CH in the Solar Spectrum

Charlotte E Moore; Herbert P Broida

doi:10.6028/jres.063A.002

. 1959 Aug 1;63A(1):19–53. doi: 10.6028/jres.063A.002

CH in the Solar Spectrum

Charlotte E Moore, Herbert P Broida

PMCID: PMC5287100 PMID: 31216139

Abstract

CH lines in the solar spectrum have been identified by direct comparison of measured laboratory and solar wavelengths and intensities. The comparisons of individual rotational lines are included in a series of tables arranged according to electronic and vibrational transitions.

A detailed investigation of the presence of CH lines in the solar spectrum has been carried out recently as part of the preparation of a current edition of solar spectrum data to replace the 1928 compendium [1].1 Along with the study of atomic lines, a parallel survey of molecules in the sun is required for any complete revision of the “Solar Spectrum.” A preliminary résumé of the number of CH, OH, and CN lines in the solar spectrum was recently published [2].

Many lines of CH are familiar features in the solar spectrum. In his original table, Rowland [3] attributed some of these lines to “C,” and numerous CH lines were included in the 1928 edition [1]. Several authors have carried the work further. For example, Hunaerts [4] and Richardson [5] have each published a list of solar lines which may be ascribed to CH.

The present results are based on a study of the rotational structure of individual bands, together with relative laboratory intensities measured along the different branches. It reveals more CH lines in the sun than have been recognized heretofore. A summary of the counts is included in table 1. In this table the counts are handled differently than they were previously, in that the counts refer to individual laboratory lines; whereas in the earlier paper [2] they referred to solar lines. Consequently, if two CH lines contribute to one solar line, each CH line is counted here as a blend. Exception has been made in the case of table 10, where the laboratory lines are so closely blended that for some groups they are not counted as separate lines. The total number of laboratory lines given for this band is 119 ± to denote that the count is somewhat arbitrary. If only the leading lines of a band are present in the sun, the counts refer only to the stronger lines of the band, as for example in table 5, where only 31 lines out of 198 enter into the count.

Table 1.

Summary

Table No.	Laboratory					Sun
	Electronic transition	Vibrational transition	Wavelength range A	Total number lines	References	Strongest solar int. Δλ/λ	Summary of counts
	Electronic transition	Vibrational transition	Wavelength range A	Total number lines	References	Strongest solar int. Δλ/λ	Present	Blend	Masked	Absent	Total

2	A ²Δ–X ²Π	0, 0	4133 to 4413	309	6	39.6	155	92	46	16	309
3		1, 1	4185 to 4446	235	6	24.3	70	68	72	15	225
4		2, 2	4238 to 4468	188	6	26.6	54	36	61	8	159
5		0, 1	4726 to 4941	198	7	0.6	5	3	14	9	31
6		1, 2	4741 to 4913	149	7		0				0

			Total	1,079			284	199	193	48	724
7	B ²Σ⁻— X ²Π	0, 0	3871 to 4084	106	6	49.4	43	41	20	2	106
8		1, 0	3627 to 3710	54	6	13	18	10	22	4	54
9		1, 1	4025 to 4119	50	6	7.6	16	11	22	1	50

			Total	210		Rowl. est.	77	62	64	7	210
10	C ²Σ⁺—X ²Π	0, 0	3086 to 3219	119±	8	[2]	31	41	18	6	96
11		1, 1	3119 to 3222	50	8	[0]	8	13	24	5	50

			Total	169±			39	54	42	11	146

Laboratory									Sun

P₁	P₂	Q₁	Q₂	R₁	R₂	Intensity	Wave number cm⁻¹	Wavelength A	Wavelength A	Disk int. Rowl. est.	⊙—lab. A	Solar identification	Notes
				26		0.2	32388.47	3086.622	3086.636	[−1]	+0.014		M
					26	0.2	32387.24	3086.739	3086.787	[ 4]	+0.048	Co i	A
				25		0.25	32384.23	3087.027	3086.988	[−2]	−0.039		M
					25	0.25	32383.11	3087.133		[−2]			A
				24		0.35	32377.11	3087.705	3087.693	[−1]	−0.012		M
					24	0.35	32376.03	3087.809	3087.843	[ 0Nd?]	+0.034	Co i—Cr ii?	M
				23		0.5	32367.58	3088.615	3088.610	[−1]	−0.005		M
					23	0.5	32366.42	3088.725	3088.752	[ 2]	+0.027		M
				22		1	32355.73	3089.746	3089.745	[ 2]	−0.001	OH	M
					22	1	32354.53	3089.860	3089.868	[ 2]	+0.008	OH	M
				21		1.5	32341.55	3091.100	3091.071	[ 4]	−0.029	Mg i	M
					21	2	32340.55	3091.196	3091.213	[ 1N]	+0.017	CH OH‖	B
				20		2	32325.75	3092.612	3092.598	[−3]	−0.014	CH OH	B
					20	2.5	32324.78	3092.704	3092.712	[ 4]	+0.008	Al i	M
				19		2.5	32308.24	3094.288	3094.295	[ 1]	+0.007	CH—	B
					19	3.5	32307.55	3094.354	3094.364	[−1]	+0.010	CH	P
				18		} 5	${\begin{matrix} 32289.14 \\ 32288.60 \end{matrix}$	3096.119	}3096.138	[ 2]	${\begin{matrix} + 0.019 \\ - 0.031 \end{matrix}$	} OH Cr ii	M
					18	} 5	${\begin{matrix} 32289.14 \\ 32288.60 \end{matrix}$	3096.169	}3096.138	[ 2]	${\begin{matrix} + 0.019 \\ - 0.031 \end{matrix}$	} OH Cr ii	M
				17		} 6	${\begin{matrix} 32268.92 \\ 32268.35 \end{matrix}$	3098.058	3098.072	[ 0]	+0.014	CH	P
					17	} 6	${\begin{matrix} 32268.92 \\ 32268.35 \end{matrix}$	3098.113					A
				16		} 8	${\begin{matrix} 32247.47 \\ 32247.15 \end{matrix}$	3100.119	}3100.150	[−1N]	${\begin{matrix} + 0.031 \\ + 0.001 \end{matrix}$	} CH CH
					16	} 8	${\begin{matrix} 32247.47 \\ 32247.15 \end{matrix}$	3100.149	}3100.150	[−1N]	${\begin{matrix} + 0.031 \\ + 0.001 \end{matrix}$	} CH CH
				15	15	10	32224.58	3102.321	3102.299	[ 3]	−0.022	CH—V ii	B
				14	14	11	32201.35	3104.559	3104.571	[ 2N]	+0.012	CH—Ti ii?	B
				13	13	13	32177.15	3106.894	3106.907	[ 1]	+0.013	CH	P
				12	12	14	32152.07	3109.318	3109.333	[ 3]	+0.015	OH CH	B
				11	11	14.5	32126.56	3111.786	3111.814	[ 2]	+0.028	Fe i CH	B
					10	} 13.5	${\begin{matrix} 32100.38 \\ 32100.05 \end{matrix}$	3114.324	3114.316	[ 2]	−0.008	Fe ii CH	B
				10		} 13.5	${\begin{matrix} 32100.38 \\ 32100.05 \end{matrix}$	3114.356	3114.353	[ 1]	−0.003	CH	P
					9	} 13.5	${\begin{matrix} 32073.67 \\ 32073.16 \end{matrix}$	3116.919	3116.917	[ 0]	−0.002	CH	P
				9	8	} 13.5	${\begin{matrix} 32073.67 \\ 32073.16 \end{matrix}$	3116.968	3116.982	[ 1]	+0.014	CH	P
						9	32046.63	3119.548	3119.504	[ 3]	−0.044	Fe i	M
				8	7	9	32045.49^*	3119.659	3119.678	[ 1]	+0.019	OH CH Cr i	B
						9	32019.32^*	3122.209	3122.219	[ 0]	+0.010	OH CH	B
				7		9	32018.18	3122.320	3122.317	[ 1]	−0.003	Fe i CH	B
					6	11	31991.55	3124.920	3124.918	[ 2]	−0.002	CH OH	B
				6		11	31990.06^*	3125.065	3125.053	[ 2]	−0.012	Cr ii—CH	B
					5	9	31963.71	3127.641	3127.671	[ 2d?]	+0.030	\|OH CH Ti i?	B
				5		9	31961.62	3127.846	3127.846	[ 1]	0.000	CH	P
					4	7	31935.88	3130.367	3130.415	[ 1]	+0.048	Be ii	M
				4		7	31933.06	3130.543	3130.567	[ 1]	+0.024	\|OH Fe ii	M
					3	5	31908.03	3133.099	3133.066	[ 1]	−0.033	‖Fe ii—Sc ii	M
				3		5	31904.23	3133.472	3133.491	[ 0]	+0.019	Zr ii	M
					2	2.5	31880.74	3135.781					A
				2		3	31874.92	3136.354	3136.345	[−1]	−0.009	CH	P
				1		3	31844.93	3139.308	3139.306	[ 0]	−0.002	CH	P
		16	16			} 90	${\begin{matrix} 31802.95 \\ 31802.8 \\ 31802.75 \\ 31802.6 \\ 31802.35 \\ 31802.2 \end{matrix}$	3143.452	} 3143.486		${\begin{array}{l} + 0.034 \\ + 0.020 \\ + 0.015 \\ - 0.001 \\ - 0.025 \\ - 0.040 \end{array}$	} V ii CH	M
			15					3143.466
		15						3143.471
		17	17					3143.487		[ 2N]			B
			14					3143.511
		14						3143.526
			13			} 77	${\begin{array}{l} 31801.75 \\ 31801.65 \\ 31801.45 \end{array}$	3143.570	} 3143.575		${\begin{array}{l} + 0.005 \\ - 0.005 \\ - 0.025 \end{array}$	CH
		18	18					3143.580		[ 1N]			B
		13						3143.600
			12			} 61	${\begin{array}{l} 31801.05 \\ 31800.5 \\ 31800.3 \\ 31800.25 \end{array}$	3143.640					A
		12						3143.694					A
		19	19					3143.714	} 3143.764		${\begin{array}{l} + 0.050 \\ + 0.045 \\ - 0.019 \\ - 0.039 \end{array}$	}	M
			11					3143.719				}	M
		11				} 51	${\begin{array}{l} 31799.6 \\ 31799.4 \end{array}$	3143.783		[ 4]		‖Ti ii CH—OH	B
			10			} 51	${\begin{array}{l} 31799.6 \\ 31799.4 \end{array}$	3143.803
		10				} 55	${\begin{array}{l} 31798.6 \\ 31798.5 \end{array}$	3143.88	} 3143.896		${\begin{array}{l} + 0.02 \\ + 0.01 \\ - 0.03 \end{array}$	CH Cr ii
			9			} 55	${\begin{array}{l} 31798.6 \\ 31798.5 \end{array}$	3143.89		[ 0]			B
		20	20			} 57	${\begin{array}{l} 31798.1 \\ 31797.6 \\ 31797.5 \end{array}$	3143.93		[ 0]
			8					31,43.98	} 3143.996	[ 2]	${\begin{array}{l} + 0.02 \\ + 0.01 \end{array}$	CH Fe i	B
		9						3143.99	} 3143.996	[ 2]	${\begin{array}{l} + 0.02 \\ + 0.01 \end{array}$	CH Fe i
			7			} 55	${\begin{array}{l} 31796.7 \\ 31796.4 \\ 31796.0 \\ 31795.9 \end{array}$	3144.07					A
		8						3144.10	}3144.116		${\begin{array}{l} + 0.02 \\ - 0.02 \\ - 0.03 \end{array}$	CH
			6					3144.14		[ 0]			B
			2					3144.15		[ 0]			A
		7	5			} 74	${\begin{array}{l} 31795.3 \\ 31795.1 \\ 31795.0 \end{array}$	3144.21	} 3144.236		${\begin{array}{l} + 0.03 \\ + 0.01 \\ 0.00 \end{array}$	CH
		21	21					3144.23		[ 0]			B
			4, 3					3144.24		[ 0]
		6				36	31794.1	3144.33	3144.326	[ 0]	0.00	CH OH\|	B
		5				25	31793.0	3144.44	3144.453	[ 1]	+0.01	CH Cr i	B
		4				22	31792.0	3144.53	3144.501	[ 1]	−0.03	Fe i CH	B
		3, 22	22			26	31790.93	3144.640	3144.629	[ 0]	−0.011	CH	P
		2				16	31789.78	3144.754	3144.737	[ 1]	−0.017	Ti ii V ii—Fe ii\|	M
		1				8	31788.13	3144.917	3144.925	[ 1	+0.008	CH Fe i	B
		23	23			6	31786.06	3145.122	3145.091	[ 3]	−0.031	\|Fe i—Cr ii (CH)	M
		24				} 4	${\begin{array}{l} 31779.59 \\ 31779.12 \end{array}$	${\begin{array}{l} 3145.763 \\ 3145.809 \end{array}$	3145.791	[ 1]	${\begin{array}{l} + 0.028 \\ - 0.018 \end{array}$	Cr ii? CH—CH	B
			24			} 4	${\begin{array}{l} 31779.59 \\ 31779.12 \end{array}$	${\begin{array}{l} 3145.763 \\ 3145.809 \end{array}$	3145.791	[ 1]	${\begin{array}{l} + 0.028 \\ - 0.018 \end{array}$	Cr ii? CH—CH	B
		25				} 3	${\begin{array}{l} 31771.48 \\ 31770.96 \end{array}$	${\begin{array}{l} 3146.566 \\ 3146.617 \end{array}$	3146.598	[ 1]	${\begin{array}{l} + 0.032 \\ - 0.019 \end{array}$	CH—CH OH	B
			25			} 3	${\begin{array}{l} 31771.48 \\ 31770.96 \end{array}$	${\begin{array}{l} 3146.566 \\ 3146.617 \end{array}$	3146.598	[ 1]	${\begin{array}{l} + 0.032 \\ - 0.019 \end{array}$	CH—CH OH	B
		26				2	31761.53	${\begin{array}{l} 3147.551 \\ 3147.609 \end{array}$	3147.599	[ 1]	${\begin{array}{l} + 0.048 \\ - 0.010 \end{array}$	Fe i—CH	B
			26			2	31760.95	${\begin{array}{l} 3147.551 \\ 3147.609 \end{array}$	3147.599	[ 1]	${\begin{array}{l} + 0.048 \\ - 0.010 \end{array}$	Fe i—CH	B
1						4	31759.34	3147.768	3147.784	[ 1]	+0.016	Fe i	M
		27				1	31749.88	3148.706		[ 1]			A
			27			1	31749.32	3148.762	3148.797	[ 0N]	+0.035		M
	2					5	31738.48	3149.837	3149.852	[ 2]	+0.015	OH	M
2						6	31732.62	3150.419	3150.417	[−1]	−0.002	CH	P
	3					6	31709.12	3152.754	3152.737	[ 1Nd?]	−0.017	Co i—CH	B
3						6	31705.16	3153.148	3153.191	[ 3]	+0.043	\|Fe i OH	M
	4					7	31680.54	3155.598	3155.622	[ 0]	+0.024	CH	P
4						7	31677.60	3155.891	3155.905	[ 0]	+0.014	CH	P
	5					14	31652.28^*	3158.416	3158.403	[ 1]	−0.013	CH	P
5						11	31650.11	3158.632	3158.633	[ 0]	+0.001	CH	P
	6					10	31624.45	3161.195	3161.204	[ 3]	+0.009	Ti ii	M
G						13	31622.73^*	3161.367	3161.382	[ 1]	+0.015	Fe i CH	B
	7					12	31596.93	3163.949	3163.930	[ 1]	−0.019	Cr ii—CH	B
7						13	31595.59	3164.083	3164.068	[ 0]	−0.015	CH	P
	8					12	31569.75	3166.673	3166.674	[ 1]	+0.001	CH Fe ii	B
8						13	31568.73	3166.775	3166.767	[ 0]	−0.008	CH	P
	9					14	31542.82	3169.376	3169.366	[ 1]	−0.010	CH	P
9						15	31542.22	3169.438	3169.427	[ 1]	−0.011	CH	P
	10					} 18	${\begin{array}{l} 31516.27 \\ 31515.92 \end{array}$	3172.047	3172.051	[ 3]	${\begin{array}{l} + 0.004 \\ + 0.005 \end{array}$	‖Fe i Cr ii (CH)	M
10						} 18	${\begin{array}{l} 31516.27 \\ 31515.92 \end{array}$	3172.082	3172.087	[ 4]	${\begin{array}{l} + 0.004 \\ + 0.005 \end{array}$	‖Fe i Cr ii (CH)	M
11	11					20	31489.89	3174.704	3174.697	[ 2]	−0.007	CH	P
12	12					18	31464.03	3177.313	3177.302	[ 2]	−0.001	Co i—CH	B
13	13					19	31438.33	3179.911	3179.901	[ 0]	−0.010	CH	P
14	14					17	31412.94	3182.481	3182.471	[ 2]	−0.010	CH	P
15	15					15	31387.76	3185.034	3185.022	[ 1N]	−0.012	CH	P
16						}11	${\begin{array}{l} 31363.00 \\ 31362.71 \end{array}$	${\begin{array}{l} 3187.549 \\ 3187.578 \end{array}$	3187.556	[ 0Nd?]	${\begin{array}{l} + 0.007 \\ - 0.022 \end{array}$	CH—CH	B
	16					}11	${\begin{array}{l} 31363.00 \\ 31362.71 \end{array}$	${\begin{array}{l} 3187.549 \\ 3187.578 \end{array}$	3187.556	[ 0Nd?]	${\begin{array}{l} + 0.007 \\ - 0.022 \end{array}$	CH—CH	B
17						} 10	${\begin{array}{l} 31338.25 \\ 31337.82 \end{array}$	3190.066	3190.042	[ 1]	−0.024	Fe i—CH	B
	17					} 10	${\begin{array}{l} 31338.25 \\ 31337.82 \end{array}$	3190.110	3190.104	[ 1]	−0.006	CH	P
18						} 8	${\begin{array}{l} 31313.65 \\ 31313.07 \end{array}$	3192.573	3192.534	[−1]	−0.039	—CH?	B
	18					} 8	${\begin{array}{l} 31313.65 \\ 31313.07 \end{array}$	3192.632	3192.617	[−1]	−0.015	CH	P
19						6	31289.07	3195.080	3195.085	[ 0]	+0.005	CH OH	B
	19					7	31288.28	3195.161	3195.140	[−1]	−0.021	Ru ii CH	B
20						4	31264.33	3197.609	3197.596	[−1]	−0.013	Y ii?—CH	B
	20					8	31263.44^*	3197.700	3197.710	[ 1N]	+0.010	CH	P
21						3	31239.60	3200.140	3200.137	[−1]	−0.003	CH	P
	21					4	31238.63	3200.240	3200.295	[ 2Nd?]	+0.055	Y ii—	M
22						3	31214.62	3202.701	3202.695	[ 0]	−0.006	CH OH	B
	22					4	31213.57	3202.809	3202.822	[ 0]	−0.013	CH	P
23						1.5	31189.12	3205.320	3205.333	[−1]	+0.013	CH	P
	23					2	31188.04	3205.431	3205.408	[ 2]	−0.023	Fe i—CH	B
24						1	31163.39	3207.967	3207.989	[ 0]	+0.022	CH—	B
	24					1.5	31162.11	3208.098	3208.094	[ 0]	−0.004	CH	P
25						1	31136.68	3210.719	3210.724	[−1]	+0.005	CH OH	B
	25					1	31135.45	3210.845	3210.836	[ 2]	−0.009	Fe i	M
26						1	31108.98	3213.577	3213.564	[−2]	−0.013	Ti ii Fe i	M
	26					1	31107.64	3213.716	3213.694	[−1]	−0.022		M
27						1	31080.42	3216.530	3216.546	[ 0]	+0.016	Cr ii	M
	27					1	31079.03	3216.674	3216.694	[ 1]	+0.020	Y ii	M
28						0.5	31050.36	3219.645					A
	28					1	31049.00	3219.786	3219.805	[ 3]	+0.019	Fe i	M

Laboratory											Sun

Q_1c	Q_1d	Q_2c	Q_2d	R_1cd	R_1dc	R_2cd	R_2dc	Intensity	Wave number cm⁻¹	Wavelength A	Wavelength A	Disk int. Δλ/λ	Spot	⊙—lab. A	Solar identification	Notes
					16		16	2	21150.36	4726.734
				16		16		2	21141.13	4728.797
							15	3	21098.50	4738.351
					15			3	21098.30	4738.396
				15		15		3	21090.29	4740.196
							14	3	21047.63	4749.804
					14			3	21047.18	4749.906
				14		14		4	21040.28^*	4751.463
							13	3	20998.06	4761.118
					13			3	20997.21^*	4761.219
						13		3	20991.33	4762.545
				13				3	20991.07	4762.602
24								2	20952.79^*	4771.305
							12	4	20948.90	4772.189
					12			4	20948.05	4772.384
						12		4	20943.28	4773.470
				12				4	20942.98	4773.538
			24					1	20931.95	4776.054
23								2	20914.78^*	4779.975
		23						2	20912.79^*	4780.429
							11	4	20901.20	4783.081
					11			4	20900.28	4783.292
	23					11		4	20896.39	4784.181
			23	11				4	20895.80	4784.317
22								1	20878.04	4788.386
		22						2	20876.51	4788.737
	22		22					1	20860.86	4792.330
							10	4	20854.80	4793.724
					10			4	20853.60	4793.999
						10		4	20850.71	4794.663
				10				4	20849.84	4794.862
21								1	20842.57	4796.536
		21						1	20841.93	4796.684
	21		21					1	20827.31	4800.050
							9	4	20809.64	4804.164
20		20			9			6	20808.15	4804.472
						9		4	20806.18	4804.925
				9				4	20805.12	4805.171
	20							2	20795.31	4807.437
			20					2	20794.70	4807.578
19		19						3	20775.59	4812.001
							8	5	20765.81^*	4814.267
					8			6	20764.24^*	4814.630
	19							2	20763.51	4814.800
			19			8		7	20763.02^*	4814.913
				8				6	20761.64^*	4815.233
18		18						4	20743.87	4819.359
	18							2	20733.14	4821.853
			18					2	20732.67	4821.962
							7	5	20723.41	4824.117
					7	7		7	20721.43	4824.577
				7				5	20719.61	4825.001
17		17						4	20713.57	4826.409
	17							3	20703.79	4828.687
			17					3	20703.31	4828.800
		16						3	20684.76	4833.131
16								3	20684.56	4833.177
							6	4	20682.62	4833.630
						6		5	20681.02	4834.004
					6			6	20680.25	4834.185
				6				5	20678.88	4834.505
	16		16					5	20675.54^*	4835.285
		15						4	20657.22	4839.573
15								4	20656.75	4839.684
	15		15					5	20648.92	4841.520
							5	5	20643.44	4842.804
						5		5	20642.36	4843.058
					5			5	20640.66	4843.457
				5				5	20639.68	4843.686
		14						5	20631.09	4845.704
14								6	20630.61^*	4845.817
	14		14					6	20623.71	4847.438
		13						6	20606.45^*	4851.499
13							4	7	20605.89	4851.630
						4		6	20605.36^*	4851.755
					4			5	20602.47	4852.435
				4				5	20601.78	4852.598
	13		13					6	20599.91	4853.038
		12						5	20583.50	4856.908
12								6	20582.64^*	4857.110
			12					6	20577.87	4858.236
	12							6	20577.42	4858.343
							3	4	20570.66	4859.939
						3		4	20570.13	4860.065
							^‡	1	20566.39	4860.949
					3			6	20565.74	4861.103
				3				6	20565.43	4861.176
		11						5	20562.10	4861.963
11								6	20561.04	4862.213
			11					6	20557.26	4863.107
	11							6	20556.64	4863.255
		10						6	20542.32	4866.644
10								6	20541.10	4866.932
			10					6	20538.26	4867.606
	10					2	2	8	20537.45	4867.799	4867.874	11.5	u	+ 0.075	Co i	M
							^‡	2	20531.58	4869.190
				2	2			7	20530.44	4869.460	4869.469	4.1	u	+ 0.009	Fe i	M
		9						6	20524.30	4870.916	4870.94	0.8		+ 0.02	Ni i	M
9								6	20522.84	4871.263						A
			9					6	20520.91	4871.721	4871.683	3.1		−0.038		A
	9							6	20519.81	4871.982	4871.935	9.2	u	−0.047	Fe i p	M
						1	1	5	20515.74	4872.950						A
		8						6	20508.01	4874.786	4874.793	4.3	w?	+ 0.007	Ni i	M
8								6	20506.31	4875.190	4875.198	0.6		+ 0.008	CH?	P
			8					6	20505.26	4875.439	4875.492	8.4	S	+ 0.053	V i	M
	8							6	20503.87	4875.771	4875.739	0.7		−0.032	Fe i p	M
							^‡	3	20497.98	4877.172
				1	1			7	20496.23^*	4877.589	4877.590	4.3	u	+ 0.001	Fe i	M
		7						6	20493.48	4878.243	4878.225	24.2	w	−0.018	Fe i	M
7			7					9	20491.43	4878.730	4878.721	0.6		−0.009	CH	P
	7							G	20489.56	4879.175	4879.150	0.4		−0.025	CH?	P
		6						5	20480.80^*	4881.262	4881.267	0.4		+ 0.005	CH?	P
			6					6	20479.27^*	4881.627						A
6								G	20478.34^*	4881.849						A
	6							7	20476.93^*	4882.185	4882.148	13.9	u	−0.037	Fe i	M
		5						5	20470.05	4883.826						A
			5					5	20468.83	4884.117						A
							^‡	1	20468.24	4884.258
5								6	20467.00	4884.555	4884.598	4.3	o	+ 0.043	Cr ii	M
	5							7	20465.98	4884.798	4884.803	1.5		+ 0.005	CH?—	B
		4						5	20461.26	4885.924	4885.950	2.4	s	+ 0.026	Cr i	M
			4				^‡	6	20460.46	4886.116	4886.086	0.2		−0.030	CH?	P
							^‡	1	20459.83	4886.266
							^‡	1	20458.12	4886.674
4							^‡	7	20457.36^*	4886.856	4886.845	0.6	s	−0.011	V i—CH?	B
	4							6	20456.67^*	4887.021	4887.009	12.9	s	−0.012	‖Cr i Ni i	M
		3						4	20454.60	4887.514	4887.533	1.0		+ 0.019		M
			3					4	20454.11	4887.631						A
							^‡	1	20453.37	4887.808
		2	2				^‡	3	20450.57	4888.477
				3				6	20449.34	4888.768						A
					3		^‡	6	20449.01	4888.850	4888.829	1.5		−0.021	—CH?	B
							^‡	1	20444.50	4889.930
				2	2			4	20442.89^*	4890.315
			3					2	20367.91	4908.318
		3						2	20367.11	4908.510
							^‡	1	20366.17	4908.737
							^‡	1	20365.41	4908.919
	3							2	20361.98	4909.746
3								2	20361.46	4909.871
			4					1	20345.30	4913.773
		4						1	20344.31	4914.011
							^‡	1	20343.19	4914.283
	4							2	20340.94	4914.827
4								2	20340.23	4914.997
			5					2	20325.13	4918.650
		5						2	20323.98	4918.927
							^‡	2	20323.26	4919.101
	5							3	20321.82	4919.451
5								3	20320.85	4919.686
			6					2	20307.32	4922.963
		6						2	20305.76	4923.342
	6							2	20304.63	4923.614
6								3	20303.26	4923.948
	22							1	20301.04	4924.487
			22					1	20299.58	4924.839
			7					4	20291.61	4926.775
	7	7						5	20289.45	4927.299
7								4	20287.51	4927.770
	21							2	20285.93	4928.154
22								2	20285.35	4928.294
	22		21					2	20284.55	4928.489
			8					4	20277.97	4930.088
	8							4	20276.17	4930.526
		8						4	20275.20	4930.762
8	20		20					5	20273.67	4931.134
21								1	20272.33	4931.460
		21						1	20271.16	4931.744
			9					4	20266.41	4932.901
	9							4	20264.88	4933.273
	19	9	19					5	20263.12	4933.702
9								4	20261.84	4934.013
20								2	20260.69	4934.294
		20						2	20260.04	4934.453
			10					3	20256.94	4935.206
	10							3	20255.70	4935.509
	18		18					3	20254.61	4935.773
		10						3	20252.96	4936.176
10								4	20251.99	4936.412
19								3	20251.35	4936.569
		19						3	20250.77	4936.710
			11					3	20249.64	4936.986
	11							4	20248.49	4937.265
	17		17					3	20248.07	4937.369
		11						3	20244.80	4938.166
11, 18			12					4	20244.16	4938.321
	12	18	16					5	20243.38	4938.511
	16							3	20242.97	4938.613
			13					3	20241.03	4939.085
			15					3	20240.55	4939.202
	13, 15							4	20240.22	4939.282
			14					3	20239.85	4939.373
	14							3	20239.26	4939.518
		12						3	20238.70	4939.654
12, 17		17						4	20238.13	4939.792
		13						3	20234.42	4940.700
13, 16		16						5	20234.21	4940.750
14, 15		14, 15						5	20232.34	4941.208

Designation	J	Laboratory
Designation	J	Wave No.	Wavelength

R_{Q 2c 1d}; R_{Q2d 1c}	3; 3	20566.39	4860.949
R_{Q 2c 1d}; R_{Q2d 1c}	2; 2	20531.58	4869.190
R_{Q 2c 1d}; R_{Q2d 1c}	1; 1	20497.98	4877.172
Q_{R 1 2d}	5	20468.24	4884.258
Q_{R 1 2d}	4	20460.46	4886.116
Q_{R 1 2d}	4	20459.83	4886.266
Q_{P 1 2d}	4	20458.12	4886.674
Q_{P 1 2d}	4	20457.36	4886.856
Q_{R 1 2c}; Q_{R 1 2d}	3; 3	20453.37	4887.808
Q_{P 2 1c}; Q_{P 2 1d}	3; 3	20450.57	4888.477
Q_{R 1 2c}; Q_{R 1 2d}	2; 2	20449.01	4888.850
Q_{P 2 1c}; Q_{P 2 1d}	2; 2	20444.50	4889.930
P_{Q 1d 2c}	3	20366.17	4908.737
P_{Q 1c 2d}	3	20365.41	4908.919
P_{Q 1c 2d}	4	20343.19	4914.283
P_{Q 1c 2d}	5	20323.26	4919.101

Laboratory											Sun

P_1dc	P_1cd	P_2dc	P_2cd	Q_1c	Q_1d	Q_2c	Q_2d	Intensity	Wave number cm⁻¹	Wavelength A	Wavelength A	Disk int. Δλ/λ	Spot	⊙—lab. A	Solar identification	Notes
							3	141	23181.39^*					−0.028	Mn i —CH	B
						3, 2	2	140	23180.78^*	4312.706	4312.709	8.8		+ 0.003	CH	P
					4		^‡	200?	23179.75^*	4312.897	4312.875	35.5	w?	−0.022	\|Ti ii—CH	B
				4			^‡	200?	23179.05^*	4313.027	4313.035	19.5	wN	+ 0.008	\|CH Fe i p	B
							^‡	M	23177.73	4313.273	4313.237	1.5		−0.036	\|CH Fe i p	A
							^‡	} 160	${\begin{matrix} 23177.15 \\ 23176.04 \\ 23175.66 \end{matrix}$	4313.381	4313.418	2.0		+ 0.037		A
					3					$\begin{matrix} 4313.587 \\ 4313.658 \end{matrix}}$	4313.631	18.8		${\begin{matrix} + 0.044 \\ - 0.027 \end{matrix}}$	CH—CH
				3						$\begin{matrix} 4313.587 \\ 4313.658 \end{matrix}}$	4313.631	18.8		${\begin{matrix} + 0.044 \\ - 0.027 \end{matrix}}$	CH—CH	B
							^‡	6	23174.46^*	4313.881	4313.890	2.6	s	+ 0.009		M
				2	2			124	23172.72^*	4314.206	4314.221	7.9	w	+ 0.015	CH	P
			3					7	23094.44	4328.829	4328.845	2.1	u	+ 0.016	CH	P
		3						6	23093.98	4328.915	4328.927	1.3		+ 0.012	CH	P
							^‡	20	${\begin{matrix} 23092.75 \\ 23092.26 \end{matrix}$	4329.146	4329.144	1.2		−0.002	CH	P
							^‡	20	${\begin{matrix} 23092.75 \\ 23092.26 \end{matrix}$	4329.238						A
	3							20	${\begin{matrix} 23088.52 \\ 23088.19 \end{matrix}$	4329.939						A
3								20	${\begin{matrix} 23088.52 \\ 23088.19 \end{matrix}$	4330.001	4330.024	8.1	s	+ 0.023	V i	M
			4					18	23067.73	4333.842						A
		4						19	23066.89	4334.000	4334.018	2.3		+ 0.018	CH	P
							^‡	10	23065.80	4334.204	4334.166	2.3		−0.038	Sm ii	M
	4							28	23063.39	4334.658	4334.672	3.9		+ 0.014	CH	P
4								28	23062.75	4334.778	4334.800	3.9	s	+ 0.022	CH—Ti i\|	B
			5					40	23042.29^*	4338.627	4338.627	3.2		0.000	CH	P
		5						40	23041.13	4338.845	4338.829	6.4	ud	−0.016	Cr i Fe i p	M
	5							45	23038.95	4339.256	4339.259	8.1	u	+ 0.003	Fe i (CH)	M
5								43	23037.92	4339.450	4339.456	27.4	s	+ 0.006	Cr i	M
			6					40	23018.16^*	4343.175	4343.216	15.0	ud^*	+ 0.041	\|Cr i —Fe i p	M
		6						45	23016.49	4343.490	4343.494	10.4		+ 0.004	CH	P
	6							50	23015.42^*	4343.692	4343.705	18.6	u	+ 0.013	Fe i (CH)	M
6								45	23013.97	4343.966	4343.968	11.5	u	+ 0.002	CH	P
			7					54	22995.12	4347.527	4347.545	9.0		+ 0.018	CH	P
	7	7						115	22992.82^*	4347.961	4347.973	13.1		+ 0.012	CH	P
7								64	22990.84	4348.336	4348.338	12.0		+ 0.002	CH	P
			8					70	22972.96	4351.720	4351.710	0.5		−0.010	CH	P
	8							78	22971.08	4352.076	4352.072	16.8		−0.004	CH	P
		8						66	22970.14	4352.254	4352.261	12.2		+ 0.007	CH	P
8								77	22968.54	4352.558	4352.557	12.2		−0.001	CH	P
			9					70	22951.90	4355.713	4355.704	11.0		−0.009	CH	P
	9							78	22950.32	4356.013	4356.000	16.8		−0.013	CH	P
		9						77	22948.41	4356.375	4356.367	12.6		−0.008	CH	P
9								77	22947.14	4356.617	4356.604	12.4		−0.013	CH	P
			10					110	22931.91^*	4359.510	4359.493	13.8		−0.017	CH	P
	10							80	22930.62	4359.755	4359.744	15.6	w	−0.011	Zr ii CH	B
		10						94	22927.76	4360.299	4360.289	13.3		−0.010	CH	P
10								94	22926.72	4360.497	4360.480	13.5	s	−0.017	Ti i CH	B
			11					100	22913.02	4363.105	4363.108	16.5	ud	+ 0.003	CH—Cr i	B
	11							103	22911.90	4363.318	4363.293	13.8	wd	−0.025	CH	P
		11						110	22908.07	4364.048	4364.041	11.0		−0.007	CH	P
11								110	22907.26	4364.202	4364.189	12.1		−0.013	CH	P
			12					100	22895.08^*	4366.524	4366.500	14.4		−0.024	CH	P
	12							104	22894.13	4366.705	4366.675	16.5		−0.030	CH	P
		12						120	22889.32^*	4367.622	4367.594	32.7	u	−0.028	\|Fe i—CH	B
12								110	22888.68	4367.745	4367.723	3.2		−0.022	CH	P
			13					100	22878.29	4369.728	4369.714	6.2	u	−0.014	Ti i—Fe i p (CH)	M
	13							100	22877.55	4369.870	4369.866	2.3		−0.004	CH	P
		13						} 150	${\begin{matrix} 22871.46 \\ 22871.26 \end{matrix}$	4371.033	} 4371.062	17.8	wd	${\begin{matrix} + 0.029 \\ - 0.010 \end{matrix}$	} CH—CH	B
13								} 150	${\begin{matrix} 22871.46 \\ 22871.26 \end{matrix}$	4371.072	} 4371.062			${\begin{matrix} + 0.029 \\ - 0.010 \end{matrix}$	} CH—CH
			14					100	22862.50	4372.746	4372.743	9.1		−0.003	CH	P
	14							100	22861.86	4372.869	4372.844	15.8		−0.025	CH	P
14		14						130	22854.73^*	4374.233	4374.226	14.4		−0.007	CH	P
			15					90	22847.78	4375.563	4375.578	15.3		+ 0.015	CH	P
	15							90	22847.20	4375.675	4375.658	15.8		−0.017	CH	P
15		15						150	22838.96^*	4377.253	4377.234	19.9		−0.019	CH	P
			16					} 100	${\begin{matrix} 22833.79 \\ 22833.50 \end{matrix}$	4378.244	} 4378.255	19.0		${\begin{matrix} + 0.011 \\ - 0.045 \end{matrix}$	} CH—CH?	B
	16							} 100	${\begin{matrix} 22833.79 \\ 22833.50 \end{matrix}$	4378.300	} 4378.255			${\begin{matrix} + 0.011 \\ - 0.045 \end{matrix}$	} CH—CH?
16		16						120	22824.21^*	4380.282	4380.367	3.4	u	+ 0.085	Mg i (CH)	M
	17		17					125	22820.85^*	4380.727	4380.724	21.0		−0.003	CH—	B
17								} 90	${\begin{matrix} \end{matrix}$ 22810.49 22810.33	4382.716	4382.689	5.7		−0.027	CH	P
		17						} 90	${\begin{matrix} \end{matrix}$ 22810.49 22810.33	4382.747	4382.764	22.4		+ 0.017	CH—Fe i\|	B
	18		18					90	22808.95^*	4383.012	4382.998	16.4		−0.014	—CH	B
	19		19					} 130	${\begin{matrix} 22798.05 * \\ 22797.66 \\ 22797.15 \end{matrix}$	4385.108	4385.124	14.1		+ 0.016	CH	P
18										4385.183						A
		18								4385.281	4385.254	12.1	u	−0.027	\|Fe i—CH	B
	20		20					80	22787.78^*	4387.084	4387.063	13.4		−0.021	CH	P
19								60	22785.64	4387.496	4387.497	13.9	s	+ 0.001	Cr i (CH)	M
		19						55	22785.10	4387.600	4387.595	9.6		−0.005	CH	P
	21		21					66	22778.38^*	4388.894	4388.870	10.7		−0.024	CH	P
20								50	22774.41	4389.660	4389.638	10.2		−0.022	CH	P
		20						40	22773.73	4389.791	4389.776	6.8		−0.015	CH	P
	22		22					60	22769.83^*	4390.543	4390.545	8.9		+ 0.002	CH	P
21								45	22763.95	4391.677	4391.668	11.8	u?	−0.009	Ce ii—CH	B
		21						44	22763.20	4391.821	4391.768	15.2	s	−0.053	Cr i (CH)	M
	23		23					44	22761.77^*	4392.097	4392.071	12.3	s	−0.026	V i CH	B
22	24		24					60	22754.30^*	4393.539	4393.524	16.2	ud?	−0.015	—CH	B
		22						35?	22753.39	4393.715	4393.700	6.4	w	−0.015	Fe i p—CH	B
	25		25					34	22747.36^*	4394.879	4394.852	11.6	s	−0.027	Ti i	M
23								48	22745.11	4395.314	4395.289	3.4		−0.025	Fe i CH	B
		23						45	22744.16	4395.498	4395.504	15.0	ud	+ 0.006	CH—Fe i	B
	26							} 20	${\begin{matrix} 22741.09 \\ 22740.72 \end{matrix}$	4396.091	4396.079	5.0		−0.012	CH	P
			26					} 20	${\begin{matrix} 22741.09 \\ 22740.72 \end{matrix}$	4396.163	4396.153	4.1		−0.010	—CH	B
24								36	22736.52	4396.975	4396.961	10.2		−0.014	CH	P
		24						} 22	${\begin{matrix} 22735.60 \\ 22734.82 \end{matrix}$	4397.153	4397.143	5.0	u	−0.010	CH	P
	27							} 22	${\begin{matrix} 22735.60 \\ 22734.82 \end{matrix}$	4397.304						A
			27						22734.38	4397.389	4397.381	3.4	u	−0.008		M
25	28							24	22728.58^*	4398.511	4398.491	7.7		−0.020	CH V ii	B
			28					16	22727.97	4398.629	4398.621	5.4	w	−0.008	Ni i CH	B
		25						14	22727.44	4398.732	4398.712	4.3	w	−0.020	CH	P
26								14	22720.92	4399.994	4399.989	4.8		−0.005	CH	P
		26						20	22719.74	4400.223	4400.185	9.3		−0.038	Ni i CH?	B
27									22713.45	4401.441	4401.451	15.0	u	+ 0.010	Fe i	M
		27							22712.19	4401.685	4401.668	2.5		−0.017	CH?	P
28									22706.19	4402.848	4402.841	4.1	u	−0.007	CH	P
		28							22704.86^*	4403.106	4403.077	4.5	uN	−0.029	CH	P
29									22698.72	4404.297	4404.277	12.0	u	−0.020	\|Ti i—CH	B
		29							22697.44	4404.546	4404.548	5.2		+ 0.002	CH?	P
30									22691.10	4405.776	4405.732	6.4	sd	−0.044	Ti i—CH?	B
		30							22689.73	4406.043	4406.036	3.0	u	−0.007	CH?	P
31									22683.17	4407.317						A
		31							22681.62	4407.618	4407.652	14.1	sd^*	+ 0.034	V i	M
32									22674.32	4409.037						A
		32							22672.69	4409.354	4409.359	2.9	uN	+ 0.005		M
33									22664.71	4410.907						A
		33							22663.07^*	4411.226	4411.227	5.4	uN	+ 0.001	CH—CH?	M
34									22654.44	4412.906	4412.877	1.4	u	−0.029		M
		34							22653.18	4413.152	4413.121	2.5		−0.031		M

Designation	J	Laboratory
Designation	J	Wave number	Wavelength

R_{Q 2d 1c}	3	23293.17^*	4291.897
R_{Q 2c 1d} ; R_{Q 2d 1c}	2; 2	23261.34^*	4297.769
R_{Q 2c 1d} ; R_{Q 2d 1c}	1; 1	23229.71^*	4303.621
Q_{R 1 2c}	3	23179.75^*	4312.897
Q_{R 1 2d}	2	23179.05^*	4313.027
Q_{P 2 1d}	3	23177.73	4313.273
Q_{P 2 1c}	3	23177.15	4313.381
Q_{P 2 1d}; Q_{P 2 1c}	2; 2	23174.46^*	4313.881
R_{Q 1d 2c}	3	23092.75	4329.146
R_{Q 1c 2d}	3	23092.26	4329.238
R_{Q 1c 2d}	4	23065.80	4334.204

d	double	S	greatly
N	diffuse		strengthened
NN	very diffuse	u	unchanged
o	obliterated	w	weakened
s	strengthened	W	greatly weakened

Laboratory											Sun

Q_1c	Q_1d	Q_2c	Q_2d	R_1dc	R_1cd	R_2dc	R_2cd	Intensity	Wave number cm⁻¹	Wavelength A	Wavelength A	Disk int. Δλ/λ	Spot	⊙—lab. A	Solar identification	Notes
				35				1	24184.33	4133.743	4133.722	1.7		−0.021	CH? CN?	B
				34				2	24182.46	4134.063						A
						34		1.5	24181.09	4134.297	4134.347	20.3	s	+ 0.050	Fe i	M
				33				2	24175.90	4135.185	4135.173	1.5		−0.012	CH?	P
						33		2	24174.40	4135.441	4135.458	4.6	uN	+ 0.017	CH?—CN?	B
				32				2.5	24165.49	4136.966	4137.005	25.1	u	+ 0.039	Fe i	M
						32		2	24163.75	4137.264	4137.274	11.6	s	+ 0.010	Ti i	M
				31				3.5	24151.56	4139.352	4139.371	3.4		+ 0.019	CH	P
						31		3	24150.15	4139.594	4139.610	3.4		+ 0.016	CH	P
				30				4	24134.77	4142.232						A
						30		4	24133.31	4142.482	4142.474	11.6	u	−0.008	Cr i	M
				29				7	24115.36	4145.566	4145.559	7.7	w	−0.007	—CH	B
						29		6	24113.94	4145.810						A
				28				7.5	24093.65	4149.301	4149.370	26.8	u	+ 0.069	Fe i	M
						28		7	24092.32	4149.530	4149.538	2.9		+ 0.008	CH	P
					27			} 4	${\begin{matrix} 24091.29 \\ 24090.63 \end{matrix}$	4149.708	4149.699	1.0		−0.009	CH	P
							27	} 4	${\begin{matrix} 24091.29 \\ 24090.63 \end{matrix}$	4149.821						A
				27				11	24069.93	4153.390	4153.389	8.7	ud?	−0.001	CH Fe i	B
						27		9.5	24068.63	4153.614	4153.620	5.8	s	+ 0.006	CH—	B
					26			} 12	${\begin{matrix} 24064.65 \\ 24064.24 \end{matrix}$	4154.301	4154.287	4.8	u	−0.014	CH	P
							26	} 12	${\begin{matrix} 24064.65 \\ 24064.24 \end{matrix}$	4154.372	4154.379	7.0		+ 0.007	CH	P
				26				14	24044.50	4157.783	4157.788	30.5	u	+ 0.005	Fe i	M
						26		13	24043.24	4158.001	4158.007	7.0		+ 0.006	CH	P
					25			22	${\begin{matrix} 24036.45 \\ 24036.15 \end{matrix}$	4159.175	4159.186	26.7	w	+ 0.011	(CH)	M
							25	22	${\begin{matrix} 24036.45 \\ 24036.15 \end{matrix}$	4159.227	4159.240	0.6		+ 0.013	CH	P
				25				17	24017.48	4162.460	4162.460	7.0	o?	0.000	\|CH—CN?	B
						25		16	24016.32	4162.661	4162.660	8.2	u	−0.001	CH—CN?	B
					24			} 32	${\begin{matrix} 24007.03 \\ 24006.79 \end{matrix}$	4164.272	4164.263	8.9	u	−0.009	CN Fe i p—CH	B
							24	} 32	${\begin{matrix} 24007.03 \\ 24006.79 \end{matrix}$	4164.314	4164.330	7.9	u	+ 0.016	CN CH	B
				24				21	23989.16	4167.374	4167.400	5.8		+ 0.026	CH	P
						24		20	23988.04	4167.569	4167.571	13.2	u	+ 0.002	CH	P
					23			} 44	${\begin{matrix} 23976.39 \\ 23976.15 \end{matrix}$	4169.594	} 4169.615	12.9	ud?	${\begin{matrix} + 0.021 \\ - 0.021 \end{matrix}$	} CH—CH	B
							23	} 44	${\begin{matrix} 23976.39 \\ 23976.15 \end{matrix}$	4169.636	} 4169.615	12.9	ud?	${\begin{matrix} + 0.021 \\ - 0.021 \end{matrix}$	} CH—CH	B
				23				27	23959.62	4172.513	4172.482	12.0	u	−0.031	CH	P
						23		26	23958.65	4172.682	4172.644	25.4	u^*	−0.038	Fe i	M
					22		22	58	23944.63^*	4175.125	4175.130	15.8	wN	+ 0.005	CH—CN	B
				22				36	23929.08	4177.838	4177.849	11.5	wN	+ 0.011	\|CH—CN	B
						22		33	23928.19	4177.994	4177.999	2.4		+ 0.005	CH	P

Laboratory						Sun

P	Q	R	Intensity	Wave number cm⁻¹	Wavelength A	Wavelength A	Disk int. Rowl. est.	⊙—lab. A	Solar identification	Notes
		19	1	32050.51	3119.171	3119.198	[ 1Nd?]	+0.027		M
		18	(CH)	32045.67^*	3119.642	3119.678	[ 1]	+0.036	OH CH Cr i	M
		17	1	32038.34	3120.355	3120.372	[ 3 ]	+0.017	Cr ii	M
		16	1.5	32029.60	3121.207	3121.160	[ 4 ]	−0.047	V ii	M
		15	(CH)	32019.19^*	3122.222	3122.219	[ 0 ]	−0.003	OH CH	M
		14	2	32006.57	3123.453	3123.443	[−1 ]	−0.010	OH	M
		13	(CH)	31990.65^*	3125.007	3124.998	[ 4 ]	−0.009	Cr ii	M
		12	4.5	31974.16	3126.619	3126.617	[ 1 ]	−0.002	CH OH—OH	B
		11	3	31956.69	3128.328	3128.289	[ 1 ]	−0.039	Sc ii OH \|	M
		10	(OH)	31936.86	3130.271	3130.267	[ 3 ]	−0.004	\|V ii—OH	M
		8	(OH)	31895.65	3134.315	3134.337	[ 1 ]	+0.022	\|OH Cr ii	M
		7	1.5	31873.48	3136.495	3136.506	[ 2 ]	+0.011	V ii	M
		6	1.3	31850.58	3138.751	3138.786	[ 0 ]	+0.035		A
		5	1.5	31826.96	3141.080	3141.106	[−1 ]	+0.026	CH?	P
	2		2	31670.8	3156.57	3156.565	[ 0 ]	−0.01	—CH	B
	3			31670.2	3156.63					A
	4		2	31669.0	3156.75	3156.727	[ −1 ]	−0.02	CH	P
	5		2	31667.2	3156.93	3156.916	[ 0 ]	−0.01	—CH	B
	6		6	31665.2	3157.13	3157.143	[ 1 ]	+0.01	\|OH—Fe ip	M
	7		3	31663.0	3157.35					A
	8		4	31660.1	3157.64	3157.634	[−1 ]	−0.01	CH	P
	9		4	31658.8	3157.77	3157.751	[ 0 ]	−0.02	CH OH?	B
	10		(CH)	31652.9^*	3158.36	3158.351	[ 0 ]	−0.01	Fe iip—	M
	11		6	31648.4	3158.80	3158.783	[ 1 ]	−0.02	Co i CH	B
	12		6	31643.3	3159.31	3159.349	[ 0 ]	+0.04	Fe iip?—V ii?	M
	13		6	31637.2	3159.92	3159.935	[ 0N ]	+0.02	CH—	B
	14		5	31630.3	3160.61	3160.612	−1	0.00	Cr i CH	B
	15		(CH)	31622.2^*	3161.42	3161.423	[ 0 ]	0.00		M
	16		6	31612.9	3162.35	3162.353	[ 1 ]	0.00	Fe i CH	B
	17		4	31602.1	3163.43	3163.423	[ 2 ]	−0.01	Nb ii—CH	B
	18		4	31589.5	3164.69	3164.685	[ 1 ]	−0.01	Mn ii—CH	B
	19		3	31575.1	3166.14	3166.130	[ 0 ]	−0.01	CH	P
	20		3	31558.4	3167.81	3167.790	[ 1 ]	−0.02	Fe i—CH	B
	21		(CH)	31540.6	3169.60	3169.616	[ 0 ]	+0.02	OH	M
6			2	31503.07	3173.376	3173.408	[ 1 ]	+0.032	Fe i	M
7			2	31473.45	3176.362	3176.351	[ 1 ]	−0.011	Fe i	M
8			2	31444.83	3179.253					A
9			3	31417.00	3182.070	3182.061	[ 1 ]	−0.009	Fe i—CH	B

Laboratory
P_1cd	P_1dc	P_2cd	P_2dc	Q_1c	Q_1d	Q_2c	Q_2d	R_1cd	R_1dc	R_2cd	R_2dc	Intensity	Wave number cm⁻¹	Wavelength A
									13		13	1	21083.78	4741.660
								13		13		2	21077.49	4743.076
									12		12	4	21040.28^*	4751.463
								12		12		1	21034.82	4752.697
											11	2	20998.22	4760.982
									11			3	20997.21^*	4761.219
										11		1	20993.57	4762.035
								11				1	20992.87	4762.194
											10	2	20956.62	4770.432
									10			2	20955.52	4770.682
										10		2	20952.79^*	4771.305
								10				2	20951.91	4771.505
											9	2	20916.02	4779.692
									9			2	20914.78^*	4779.975
										9		2	20912.79^*	4780.429
								9				2	20911.85	4780.644
											8	2	20876.26	4788.794
									8			2	20874.73	4789.145
										8		2	20873.82	4789.354
								8				2	20872.56	4789.644
											7	2	20837.84	4797.625
									7	7		3	29835.83	4798.089
								7				2	20834.15	4798.475
											6	2	20800.39	4806.263
										6		2	20798.97	4806.591
									6			2	20798.14	4806.784
				17		17		6				3	20796.78	4807.097
					17		17					1	20787.35	4809.279
				16		16						2	20774.31	4812.296
					16		16					5	20765.81^*	4814.267
											5	6	20764.24^*	4814.630
										5		7	20763.02^*	4814.913
									5			6	20761.64^*	4815.233
								5				2	20760.55	4815.486
						15						2	20752.52	4817.350
				15								1	20751.93	4817.486
					15		15					2	20744.41	4819.232
						14						2	20731.59	4822.214
				14								2	20730.92	4822.370

Laboratory											Sun

Q_1c	Q_1d	Q_2c	Q_2d	R_1dc	R_1cd	R_2dc	R_2cd	Intensity	Wave number cm⁻¹	Wavelength A	Wavelength A	Disk int. Δλ/λ	Spot	⊙–lab. A	Solar identification	Notes
				29, 28				3?	23886.86^*	4185.222						A
						29, 28		4?	23883.64^*	4185.787	4185.779	4.5		−0.008		M
				27				6?	23880.52	4186.334	4186.336	9.3	uN	+ 0.002	CN—Cr i	M
				30		27		M	23879.45^*	4186.521						A
				26				4	23872.78	4187.691	4187.720	7.2		+ 0.029		M
						26		4	23871.58	4187.901	4187.812	20.8	u	−0.089	Fe i	M
				25				5	23861.81	4189.616	4189.565	16.7	u	−0.051	Fe i	M
						25		5	23860.75	4189.802	4189.816	3.8	s	+ 0.014	V i	M
				24	23		23	13	23848.12^*	4192.021	4192.016	12.4	u	−0.005	CN?—CH	B
						24		6?	23847.29	4192.167	4192.204	3.6		+ 0.037	CH	P
				23				(CH)	23831.96^*	4194.864	4194.848	15.5	u	−0.016	CH	M
						23		8?	23831.30	4194.980	4194.996	11.2	sd?	+ 0.016	CH Cr I—CN	B
					22		22	11	23828.76^*	4195.427	4195.415	3.6		−0.012	Cr ii—CH	B
				22				10	23813.78	4198.066	4198.068	23.1	uN	+ 0.002	Fe i—	M
						22		10	23813.08	4198.189	4198.242	32.9	u	+ 0.053	Fe i	M
					21		21	15	23807.69^*	4199.140	4199.105	43.6	u	−0.035	Fe i	M
				21				14	23793.81	4201.589	4201.577	7.4	w	−0.012	—CH	B
						21		12	23793.07	4201.720	4201.715	17.1	w	−0.005	\|Ni i Fe i	M
					20		20	18	23785.01	4203.144	4203.129	9.5	sd	−0.015	—CH	B
				20				16	23772.11	4205.426	4205.390	9.8	wN	−0.036	Mn ii—CH	B
						20		14	23771.49	4205.535	4205.544	21.2	s	+ 0.009	Fe i (CH)	M
					19		19	16	23760.89^*	4207.411	4207.408	14.0	wN	−0.003	CH	P
				19				19	23748.98	4209.521	4209.500	6.4	u	−0.021	CH	P
						19		18	23748.45	4209.615	4209.602	7.1	u	−0.013	CH	P
					18		18	33	23735.48^*	4211.916	4211.895	15.4	u	−0.021	\|Zr ii—CH	B
				18				} 26	${\begin{matrix} 23724.56 \\ 23724.27 \end{matrix}$	4213.854	4213.839	4.7	u	−0.015	CH	P
						18		} 26	${\begin{matrix} 23724.56 \\ 23724.27 \end{matrix}$	4213.906	4213.909	10.7		+ 0.003	CH	P
					17		17	39	23709.04	4216.613	4316.599	11.6	uN	−0.014	CH	P
				17		17		} 36	${\begin{matrix} 23699.07 \\ 23698.85 \end{matrix}$	4218.387 4218.426	} 4218.392	12.6	uN	${\begin{matrix} + 0.005 \\ - 0.034 \end{matrix}$	} CH—CH	B
					16		16	43	23681.72^*	4221.477	4221.469	12.8		−0.008	CH	P
				16		16		45	23672.66^*	4223.093	4223.091	15.6		−0.002	CH	P
							15	} 45	${\begin{matrix} 23653.77 \\ 23653.58 \end{matrix}$	4226.465	4226.431	52.5	u	−0.034	Fe i	M
					15			} 45	${\begin{matrix} 23653.77 \\ 23653.58 \end{matrix}$	4226.499						A
				15		15		54	23645.54^*	4227.936	4227.944	15.6	s	+ 0.008	CH	P
							14	42	23625.14	4231.587	4231.609	9.7	uN	+ 0.022	CH—Zr ii	B
					14			40	23624.66	4231.673	4231.688	9.7	uN	+ 0.015	CH–Fe i	B
				14		14		63	23617.71^*	4232.919	4232.927	15.1	u	+ 0.008	\|CH—V i?	B
							13	40	23595.95	4236.822	4236.806	12.0	u	−0.016	CH V ii	B

PERMALINK

CH in the Solar Spectrum

Charlotte E Moore

Herbert P Broida

Abstract

Table 1.

Table 10.

Table 5.

Table 2.

Table 11.

Table 6.

Table 3.

Table 4.

Table 7.

Table 8.

Table 9.

Footnotes

References

ACTIONS

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