependence of the binding energy E0 and amplitude of the coherence peak ΔIpeak, extracted from the experimental data and their derivative as indicated in Fig. 2k, are presented in Fig. 2l,m. It is clear that while ΔIpeak (blue open circles in Fig. 2m) closely mimics the temperature dependence of the superconducting gap found in the middle of the propellerlike structure at the M point of the Brillouin zone (red open circles in Fig. 2), the binding energy of the coherence peak shows negligible temperature dependence, suggesting filling-in, rather than closing, of the superconducting energy gap at the Γ point.

Finally, and in stark contrast to previous studies, the outer surface-related band in our samples shows no sign of the superconducting energy gap, as shown in Fig. 2h, providing further compelling evidence for the extrinsic character of this feature. The absence or strong suppression of the proximity effect between the bulk and the surface layer of NdFeAsO0.6F0.4 is remarkable, albeit not unprecedented21, and requires further investigation.

The proximity of band-edge singularities to the Fermi level simultaneously at the Γ and M points of the Brillouin zone, connected by the ubiquitous in the iron-based superconductors (π, π) Q-vector, indicates that nesting may play an important role in the low-energy electrodynamics of this material. At the same time, the sizable value of the superconducting energy gap on the features of the electronic structure both at the Γ and M points implies that the condition Inline graphic, where Δ is the superconducting energy gap and EF is the Fermi energy, required for the Migdal approximation of the conventional theories of superconductivity is violated. This suggests that a more general theory is necessary for an adequate description of the superconducting properties of this and likely other compounds of the iron-based family22,23.

Our observation of the dramatic enhancement of the superconducting energy gap in NdFeAsO0.6F0.4 given the band structure almost identical to that of SmFe0.92Co0.08AsO is striking. It leaves one with only two alternatives: either the superconducting pairing does not depend on the exact shape of the Fermi surface at all, or it must be extremely sensitive to very fine changes in the low-energy electronic structure of the iron oxypnictides. The former case is indeed possible and realized in conventional superconductors, in which the exact shape of the Fermi surface is largely irrelevant, given the same density of states at the Fermi level24, and the superconducting pairing driven by a mediator not belonging to the electronic system in which superconductivity occurs, i.e. phonons. However, it has been shown early on that the sheer strength of the electron-phonon coupling is insufficient to explain the elevated superconducting transition temperatures in the iron oxypnictides25,26. The density of states of two-dimensional parabolic bands (which is the case in NdFeAsO0.6F0.4, as demonstrated in this work) is expected to be constant up to their respective band edges and thus would be very similar near the Fermi level in NdFeAsO0.6F0.4 and SmFe0.92Co0.08AsO. Therefore, one appears to be left with the latter option. If the pairing interaction originates in the same electronic subsystem that achieves the superconducting ground state then the simultaneous self-consistent account of the essential features of superconductivity and the experimentally observed highly singular electronic structure is indispensable.

Additional Information

How to cite this article: Charnukha, A. et al. High-temperature superconductivity from fine-tuning of Fermi-surface singularities in iron oxypnictides. Sci. Rep. 5, 18273; doi: 10.1038/srep18273 (2015).

Supplementary Material

Supplementary Information
srep18273-s1.pdf (4.6MB, pdf)

Acknowledgments

This project was supported by the German Science Foundation under Grants No. BO 1912/2-2 within SPP 1458. Work at PSI is supported by the Swiss National Science Foundation (No. 200021-137783) and the Sino-Swiss Science and Technology Cooperation (Project No. IZLCZ2138954). Work at ETH was partially supported by the SNSF and the NCCR program MaNEP. A.C. acknowledges financial support by the Alexander von Humboldt foundation.

Footnotes

Author Contributions A.C., D.V.E., C.E.M., N.X. and S.V.B. carried out the experiments. A.C., D.V.E. and S.V.B. analyzed the data. A.C. wrote the manuscript. N.D.Z. carried out the sample growth and characterization. S.V.B., M.S., B.Bg. and B.B. supervised the project. All authors discussed the results and reviewed the manuscript.

References

  1. Mazin I. I. & Schmalian J. Pairing symmetry and pairing state in ferropnictides: Theoretical overview. Phys. C 469, 614–627 (2009). [Google Scholar]
  2. Zabolotnyy V. B. et al. (π, π) electronic order in iron arsenide superconductors. Nature 457, 569–572 (2009). [DOI] [PubMed] [Google Scholar]
  3. Evtushinsky D. V. et al. Momentum dependence of the superconducting gap in Ba1−xKxFe2As2. Phys. Rev. B 79, 054517 (2009). [Google Scholar]
  4. Charnukha A. et al. Interaction-induced singular Fermi surface in a high-temperature oxypnictide superconductor. Sci. Rep. 5, 10392 (2015). [DOI] [PMC free article] [PubMed] [Google Scholar]
  5. Wang Y. et al. Superconducting gap in LiFeAs from three-dimensional spin-fluctuation pairing calculations. Phys. Rev. B 88, 174516 (2013). [Google Scholar]
  6. Saito T. et al. Reproduction of Experimental Gap Structure in LiFeAs based on the Orbital-Spin Fluctuation Theory: s++-wave, s±-wave, and Inline graphic-wave states. Phys. Rev. B 90, 035104 (2014). [Google Scholar]
  7. Kondo T. et al. Momentum Dependence of the Superconducting Gap in NdFeAsO0.9F0.1 Single Crystals Measured by Angle Resolved Photoemission Spectroscopy. Phys. Rev. Lett. 101, 147003 (2008). [DOI] [PubMed] [Google Scholar]
  8. Liu C. et al. Electronic properties of iron arsenic high temperature superconductors revealed by angle resolved photoemission spectroscopy (ARPES). Phys. C: Supercond. 469, 491–497 (2009). [Google Scholar]
  9. Lu D. H. et al. Electronic structure of the iron-based superconductor LaOFeP. Nature 455, 81–84 (2008). [DOI] [PubMed] [Google Scholar]
  10. Liu H.-Y. et al. Pseudogap and Superconducting Gap in SmFeAs(O1−xFx) Superconductor from Photoemission Spectroscopy. Chin. Phys. Lett. 25, 3761 (2008). [Google Scholar]
  11. Lu D. et al. ARPES studies of the electronic structure of LaOFe(P, As). Phys. C: Supercond. 469, 452–458 (2009). [Google Scholar]
  12. Liu H. et al. Unusual Electronic Structure and Observation of Dispersion Kink in CeFeAsO Parent Compound of FeAs-based Superconductors. Phys. Rev. Lett. 105, 027001 (2010). [DOI] [PubMed] [Google Scholar]
  13. Liu C. et al. Surface-driven electronic structure in LaFeAsO studied by angle-resolved photoemission spectroscopy. Phys. Rev. B 82, 075135 (2010). [Google Scholar]
  14. Yang L. X. et al. Surface and bulk electronic structures of LaFeAsO studied by angle-resolved photoemission spectroscopy. Phys. Rev. B 82, 104519 (2010). [Google Scholar]
  15. Yang L. et al. Electronic structure of SmOFeAs. J. Phys. Chem. Solids 72, 460–464 (2011). [Google Scholar]
  16. Nishi I. et al. Angle-resolved photoemission spectroscopy study of PrFeAsO0.7: Comparison with LaFePO. Phys. Rev. B 84, 014504 (2011). [Google Scholar]
  17. Sato M. et al. Studies on Effects of Impurity Doping and NMR Measurements of La 1111 and/or Nd 1111 Fe-Pnictide Superconductors. J. Phys. Soc. Jpn. 79, 014710 (2010). [Google Scholar]
  18. Singh D. J. & Du M.-H. Density Functional Study of LaFeAsO1−xFx: A Low Carrier Density Superconductor Near Itinerant Magnetism. Phys. Rev. Lett. 100, 237003 (2008). [DOI] [PubMed] [Google Scholar]
  19. Eschrig H., Lankau A. & Koepernik K. Calculated cleavage behavior and surface states of LaOFeAs. Phys. Rev. B 81, 155447 (2010). [Google Scholar]
  20. Ding H. et al. Observation of Fermi-surface–dependent nodeless superconducting gaps in Ba0.6K0.4Fe2As2. Europhys. Lett. 83, 47001 (2008). [Google Scholar]
  21. Yilmaz T. et al. Absence of a Proximity Effect for a Thin-Films of a Bi2Se3 Topological Insulator Grown on Top of a Bi2Sr2CaCu2O8+δ Cuprate Superconductor. Phys. Rev. Lett. 113, 067003 (2014). [DOI] [PubMed] [Google Scholar]
  22. Perali A., Bianconi A., Lanzara A. & Saini N. The gap amplification at a shape resonance in a superlattice of quantum stripes: A mechanism for high Tc. Solid State Commun. 100, 181–186 (1996). [Google Scholar]
  23. Bianconi A. Quantum materials: Shape resonances in superstripes. Nature Phys. 9, 536–537 (2013). [Google Scholar]
  24. Tinkham M. Introduction To Superconductivity (McGraw-Hill, 1995). [Google Scholar]
  25. Boeri L., Dolgov O. V. & Golubov A. A. Is LaFeAsO1−xFx an electron-phonon superconductor? Phys. Rev. Lett. 101, 026403 (2008). [DOI] [PubMed] [Google Scholar]
  26. Boeri L. et al. Effects of magnetism and doping on the electron-phonon coupling in BaFe2As2. Phys. Rev. B 82, 020506 (2010). [Google Scholar]

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Supplementary Materials

Supplementary Information
srep18273-s1.pdf (4.6MB, pdf)

Articles from Scientific Reports are provided here courtesy of Nature Publishing Group

RESOURCES