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. 2016 Apr 23;22(23):7970–7977. doi: 10.1002/chem.201600116

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© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.

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Scheme 4 — Lewis acid‐catalyzed rearrangement of cyclohexasilanes 12 to give silylcyclopentasilanes 13 (a: R¹=R²=R³=Me; b: R¹=R²=SiMe₃, R³=Me; c: R¹=R²=R³=SiMe₃). Reaction conditions for 12 a: Lewis acid: Ph₃C⁺, solvent: CD₂Cl₂ or C₆D₆; for 12 b: Lewis acid: AlCl₃, solvent: cyclohexane; for 12 c: Lewis acid: AlCl₃, solvent: cyclohexane).14