. 2017 Dec 6;9(12):1328. doi: 10.3390/nu9121328

Table 1.

Flavanone compounds in bergamot juice.

Id.	Compounds	RT (min)	[M − H]⁻ (m/z)	MS² Ion Fragments (m/z) ^a	MS³ Ion Fragments (m/z) ^a	Ident. ^c	Concentration (μmol/g dw)
1	Eriodictyol-7-O-rutinoside (eriocitrin)	9.5	595	287 ^b	151	[34]	2.30 ± 0.22
2	Eriodictyol-7-O-neohesperidoside (neoeriocitrin)	9.71	595	459, 287, 235	235, 357, 441, 271, 151	[34]	7.83 ± 0.85
3	Naringenin-7-O-rutinoside (narirutin)	10.19	579	271	151, 177	Std	1.06 ± 0.05
4	Hesperetin-7-O-rutinoside (hesperidin)	10.2	609	301	286, 242, 283, 257, 125	Std	2.10 ± 0.22
5	Naringenin-7-O-neohesperidoside (naringin)	10.4	579	459, 271, 235	357, 235, 271, 441, 339	[38]	12.46 ± 1.61
6	Eriodictyol-7-O-neohesperidoside-6″-O-HMG	10.57	739	595, 637, 677	459, 287	[35]	7.53 ± 0.76
7	Hesperetin-7-O-neohesperidoside (neohesperidin)	10.79	609	301, 343, 489, 447	286, 242, 283, 257, 125	[34]	10.31 ± 0.61
8	Naringenin-7-O-neohesperidoside-6″-O-HMG (melitidin)	11.13	723	579, 621, 661	459, 271, 313	[34]	8.25 ± 0.93
9	Naringenin-7-O-glucoside-6″-O-HMG	11.39	577	271, 433, 475	151, 177	[35]	0.27 ± 0.03
10	Hesperetin-7-O-neohesperidoside-6″-O-HMG (brutieridin)	11.43	753	609, 651, 691	301, 343, 489	[34]	19.70 ± 2.04
11	Isosakuranetin-7-O-rutinoside (didymin)	12.25	593	285, 327, 473	270, 243, 164, 241, 151	Std	0.26 ± 0.02
12	Isosakuranetin-7-O-neohesperidoside-6″-O-HMG (parmigin)	12.75	737	593, 635, 675	285 (MS⁴: 270, 243), 327, 473	-	0.99 ± 0.03
13	Naringenin	13.32	271	151, 177		Std	traces
14	Isosakuranetin	13.57	285	270, 243		Std	traces
15	Hesperetin	13.78	301	286, 242		Std	traces
16	Eriodyctiol	13.82	287	151		[38]	traces

^a Fragment ions are listed in order of relative abundance; ^b MS ions in bold were those subjected to successive MS fragmentation; ^c Ident., identification mode: [Reference] or Std (standard, compound identified by comparison of its retention time and MS data with that of a reference compound). Mean (n = 3) ± SD. RT, retention time.