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. 2018 Feb 7;140(7):2700. doi: 10.1021/jacs.7b08973

Retraction of “Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene”

Yam N Timsina, Souvagya Biswas, T V RajanBabu
PMCID: PMC5839601  PMID: 29409319

The authors retract this Communication because one of the major conclusions of the work [the (E) to (Z) isomerization of a 1,3-diene] is wrong and resulted from a misinterpretation of the experimental results. We found that under the ethylene-free reaction conditions certain Co-catalysts, in a highly selective reaction, consume only the (E)-isomer from a mixture of geometrical isomers to give higher molecular weight oligomers leaving behind the pure (Z)-isomer. The oligomers were not detected in our characterization, which resulted in a wrong conclusion that the (E) isomer was converted into the (Z) isomer.

The original paper was published on April 8, 2014 and was retracted on February 7, 2018.


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