Abstract
Due to their wide band gaps, III-N materials can exhibit behaviors ranging from the semiconductor class to the dielectric class. Through an analogy between a Metal/AlGaN/AlN/GaN diode and a MOS contact, we make use of this dual nature and show a direct path to capture the energy band diagram of the nitride system. We then apply transparency calculations to describe the forward conduction regime of a III-N heterojunction diode and demonstrate it realizes a tunnel diode, in contrast to its regular Schottky Barrier Diode designation. Thermionic emission is ruled out and instead, a coherent electron tunneling scenario allows to account for transport at room temperature and higher.
Introduction
III-N materials are today at the heart of continuous academic and industrial efforts worldwide. With applications in lighting, radio-frequency or power technologies, Gallium, Indium and Aluminum Nitride alloys offer versatile and outstanding platforms that enable high performance electronics and enhanced solutions in multiple sectors.
Due to its intrinsic properties, GaN is nowadays drawing a lot of attention in the power electronics area as it leads to lower conversion losses at higher frequency compared to Silicon or Silicon Carbide devices. Multiple leading companies have already demonstrated GaN power technologies with extremely promising results1–4, thereby paving the way to new and greener energy converters with a market expected to ramp up in the forthcoming years.
At the core of most of these GaN power devices lies the AlGaN/GaN heterojunction due to its exceptional properties, in particular the existence of a two-dimensional electron gas. Finding its origin in spontaneous and piezoelectric polarization5, it gives rise to a high electron concentration combined with a high electron mobility.
In this work, we propose to draw parallels between an AlGaN/AlN/GaN heterojunction diode and a Metal/Oxide/Semiconductor (MOS) contact by using the duality found in III-N wide band gap materials: semiconductors on the one hand6–8, dielectrics on the other hand9–11, which can depend on their doping and on their electromagnetic environment. With the use of this analogy, we are able to map the energy band diagram at the rectifying contact vicinity in a direct way in order to address the underlying transport mechanisms. By combining the Transfer Matrix formalism12 to compute the system’s transparency and the Tsu-Esaki current formula13, 14, we describe the forward conduction regime of the heterojunction diode with respect to applied voltage and operating temperature.
We show thereby that the III-N heterojunction diode realizes a tunnel diode and rule out thermionic emission, too often incorrectly used to capture such architectures. Through this approach we propose an alternative path of understanding the physics of III-N heterostructures and devices.
MOS analogy
We start by considering an AlGaN/AlN/GaN double heterojunction, a widely used design15–17 where the AlGaN layer is often referred to as the barrier layer, the AlN as the spacer layer and the GaN as the channel layer which contains a Two-Dimensional Electron Gas (2DEG) at the AlN/GaN interface. The system is completed with a surface metal on top of the AlGaN, more specifically Titanium Nitride (TiN). A common approach to studying this system is the use of a Poisson-Schrödinger simulator which allows the derivation of the energy band diagram of the contact and captures the existence of the 2DEG18. We propose here an alternative approach to the problem.
To allow an equivalence between the TiN/AlGaN/AlN/GaN contact and a MOS contact we make two main assumptions. First we assume that the AlGaN and AlN layers are depleted from free carriers, thus allowing to consider purely their dielectric nature and equate them to the gate oxide found within a MOS. Then we assume the GaN channel layer to be a n type semiconductor which will be the stage of an electron accumulation layer as found at the semiconductor/oxide interface of a MOS contact. Figure 1 illustrates this analogy by representing schematically an AlGaN/AlN/GaN diode (b) where the rectifying contact part or anode (b, dotted box) can be mapped on an effective MOS contact (a).
Figure 1.

MOS analogy. (a) Typical MOS contact as found in a Silicon MOS capacitor. (b) AlGaN/AlN/GaN diode half cell separated into two main components: the rectifying contact and the access resistance.
This analogy allows us to employ the main equation used to describe MOS capacitors with a first focus being the derivation of the energy band diagram. We start by considering only the rectifying contact part and express the potential equilibrium as found in a MOS capacitor:
| 1 |
where V is the metal potential (referenced to the bulk GaN supposed grounded), V fb the flat band potential, V ox the potential drop across the oxide and Ψs the surface potential of the semiconductor which translates the amount of band bending in the accumulation layer.
We detail now the different terms of this equation when applied to the Metal/AlGaN/AlN/GaN contact. The flat band potential expresses the difference between the Fermi levels in the metal (TiN) and in the semiconductor (bulk GaN).
| 2 |
where W is the metal’s work function, χ the electron affinity of GaN and (E C − E F) the energy difference between the bottom of the conduction band and the Fermi energy in the bulk GaN.
As far as V ox is concerned, we recall that III-N materials have polar bonds. Within the bulk, the dipoles created by each chemical bond are canceled by the neighboring ones, two by two. However, at a hetero-interface this balance is no longer present and polarization surface charges develop at them. Figure 2(a) illustrates the different interface charges and their polarity present in the case of a Ga-face oriented heterojunction. The effective oxide (AlGaN/AlN) under consideration is therefore natively charged.
Figure 2.
Polarisation charges considerations and related band diagram. (a) GaN/AlN/AlGaN/TiN stack showing the different interface charges (fixed and mobile) found at each heterojunction. (b) Reference structure computed conduction band profile employing the MOS analogy.
By taking into account spontaneous and piezoelectric charges and expressing the continuity of the normal component of the electric field in the structure, the voltage drop across the AlN and AlGaN layers reads:
| 3 |
where σ s denotes the accumulation charge (mobile electrons) per unit area in the GaN accumulation layer and C AlN and C AlGaN denote the equivalent AlN and AlGaN capacitances per unit area respectively. and express the net polarization charges found at the GaN/AlN and AlN/AlGaN interfaces respectively (refer to supplementary information). For each material, the spontaneous contribution is determined following5 and the piezoelectric part is determined following19 by assuming the AlN and the AlGaN to be fully strained on a relaxed GaN layer.
The surface charge density σ s can be related to the surface potential Ψs by solving Poisson’s equation20:
| 4 |
where σ s is taken to be negative when Ψs is positive and vice versa. n 0, p 0 correspond to the electron and hole concentrations in the bulk GaN, N C and N V to the GaN conduction and valence band effective density of states and L D to the Debye length written as:
| 5 |
The F − and F + functions are defined as:
| 6 |
| 7 |
with F 3/2 corresponding to the normalized Fermi-Dirac integral F j(x) with order j = 3/221:
| 8 |
Combining (3) and (4) and injecting the outcome with (2) into (1), one can solve numerically the surface potential Ψs at the GaN/AlN interface, which in turn determines σ s and finally V ox.
To illustrate the procedure, we apply it to the computation of the band diagram of a reference structure and more precisely we focus on the conduction band profile. The main operating and structural parameters used are summarized in Table 1.
Table 1.
Reference structure main parameters.
| Metal voltage (V) | 0 V |
| Temperature | 300 K |
| TiN work function (W) | 4.7 eV49 |
| Al0.25Ga0.75N thickness | 25 nm |
| AlN thickness | 0.5 nm |
| Bulk GaN electron concentration (n 0) | 1e15 cm−3 |
Figure 2(b) illustrates the obtained conduction band profile for the reference TiN/AlGaN/AlN/GaN contact where the conduction band offsets were accounted for following5. Note that the profile of the conduction band from the bulk GaN (at z = −50 A) to the GaN/AlN interface (z = 0 A) is shown for the sake of clarity and was not calculated explicitly. Indeed only the amount of band bending at the surface of the GaN referenced to the bulk, where the position of the Fermi energy is known through n 0, was calculated.
We observe that the existence of the 2D electron gas, or the electron accumulation layer, naturally arises from the calculation and is induced by the strong polarization charges found within the hetero-structure. The extracted sheet carrier density within the accumulation layer is n s = 1e13 cm−2 which agrees well with experimental values reported for similar heterojunctions15, 16.
Practical considerations
Transfer length
III-N heterojunction diodes have been fabricated at CEA-LETI using 200 mm GaN on Silicon wafers grown on site that were processed through a CMOS compatible integration flow. Figure 3(a) shows a close view of the TiN/AlGaN/AlN/GaN contact found on a processed diode which in this case contains a recessed Al0.25Ga0.75N barrier with 6 nm left above the AlN spacer. For the purpose of this study, interdigitated diodes (Fig. 3b) were fabricated with anode length, cathode length and anode to cathode distance all of 15 μm.
Figure 3.

Fabricated heterojunction diode. (a) TEM close view around the anode contact found on a III-N heterojunction diode fabricated at CEA-LETI. Dashed box: TiN/AlGaN/AlN/GaN contact. (b) Upper view of the power diode showing the interdigitated designed used.
Before going into the details of the transport mechanisms entering the on state of the presented diode, we recall a common feature found in contact physics: the transfer length notion. This parameter, often characterized through Transmission Line Measurements (TLM), expresses the length over which a contact, ohmic in the TLM case, is effectively operating. The concept can be extended to nonlinear contacts and corresponding nonlinear transmission lines22. Understand thereby that for heterojunction diodes with sufficiently long anode contacts, the majority of the current is emitted at the anode periphery in the forward regime.
To account for this feature and avoid 2D calculations to reproduce the on state current, we propose a compromise between the regular 1D surface independent current emission (Fig. 4a) and the more complex 2D surface dependent current (Fig. 4b). Figure 4(c) represents the intermediate case we will consider in the following which makes use of an effective anode contact length L eff over which the current is assumed constant. Through this simplification a 1D approach is possible with a reduced contact surface S = 2L eff ω, where ω stands for the anode width.
Figure 4.

Electron flow under the anode contact. (a) 1D standard case, the current is assumed constant over the entire anode length. (b) 2D case, the current varies over the anode length with the majority of the current emitted at the periphery. (c) 1D intermediate case, an effective length is introduced at the edges of the anode and over which the current is assumed constant.
Anode recess impact
As detailed in the previous section, the rectifying contact of the diode under study is realized through a partial recess of the Al0.25Ga0.75N barrier with a targeted thickness of 6 nm left above the AlN spacer. This strategy is common in such architectures and offers the benefit of reducing the turn-on voltage of the diode23–25 allowing more current to be delivered in the on state, a critical feature for end users.
We derive the band diagram of the recessed diode using the same set of parameters as in the reference structure (Table 1) and adjust the AlGaN thickness to 6 nm. The calculated resulting sheet carrier density under the contact is n s = 7.3e12 cm−2. C(V) measurements performed on representative test structures reveal an experimentally smaller value falling in the range 1e12 cm−2 to 3e12 cm−2.
To explain this difference, we turn back to the etching process steps which allow the anode contact recess. The process sequence uses Reactive Ion Etching and comprises the Si3N4 passivation layer opening using Fluorine species (F−) followed by the Al0.25Ga0.75N etching using Chlorine species (Cl−). Fluorine implantation through a similar process was already reported in the AlGaN barrier by coworkers26 and we believe that within the etching condition used, negatively charged ions contaminate the active layers, more precisely the AlGaN left under the TiN metal.
In order to take into consideration ion trapping in the AlGaN, we introduce an effective surface charge at the AlN/AlGaN interface. We modify σ 21 in equation (3) to where σ etch = −0.013 C·m−2 represents a negative surface charge density linked to Fluorine/Chlorine ion implantation. The resulting sheet carrier density becomes n s = 1.8e12 cm−2 which falls into the experimental range.
Tunneling current
Once the conduction band profile is known, the question of the current flowing through the contact can be addressed through the transmission probability of an electron moving from the accumulation layer to the metal. In order to determine this probability through an arbitrary potential barrier, in our case the conduction band profile of the AlN and AlGaN layers, we employ the Transfer Matrix formalism12 which goes beyond the WKB approximation27–29.
The procedure to follow is to discretize the potential barrier into N regions of constant potential (Fig. 5a).
Figure 5.

Electron transmission probability. (a) Arbitrary potential barrier discretization. (b) Transmission probability as a function of energy at V = 200 mV and T = 300 K calculated using the transfer matrix formalism. Inset: Associated recessed anode conduction band profile. (c) Schematic representation of various electron tunneling events accounted for in the recessed anode diode using the Tsu-Esaki formula.
Locally the shape of the electron wave function Φi in region i can be assigned as:
| 9 |
where the wave vector as a function of energy E, potential U i and effective mass m * reads:
| 10 |
Through the continuity of the wave function from the i to the i + 1 region, one can express how it transforms through a local transfer matrix Mi:
| 11 |
| 12 |
By iteration, a product of N matrices leads to the global transfer matrix through the potential barrier. From it, the electron transmission probability T(E) from region i = 0 (accumulation layer) to region i = N + 1 (metal) can be derived as a function of energy:
| 13 |
| 14 |
| 15 |
We show in Fig. 5(b) the calculation of the transmission probability T(E) for the recessed TiN/AlGaN/AlN/GaN contact. The computation is carried out from the bottom of the conduction band in the accumulation layer to a cut-off energy of 2 eV, using a voltage bias of 200 mV at 300 K.
In order to derive the current flow through the contact, we follow the Landauer vision of transport in a mesoscopic system where its quantum resistance is expressed in terms of the transmission and reflection properties of the structure30–33. In the coherent tunneling limit and none-interacting electrons, the current density reads:
| 16 |
where f L and f R represent the equilibrium distribution functions in both reservoirs, indexed L and R, connected to the quantum conductor and T(E, V) denotes the conductor’s transmission probability.
The use of such an approach to mesoscopic transport has proved to be versatile and a powerful tool which has been applied to various systems such as molecular junctions and transistors34–36, carbon nanotubes37, or quantum dots38.
In the case of parallel wave vector conservation and effective masses for each parabolic band of interest, equation (16) can be reduced to the so called Tsu-Esaki current formula13, 14:
| 17 |
where T(E ⊥, V) is the transmission probability at transverse energy, that is to say in the transport direction, and which will be evaluated through the Transfer Matrix formalism. The logarithmic term arises from the assumption that the occupancy functions f L(R) follow the Fermi-Dirac distribution in both leads. The metal (TiN) and the electron accumulation layer (2DEG) are treated here as incoherent reservoirs where temperature dictates the precise shape of these distributions. The summation from the bottom of the conduction band (E 0) at the GaN/AlN interface to a high energy cut-off allows to account for electron emission from the GaN accumulation layer at different energies. Therefore multiple elastic processes, from direct tunneling in the forbidden band gap of the effective oxide (AlN and AlGaN) to thermionic emission over the potential barrier (above the AlN), are taken into consideration which is represented schematically in Fig. 5(c). Within this framework, an electron emitted at energy E from the 2DEG (left Fermi reservoir) tunnels coherently to the contact metal (right Fermi reservoir) where it is absorbed. It is thereby understood that it loses its energy and previous state memory through incoherent relaxation. It should be noted that temperature does not influence the transmission probability itself but governs the kinetic energy of electrons available for transport in both reservoirs.
Application to forward conduction
We focused in the last sections on the rectifying contact part of the lateral diode (Fig. 1b, dotted box). In order to reproduce the I(V) characteristics of the entire device, we also need to take into consideration the access resistance (Fig. 1b dashed box). It comprises mainly of the 2DEG’s resistance in the anode to cathode region in series with the ohmic contact’s resistance which is realized through a high temperature annealing of a Ti/Al stack. We suppose this resistance R to be constant at a given temperature within the voltage bias range we are about to explore. The effect of the access resistance is accounted for by setting the effective voltage drop across the rectifying contact in the right hand side of equation (17) to: V eff = V − RI, V being now the Anode-Cathode voltage bias. The diode’s current density then becomes implicit and needs to be solved at each applied bias. Finally the total current is determined by recalling that I(V) = 2ωL eff J(V) (Fig. 4c), where ω = 26 mm by design.
Before presenting the results of our calculations we recall a widely used empirical formula to reproduce the on state current of several different types of diodes including the studied architecture, the thermionic formula:
| 18 |
where S denotes the rectifying contact surface, A * denotes the modified Richardson constant, Φb the barrier height and η the ideality factor. Figure 6 shows the forward conduction state of the fabricated diode at room temperature fitted via equation (18) at 300 K (a) and 425 K (b). The adjustable parameters extracted from each fit are (Φb = 0.76 eV, η = 2.39, R = 0.21 Ω) at room temperature and (Φb = 0.94 eV, η = 1.91, R = 0.4 Ω) at 425 K using S = 2ωL eff. Although the agreement seems good, such fits miss completely the physics of the device which we are about to show. On the one hand high ideality factors are synonymous of underlying tunnel events39 which thermionic emission does not account for. On the other hand Φb and η need to have strong temperature dependencies in order to capture the evolution of the current, another sign of the irrelevance of such a physical picture in the present case.
Figure 6.

Thermionic fit at various temperatures. (a) Semilog plot of the I(V) on state characteristics of the recessed diode at 300 K fitted using the thermionic formula. Inset: Linear plot showing the ohmic regime above the turn-on voltage. (b) 425 K case.
Figure 7(a) presents the results of the calculations compared to the raw data acquired at 300 K and 425 K. As can be observed, an excellent agreement is met within temperature and over the entire operating voltage range with the current spanning over more than 10 orders of magnitude. Note that the material parameters used are close to the experimental measured and targeted values (Table 2). We emphasize that the only parameter changed with temperature is the access resistance, where the 2DEG mobility is known to be a strong function of temperature due to electron-phonon interaction in particular40. In the present case, R is adjusted to fit the ohmic regime of the diode above the turn-on voltage and is the single free parameter once the calculation is calibrated at a given temperature.
Figure 7.

Calculated tunnel current and related current spectroscopy. (a) Semilog plot of the I(V) characteristics of the recessed diode at 300 K and 425 K reproduced using the model exposed. Inset: Linear plot showing the ohmic regime above the turn-on voltage at both temperatures. (b) Current density per unit area and energy as a function of energy at all voltages at 300 K. E = 0 denotes the Fermi energy in the bulk GaN. (c–e) Calculated conduction band profiles of the rectifying contact at room temperature and for applied biases of 0.5, 1 and 2 V. The shaded area in the accumulation layer represents the main energies contributing to the total current. Note that the contact sees an effective voltage drop of V − RI which is noticeable above the turn-on voltage, that is to say case (e) in the present situation.
Table 2.
Recessed anode diode main parameters.
| TiN work function (W) | 4.7 eV |
| n 0 | 1e15 cm−3 |
| L eff | 3 μm |
| ω | 26 mm |
| AlGaN Al content | 0.25 (0.24 measured) |
| AlGaN thickness | 5.4 nm (5–7 nm measured) |
| AlN thickness | 0.58 nm (1 nm targeted) |
| R | 0.2 Ω (300 K), 0.37 Ω (425 K) |
Figure 7(b) allows us to go deeper into the transport mechanisms involved under and above the turn-on voltage of the recessed diode by providing the current spectroscopy. As can be seen, the majority of the current at all voltages is emitted in an energy band of a few hundred of meV centered near the Fermi level of the GaN layer. By correlating this observation with band diagrams obtained at different voltages (Fig. 7c–e), different conclusions can be drawn. First, within the voltage range explored, electrons never overcome the AlN potential barrier due to its important height, they tunnel directly through it. Second, below the turn-on voltage (Fig. 7c,d) where the current grows exponentially, hardly any electrons are emitted above the AlGaN conduction band near the AlN/AlGaN interface. At best, they tunnel through its band gap over a certain distance before reaching its conduction band minimum further in the layer. Such a mechanism could be approached to Nordheim-Fowler tunneling41. Overall, within the operating voltage and temperature range, no thermionic processes participate to the transport in the forward conduction regime. We infer that the use of the thermionic equation for similar devices as it is commonly done, is bound to return incorrect parameters and lead to misinterpretations.
The derived electronic transport scenario reveals that the recessed TiN/AlGaN/AlN/GaN realizes a tunnel diode with large output currents. More precisely, the formalism employed suggests that this diode is the stage of coherent electron tunneling events at the vicinity of the anode at room temperature and even higher, a property that would be worth investigating more deeply. From a wider perspective than conventional power conversion, we believe that ultra fast operation could be possible using more compact and fine tuned designs in order to achieve rectification at very high frequencies such as in the infrared spectrum42.
Beyond the studied diode design, the sensitivity of electron tunneling to potential barrier heights and thickness raises different questions. First, the removal of the AlN layer would allow higher transparency as far as electrons propagating from the 2DEG to the metal, though it would also imply lower carrier concentration and higher access resistance. Indeed the AlN layer is known to lead to improved sheet resistance in the electron channel due to stronger polarization and enhanced confinement43. A comparable argument could be made as far as the Al content in the AlGaN barrier and in both cases a compromise could be possible. Moreover, the reduction of the AlGaN thickness under the TiN metal would also lead to higher transparency. Through further recessing, the impact on the 2DEG arises. For the extreme case of full recess, the 2DEG is removed below the anode metal and a different type of contact is realized: a lateral Metal/GaN contact24 for which the transport mechanisms would be worth investigating thoroughly. Finally, for thicker barriers (or alternatively shallower recesses) the coherent tunneling picture might break down due to the loss of phase coherence. Indeed, one cannot rule out incoherent scattering processes over longer tunneling distances and more a general tunneling approach might be required to describe a wider variety of heterostructure designs.
Conclusion and Perspectives
Via an analogy with a MOS contact and current calculations based on the Tsu-Esaki formula, a coherent tunneling transport picture could be provided as far as forward conduction is concerned in a III-N heterojunction diode. This result contrasts the common approach involving thermionic emission which can lead to invalid and misleading physical interpretations. We believe that, in essence, the proposed approach which highlights the importance of field effect and takes into account natively electron emission at multiple energies, can be applied to other architectures and materials. As far as III-N heterojunction applications are concerned, we may cite RF or power GaN High Electron Mobility Transistors for which the gate electrostatic control and leakage could be tested on a solid basis. We may also mention III-N LED which involve multiple quantum wells and where transport in the forward regime could be explored more thoroughly.
We emphasize that within the coherent tunneling framework used, questions related to trap assisted events or inelastic tunneling may arise44–48. The good agreement between experimental and calculated data proves that such events do not play an essential role within the device and associated conduction regime explored. Nonetheless pushing the reasoning further to incorporate such effects would provide a larger frame of investigation. Other refinements could be further implemented such as describing the access resistance in better details to capture its temperature variation for example. One may also consider self-heating effects which mainly occur for high current densities and that would open broader voltage ranges to be analyzed. Finally, the energy quantization of the 2DEG, which was treated as a classical incoherent electron reservoir, would be worth evaluating.
Methods
III-N on Silicon growth was realized via MOCVD using a single chamber closed coupled showerhead equipment manufactured by AIXTRON capable of fully automated handling of 200 mm wafers. Au free process integration was carried out using CEA-LETI’s CMOS facilities on the basis of a process flow comprised of approximately 80 technological steps. Electrical characterization was performed by the use of a Tesla 300 mm semi-automatic prober and an Agilent B1505A power device analyzer. All numerical calculations were performed on specifically developed scripts and were double checked using various commercial and open source coding environments.
Data availability
The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.
Electronic supplementary material
Acknowledgements
The authors thank CEA-LETI’s clean room department and technical staff for carrying out multiple process integration steps and in-line control measurements. They also thank S. Bécu for fruitful discussions and comments on the manuscript. This work was performed in the frame of the TOURS 2015 project supported by the french “Programme de l'économie numérique des Investissements d’Avenir”.
Author Contributions
Y.B. and J.Bu. developed the model and performed the numerical calculations. J.Bi. and G.G. supervised process integration with the support of CEA-LETI’s CMOS clean room department. M.C. was in charge of 200 mm GaN on Silicon wafer growth via MOCVD. W.V. performed power diodes electrical characterization. C.G. and M.P. led the entire power diode project. All authors discussed the results and commented on the manuscript.
Competing Interests
The authors declare that they have no competing interests.
Footnotes
Electronic supplementary material
Supplementary information accompanies this paper at doi:10.1038/s41598-017-08307-0
Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
References
- 1.Kaneko, S. et al. Current-collapse-free operations up to 850v by gan-git utilizing hole injection from drain. 2015 IEEE 27th International Symposium on Power Semiconductor Devices IC’s (ISPSD), 41–44, doi:10.1109/ISPSD.2015.7123384 (2015).
- 2.Moens, P. et al. An industrial process for 650v rated gan-on-si power devices using in-situ sin as a gate dielectric. 2014 IEEE 26th International Symposium on Power Semiconductor Devices IC’s (ISPSD), 374–377, doi:10.1109/ISPSD.2014.6856054 (2014).
- 3.Kim, J. et al. High threshold voltage p-gan gate power devices on 200 mm si. 2013 25th International Symposium on Power Semiconductor Devices IC’s (ISPSD), 315–318, doi:10.1109/ISPSD.2013.6694412 (2013).
- 4.Jones EA, Wang FF, Costinett D. Review of commercial gan power devices and gan-based converter design challenges. IEEE Journal of Emerging and Selected Topics in Power Electronics. 2016;4:707–719. doi: 10.1109/JESTPE.2016.2582685. [DOI] [Google Scholar]
- 5.Ambacher O, et al. Two-dimensional electron gases induced by spontaneous and piezoelectric polarization charges in n- and ga-face algan/gan heterostructures. Journal of Applied Physics. 1999;85:3222–3233. doi: 10.1063/1.369664. [DOI] [Google Scholar]
- 6.Huang, W., Khan, T. & Chow, T. P. Enhancement-mode n-channel gan mosfets on p and n-gan/sapphire substrates. 2006 IEEE International Symposium on Power Semiconductor Devices and IC’s, 1–4, doi:10.1109/ISPSD.2006.1666133 (2006).
- 7.Yoshizumi Y, Hashimoto S, Tanabe T, Kiyama M. High-breakdown-voltage pn-junction diodes on gan substrates. Journal of Crystal Growth. 2007;298:875–878. doi: 10.1016/j.jcrysgro.2006.10.246. [DOI] [Google Scholar]
- 8.Kizilyalli IC, et al. 3.7 kv vertical gan pn diodes. IEEE Electron Device Letters. 2014;35:247–249. doi: 10.1109/LED.2013.2294175. [DOI] [Google Scholar]
- 9.Moens, P. et al. Impact of buffer leakage on intrinsic reliability of 650v algan/gan hemts. 2015 IEEE International Electron Devices Meeting (IEDM), 35.2.1–35.2.4, doi:10.1109/IEDM.2015.7409831 (2015).
- 10.Moereke J, et al. Leakage current paths in isolated algan/gan heterostructures. IEEE Transactions on Semiconductor Manufacturing. 2016;29:363–369. doi: 10.1109/TSM.2016.2598179. [DOI] [Google Scholar]
- 11.Selvaraj, S. L., Ito, T., Terada, Y. & Egawa, T. Aln/algan/gan metal-insulator-semiconductor high-electron-mobility transistor on 4in. silicon substrate for high breakdown characteristics. Applied Physics Letters90, doi:10.1063/1.2730751 (2007).
- 12.Ando Y, Itoh T. Calculation of transmission tunneling current across arbitrary potential barriers. Journal of Applied Physics. 1987;61:1497–1502. doi: 10.1063/1.338082. [DOI] [Google Scholar]
- 13.Duke, C. B. Tunneling in Solids (Academic, New York, 1969).
- 14.Tsu R, Esaki L. Tunneling in a finite superlattice. Applied Physics Letters. 1973;22:562–564. doi: 10.1063/1.1654509. [DOI] [Google Scholar]
- 15.Wang X, et al. Algan/aln/gan/sic HEMT structure with high mobility gan thin layer as channel grown by MOCVD. Journal of Crystal Growth. 2007;298:835–839. doi: 10.1016/j.jcrysgro.2006.10.219. [DOI] [Google Scholar]
- 16.Shen L, et al. Algan/aln/gan high-power microwave hemt. IEEE Electron Device Letters. 2001;22:457–459. doi: 10.1109/55.954910. [DOI] [Google Scholar]
- 17.Ohmaki Y, Tanimoto M, Akamatsu S, Mukai T. Enhancement-mode algan/aln/gan high electron mobility transistor with low on-state resistance and high breakdown voltage. Japanese Journal of Applied Physics. 2006;45:L1168. doi: 10.1143/JJAP.45.L1168. [DOI] [Google Scholar]
- 18.Zhang K, et al. Low al-composition p-gan/mg-doped al0.25ga0.75n/n+-gan polarization-induced backward tunneling junction grown by metal-organic chemical vapor deposition on sapphire substrate. Scientific Reports. 2014;4:6322. doi: 10.1038/srep06322. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 19.Siklitsky, V. Physical Properties of Semiconductors. http://www.ioffe.ru/SVA/NSM/Semicond/ (1998).
- 20.Seiwatz R, Green M. Space charge calculations for semiconductors. Journal of Applied Physics. 1958;29:1034–1040. doi: 10.1063/1.1723358. [DOI] [Google Scholar]
- 21.Aymerich-Humet X, Serra-Mestres F, Millán J. A generalized approximation of the fermi–dirac integrals. Journal of Applied Physics. 1983;54:2850–2851. doi: 10.1063/1.332276. [DOI] [Google Scholar]
- 22.Piotrzkowski R, Litwin-Staszewska E, Grzanka S. Towards proper characterization of nonlinear metal-semiconductor contacts. generalization of the transmission line method. Applied Physics Letters. 2011;99:052101. doi: 10.1063/1.3619813. [DOI] [Google Scholar]
- 23.Bahat-Treidel E, et al. Fast-switching gan-based lateral power schottky barrier diodes with low onset voltage and strong reverse blocking. IEEE Electron Device Letters. 2012;33:357–359. doi: 10.1109/LED.2011.2179281. [DOI] [Google Scholar]
- 24.Zhu M, et al. 1.9-kv algan/gan lateral schottky barrier diodes on silicon. IEEE Electron Device Letters. 2015;36:375–377. doi: 10.1109/LED.2015.2404309. [DOI] [Google Scholar]
- 25.Hu J, et al. Leakage-current reduction and improved on-state performance of au-free algan/gan-on-si schottky diode by embedding the edge terminations in the anode region. Physica status solidi (c) 2014;11:862–865. doi: 10.1002/pssc.201300472. [DOI] [Google Scholar]
- 26.Lehmann, J. et al. Influence of epitaxy and gate deposition process on ron resistance of algan/gan-on-si hemt. In 2015 IEEE 27th International Symposium on Power Semiconductor Devices IC’s (ISPSD), 261–264, doi:10.1109/ISPSD.2015.7123439 (2015).
- 27.Wentzel G. Eine verallgemeinerung der quantenbedingungen für die zwecke der wellenmechanik. Zeitschrift für Physik. 1926;38:518–529. doi: 10.1007/BF01397171. [DOI] [Google Scholar]
- 28.Kramers HA. Wellenmechanik und halbzahlige quantisierung. Zeitschrift für Physik. 1926;39:828–840. doi: 10.1007/BF01451751. [DOI] [Google Scholar]
- 29.Brillouin L. The undulatory mechanics of schrödinger. Compt. Rend. Acad. Sci. 1926;183:24–26. [Google Scholar]
- 30.Landauer R. Electrical resistance of disordered one-dimensional lattices. Philosophical Magazine. 1970;21:863–867. doi: 10.1080/14786437008238472. [DOI] [Google Scholar]
- 31.Lenstra D, Smokers RTM. Theory of nonlinear quantum tunneling resistance in one-dimensional disordered systems. Phys. Rev. B. 1988;38:6452–6460. doi: 10.1103/PhysRevB.38.6452. [DOI] [PubMed] [Google Scholar]
- 32.Meir Y, Wingreen NS. Landauer formula for the current through an interacting electron region. Phys. Rev. Lett. 1992;68:2512–2515. doi: 10.1103/PhysRevLett.68.2512. [DOI] [PubMed] [Google Scholar]
- 33.Jauho A-P, Wingreen NS, Meir Y. Time-dependent transport in interacting and noninteracting resonant-tunneling systems. Phys. Rev. B. 1994;50:5528–5544. doi: 10.1103/PhysRevB.50.5528. [DOI] [PubMed] [Google Scholar]
- 34.Solomon GC, Herrmann C, Hansen T, Mujica V, Ratner MA. Exploring local currents in molecular junctions. Nat Chem. 2010;2:223–228. doi: 10.1038/nchem.546. [DOI] [PubMed] [Google Scholar]
- 35.Guedon CM, et al. Observation of quantum interference in molecular charge transport. Nat Nano. 2012;7:305–309. doi: 10.1038/nnano.2012.37. [DOI] [PubMed] [Google Scholar]
- 36.Li Y, Mol JA, Benjamin SC, Briggs GAD. Interference-based molecular transistors. Scientific Reports. 2016;6:33686. doi: 10.1038/srep33686. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 37.Wu F, et al. Shot noise with interaction effects in single-walled carbon nanotubes. Phys. Rev. Lett. 2007;99:156803. doi: 10.1103/PhysRevLett.99.156803. [DOI] [PubMed] [Google Scholar]
- 38.Baines DY, et al. Transport through side-coupled double quantum dots: From weak to strong interdot coupling. Phys. Rev. B. 2012;85:195117. doi: 10.1103/PhysRevB.85.195117. [DOI] [Google Scholar]
- 39.Sze, S. M. & Ng, K. K. Physics of Semiconductor Devices (Wiley-Blackwell, 2006).
- 40.Lisesivdin, S. B. et al. Scattering analysis of two-dimensional electrons in algan/gan with bulk related parameters extracted by simple parallel conduction extraction method. Journal of Applied Physics108, doi:10.1063/1.3456008 (2010).
- 41.Fowler RH, Nordheim L. Electron emission in intense electric fields. Proceedings of the Royal Society of London A: Mathematical, Physical and Engineering Sciences. 1928;119:173–181. doi: 10.1098/rspa.1928.0091. [DOI] [Google Scholar]
- 42.Davids PS, et al. Infrared rectification in a nanoantenna-coupled metal-oxide-semiconductor tunnel diode. Nat Nano. 2015;10:1033–1038. doi: 10.1038/nnano.2015.216. [DOI] [PubMed] [Google Scholar]
- 43.Smorchkova IP, et al. Aln/gan and (al,ga)n/aln/gan two-dimensional electron gas structures grown by plasma-assisted molecular-beam epitaxy. Journal of Applied Physics. 2001;90:5196–5201. doi: 10.1063/1.1412273. [DOI] [Google Scholar]
- 44.Hill RM. Poole-frenkel conduction in amorphous solids. Philosophical Magazine. 1971;23:59–86. doi: 10.1080/14786437108216365. [DOI] [Google Scholar]
- 45.Mott NF. Conduction in non-crystalline materials. Philosophical Magazine. 1969;19:835–852. doi: 10.1080/14786436908216338. [DOI] [Google Scholar]
- 46.Ghetti, A., Hamad, A., Silverman, P. J., Vaidya, H. & Zhao, N. Self-consistent simulation of quantization effects and tunneling current in ultra-thin gate oxide mos devices. Simulation of Semiconductor Processes and Devices, 1999. SISPAD’99. 1999 International Conference on, 239–242, doi:10.1109/SISPAD.1999.799305 (1999).
- 47.Suzuki E, Schroder DK, Hayashi Y. Carrier conduction in ultrathin nitrided oxide films. Journal of Applied Physics. 1986;60:3616–3621. doi: 10.1063/1.337568. [DOI] [Google Scholar]
- 48.Takagi S, Yasuda N, Toriumi A. A new i–v model for stress-induced leakage current including inelastic tunneling. IEEE Transactions on Electron Devices. 1999;46:348–354. doi: 10.1109/16.740901. [DOI] [Google Scholar]
- 49.Li L, et al. Gan schottky barrier diode with tin electrode for microwave rectification. IEEE Journal of the Electron Devices Society. 2014;2:168–173. doi: 10.1109/JEDS.2014.2346395. [DOI] [Google Scholar]
Associated Data
This section collects any data citations, data availability statements, or supplementary materials included in this article.
Supplementary Materials
Data Availability Statement
The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

