Table 1. Calculated and Observed Activation Barriers (kcal/mol) for Different Systems.
System | ΔG‡ (cal) | ΔG‡ (obs) |
---|---|---|
I | 20.2 | 19.8 |
II | 25.6 | - |
III | 27.3 | - |
IV | 32.6 | - |
V | 37.6 | - |
System | ΔG‡ (cal) | ΔG‡ (obs) |
---|---|---|
I | 20.2 | 19.8 |
II | 25.6 | - |
III | 27.3 | - |
IV | 32.6 | - |
V | 37.6 | - |