Table 4.

Substrates for the stereoselective iodine(III)-mediated thioamination.

Entry	Substrate	Product	Yield [%]	ee [%]
1	1 a (R=H)	2 a (R=H)	68	79
2	3 (R=Cl)	4 (R=Cl)	50	74
3	5 (R=OMe)	6 (R=OMe)	53	70
4	7	8	47	60
5	9	10	57	61
6	11	12	42	55
7[a]	11	14	40	25

[a] Use of 1-methyl-1H-imidazole-2-thiol instead of sodium thiophenolate.