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. 2017 May 23;23(33):8014–8024. doi: 10.1002/chem.201700793

Figure 12.

Figure 12

Proposed mechanism for transfer of saturation in STD NMR experiments performed with supramolecular hydrogels. Gelator molecules forming the network (bound state, left) are in fast exchange with those in the bulk solution phase (free state, right), allowing accumulation and detection of saturation in solution.