Table 5.
Complex | Redox Process | Potential (V) | Peak Separation (mV) | Ref |
---|---|---|---|---|
Ni(Me2Bcyclen)Cl2 | Ni2+ → Ni+ | Ered = −2.036 | --- | [42] |
Ni2+ / Ni3+ | E1/2 = +0.863 | 68 | ||
???? | Eox = +1.450 | --- | ||
Ni(3)2+ | Ni2+ → Ni+ | Ered = −1.287 | --- | |
Ni2+ → Ni3+ | Eox = +1.375 | --- | ||
Ni(4)Cl+ | Ni2+ / Ni3+ | E1/2 = +1.034 | 76 | |
???? | E1/2 = +1.313 | 87 | ||
Ni(PyMeEBC)Cl+ | Ni2+ → Ni+ | Ered = −1.026 | --- | [12] |
Ni2+ → Ni3+ | Eox = +1.290 | --- | ||
Co(Me2BCyclen)Cl2 | Co2+ → Co+ | Ered = −2.202 | --- | [47] |
Co2+ / Co3+ | E1/2 = −0.157 | 288 | ||
???? | Eox = +0.983 | --- | ||
Co(3)Cl+ | Co2+ → Co+ | Ered = −1.884 | --- | |
Co2+ → Co3+ | Eox = +1.121 | --- | ||
???? | Eox = +1.411 | --- | ||
Co(4)Cl2+ | Co3+ → Co2+ | E1/2 = −0.127 | 107 | |
Co(PyMeEBC)Cl+ | Co2+ / Co+ | E1/2 = −1.386 | 143 | [12] |
Co2+ / Co3+ | E1/2 = +0.657 | 154 | ||
Cu(Me2BCyclen)2+ | Cu2+ → Cu+ | Ered = −0.651 | --- | [31] |
Cu(3)2+ | Cu2+ → Cu+ | Ered = −0.406 | --- | |
Cu2+ → Cu3+ | Eox ~ +1.75 | --- | ||
Cu(4)2+ | Cu2+ / Cu+ | E1/2 = −0.341 | 86 | |
Cu2+ → Cu3+ | Eox ~ +1.86 | --- | ||
Cu(SB-PyCyclam)2+ | Cu2+ / Cu+ | E1/2 = −0.586 | 77 | [10] |
Cu(PyMeEBC)2+ | Cu2+ / Cu+ | E1/2 = −0.402 | 80 | [12] |