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Reactivity of rollover cycloplatinated Pt(CH3)(dmso)(bipy - H) complex 2b. i) Pt(dmso)2(CH3)2, acetone, 50°C, 5 hrs, 89%. ii) HCl (0.1N), acetone, dmso, 8 hrs, 70%; iii) PPh3, CH2Cl2, 2 hrs, 98%. X-ray crystallographic structures of proligand 1b and of cycloplatinated complex 3b.
