Hexagonal MoTe₂ with Amorphous BN Passivation Layer for Improved Oxidation Resistance and Endurance of 2D Field Effect Transistors

Abstract

Environmental and thermal stability of two-dimensional (2D) transition metal dichalcogenides (TMDs) remains a fundamental challenge towards enabling robust electronic devices. Few-layer 2H-MoTe₂ with an amorphous boron nitride (a-BN) covering layer was synthesized as a channel for back-gated field effect transistors (FET) and compared to uncovered MoTe₂. A systematic approach was taken to understand the effects of heat treatment in air on the performance of FET devices. Atmospheric oxygen was shown to negatively affect uncoated MoTe₂ devices while BN-covered FETs showed considerably enhanced chemical and electronic characteristic stability. Uncapped MoTe₂ FET devices, which were heated in air for one minute, showed a polarity switch from n- to p-type at 150 °C, while BN-MoTe₂ devices switched only after 200 °C of heat treatment. Time-dependent experiments at 100 °C showed that uncapped MoTe₂ samples exhibited the polarity switch after 15 min of heat treatment while the BN-capped device maintained its n-type conductivity for the maximum 60 min duration of the experiment. X-ray photoelectron spectroscopy (XPS) analysis suggests that oxygen incorporation into MoTe₂ was the primary doping mechanism for the polarity switch. This work demonstrates the effectiveness of an a-BN capping layer in preserving few-layer MoTe₂ material quality and controlling its conductivity type at elevated temperatures in an atmospheric environment.

Introduction

Recent advances in the field of 2D materials have focused on molecular-thin, TMDs as semiconductor counterparts to graphene in the use of nanoscale electronics^1–5. One such TMD is MoTe₂, which offers a unique combination of a semiconductor (hexagonal 2 H polytype) to metal (trigonal 1 T′ polytype) phase transition, indirect-to-direct bandgap transition in low-dimensional limits, spin-orbit coupling, strong photoluminescence response, and high transistor on/off ratios^6–9. Monolayer 2H-MoTe₂ has a direct band gap of 1.10 eV, which transitions to an indirect band gap of 0.81 eV for bulk MoTe₂ as the layer number increases¹⁰. The charge carrier quantum confinement, high mobility, and reduced interaction with adjusted layers due to a lack of dangling surface bonds has initiated an extensive number of studies regarding monolayer TMDs for electrical and optoelectronic devices. In this respect, field effect transistors made of 2D MoTe₂ have been demonstrated to exhibit p-type^11,12, n-type¹³, and ambipolar¹⁴ behavior. MoTe₂ FETs have been reported to have on/off ratios above 10⁶, subthreshold swing of 140 mV/dec, and Hall mobilities around 10 cm² (V s)^−1 11. Such properties with an interesting ability for ambipolar behavior suggest monolayer 2H-MoTe₂ can be attractive for semiconducting devices as compared to other 2D TMDs.

A major hindrance of many 2D TMDs is their limited stability in air, especially when they are subjected to moderate heating during processing or device operation. While the perfect TMD monolayers are relatively stable, the presence of defects, such as point defects and edges of single crystal domains, play a decisive role in determining the stability of 2D TMDs when exposed to an oxidizing environment. Oxygen substitution of chalcogen atoms and oxidation along the crystal edges are the most commonly reported culprits for the deterioration of charge confinement and transport characteristics of 2D TMDs^15,16. From this perspective, the packaging of 2D TMDs layers within electrically insulating and dielectric (for FET applications) thin layers, which can also prevent oxidation and deterioration of 2D TMD characteristics, is of a significant practical interest to advance 2D TMDs for device applications. The challenge of such passivation layers is in avoiding interaction of the 2D TMD layers with the adjusted electrically insulating materials, where typical thin dielectrics are mostly based on oxides (e. g., SiO₂, Al₂O₃, HfO₂), which intrinsically bring oxygen atoms in contact with TMDs and can contribute to TMD deterioration. This becomes especially prevalent if elevated temperatures are encountered during dielectric layer deposition or device operation. Thus, an exploration of a non-oxide based and environmentally stable dielectric material to be used in conjunction with TMD FET devices, or other 2D materials such as graphene and black phosphorus, and would benefit the wider usage of such materials.

Boron nitride has emerged as a dielectric counterpart to TMDs due to its chemical stability, lack of dangling bonds, and wide bandgap (5.97 eV) characteristics¹⁷. Most notably, hexagonal boron nitride (h-BN), which has a similar crystal structure to graphene¹⁸, can be exfoliated onto various 2D materials to form heterostructures such as h-BN-MoS₂^19–21, h-BN-WS₂²², h-BN-MoSe₂²³, and BN-WSe₂-BN²⁴ with remarkable electrical properties²⁵. While these studies clearly demonstrate the benefit of h-BN packaging with TMD for improved mobility, on/off ratio, and thermal management, the challenge of exfoliation routes for such 2D heterostructure device assemblies is prohibitive for the scalable and cost-effective device production, leading to the search of alternative routes for h-BN synthesis and integration with TMD structures¹⁸. Deposition of h-BN layers via chemical vapor deposition routes have been extensively explored but require high temperatures during synthesis and annealing^26–29, reducing applicability for temperature sensitive TMDs.

Most recently, research involved in physical vapor deposition (PVD) of BN thin films has demonstrated the advantage of room temperature growth of amorphous BN (a-BN) layers on the order of 2 nm to 3 nm thickness over large areas, which show a bandgap of 4.5 eV, dielectric constant of about 6 and breakdown voltage on the order of 10 MV/cm^30,31. This makes them comparable to exfoliated h-BN for dielectric applications. Passivation layers of PVD-grown a-BN in combination with graphene³², 2D WS₂ and MoS₂³³, have shown improved field effect mobility and reduced background charge carrier concentration. Herein, we investigate devices composed of exfoliated 2 H MoTe₂ with a PVD-grown a-BN passivation layer to study chemical and structural stability of 2D MoTe₂ at elevated temperatures. The studies also include an analysis of FET device performance (including n- to p-type behavior transition, on/off ratio, and carrier mobility) after heating in air, covering a possible range of temperatures of such 2H-MoTe₂/a-BN device applications in electronic devices. Formation of Te vacancy sites and the potential for atmospheric oxygen to form substitutional dopants were of critical attention in the performed study. We find this BN capping layer to be an effective barrier layer, which protects the 2D TMD material from detrimental chemical oxidation, and significantly reduces the rate of field effect mobility and on/off ratio degradation of FET devices as compared to the uncapped sample.

Results and Discussion

Material exfoliated and characterization

Figure 1a depicts an optical image of an exfoliated 2H-MoTe₂ flake. The optical contrast of few layers and bulk flakes on SiO₂/Si substrates provides a good guide to the flake thickness, since it is known that 2D flakes that contain one to few layers show a darker optical color than bulk material due to altering optical contrast with the SiO₂/Si substrate³⁴. AFM from a non-contact scan is shown in Fig. 1b, demonstrating good thickness uniformity of the dark-green area from Fig. 1a. A line scan measures a height difference of 2.30 nm, which corresponds to tri-layer MoTe₂³⁵. The Raman spectrum in Fig. 1c, clearly shows three distinct peaks typical for MoTe₂ at 170 cm⁻¹, 235 cm⁻¹ and 289 cm⁻¹, corresponding to the A_1g, E¹_2g and B_2g phonon modes, respectively³⁶. The A_1g mode is due to out-of-plane phonon vibrations and is typically weak for 532 nm laser excitations³⁷. The E¹_2g peak is the dominant mode and corresponds to in-plane atomic oscillations, and it has been shown to exhibit a strong signal for MoTe₂ in the 2D form and is relatively weak for bulk material³⁶. The B_2g mode corresponds to the out-of-plane interaction of adjacent layers and has an interesting property in which it is clearly present for 2 to 5 of MoTe₂ layers but absent for either monolayer or the bulk thickness. This peak was reported to have its strongest value for 2 layers and rapidly decreasing as the thickness increases until it disappears after 5 layers³⁴. Therefore, the relative intensities of the E¹_2g and B_2g peaks can be used to determine layer thickness and verify AFM measurements as presented in Fig. 1b. For all MoTe₂ flakes selected for this study, the Raman spectra displayed a strong E¹_2g peak and less intense A_1g and B_2g peaks, which is in agreement with 3-layer thickness measurements with AFM (Fig. 1c).

Figure 1.

(a) An optical image of an MoTe₂ exfoliated flake on SiO₂/Si substrate: the few-layer section can be identified by the dark green color while the bulk is a lighter blue-green. (b) AFM image and line scan (dashed black line) from the few-layer section of flake in 1a: the height profile from the line scan measures a difference of 2.30 nm, which corresponds to 3 monolayers of MoTe₂. (c) The Raman spectrum from MoTe₂ flake, which is in agreement with few-layer MoTe₂.

In order to analyze the 2D MoTe₂ thermal degradation rate over time, Raman spectra comparing the 2H-MoTe₂ E¹_2g mode for samples heated at 100 °C for up to 60 min with 10 min increment were collected and are shown in Fig. 2a. Gauss peak fitting of the E¹_2g mode had determined that this vibration mode maintains its location at ≈234 cm⁻¹ throughout the experiment, which suggests the 2H-MoTe₂ did not undergo a thickness change after 60 min of 100 °C heat treatment in air. However, the E¹_2g peak exhibits a continuous intensity decline from its max value at room temperature, and the rate of this decline is strongly affected by the presence of the BN cap layer. The Raman analysis did not show the presence of MoO₃ or MoO₂ vibration modes for both uncapped and a-BN capped 2H-MoTe₂ flakes, suggesting that no individual phases of molybdenum oxide crystal structure was formed. However, XPS analysis discussed below shows that heating in air had resulted in surface oxidation. Normalizing the E¹_2g peaks to the Raman peak of silicon at 520 cm⁻¹ allows for comparison between uncapped and BN capped flakes. Figure 2b clearly shows that the uncapped MoTe₂ exhibits a much greater rate of decay of the E¹_2g Raman mode. Such is likely brought by damping the inter-layer oscillation modes with increased lattice imperfections and internal atomic stresses from Te vacancies and oxygen substitutions. In contrast, normalized Raman spectra of the BN-capped MoTe₂ sample maintained its E¹_2g peak intensity after 60 min of heating, see Supplementary data Figure S1. Applying a linear fit to the data, the slopes of the fitting lines suggest that the decay rate for the E¹_2g mode in 2H-MoTe₂ material with 100 °C exposure time is an order of magnitude higher than that for the 2H-MoTe₂/a-BN, (8.3 × 10⁻³ min⁻¹ versus 8.1 × 10⁻⁴ min⁻¹, respectively). The results clearly demonstrated the benefit of the BN capping layer for the preservation of 2H-MoTe₂ structure at elevated temperatures in air.

Figure 2.

(a) Raman spectra of the E¹_2g peak intensity variation for few monolayers thick 2H-MoTe₂ flakes exposed to 100 °C in air for the shown time intervals. (b) Comparison of E¹_2g peak intensities changes as a function of 100 °C in air holding time for uncapped MoTe₂ and BN-capped MoTe₂ flakes; to facilitate the comparisons and avoid errors due to absolute peak intensity changes over time, the peak intensity was normalized to the Si substrate peak (520.5 cm⁻¹). The shown linear fitting was used to calculate E¹_2g peak intensity decline due to oxidation processes for 2H-MoTe₂ and 2H-MoTe₂/a-BN.

In order to investigate in more detail, the chemical state changes of MoTe₂ after exposure to elevated temperatures in air, XPS analysis was conducted on exfoliated flakes with and without BN layers after heating at 100 °C for 60 min. The results are presented in Fig. 3, and XPS spectra of MoTe₂ flakes before heating can be found in Supplemental Figure S2. The uncoated MoTe₂ flake shows three distinct peaks for the Mo 3d orbital, which can be seen in the top spectrum of Fig. 3a. The recorded spectra deconvolutions with 3d doublets reveal a clear presence of two chemical states with Mo 3d_3/2 peak locations at 234.6 eV and 231.5 eV. The higher binding energy doublet belongs to Mo⁶⁺ in MoO₃ bonding, and the lower one to Mo⁴⁺ in MoTe₂³⁸. This suggests partial oxidation of the MoTe₂ surface. In a sharp contrast, similar analysis of the MoTe₂/BN sample after 60 min exposure to 100 °C in air shows only one doublet with Mo 3d_3/2 peak location at 231.4 eV, indicating the absence of molybdenum oxidation when the BN capping layer was applied. Similar observation of the BN-capping layer preventing oxidation can be made from corresponding XPS spectra of Te 3d, shown in Fig. 3b. The un-capped MoTe₂ (upper spectrum) has dominant Te-O peaks at 575.92 eV and 586.42 eV, corresponding to TeO₂ formation. On the other hand, the BN-capped (lower spectrum) sample has dominant peaks at 572.9 eV and 583.4 eV and significantly weaker Te-O peaks at 576.3 eV and 586.8 eV. This suggests that heating of the uncapped MoTe₂ in air results in possible oxidation as evidenced by the appearance of Mo-O and Te-O bonds in the XPS spectra. This process was significantly suppressed for the MoTe₂/BN sample. The XPS analysis corroborate the Raman studies that the application of the 10 nm thin BN layer can effectively resist oxidation of MoTe₂ at elevated temperatures in air.

Figure 3.

XPS analysis of the (a) Mo 3d and (b) Te 3d binding energies for 2H-MoTe₂ and 2H-MoTe₂/a-BN flakes after 60 minutes of 100 °C heating. The BN-capped sample maintains its Mo-Te bonding, demonstrating increased resistance to oxidation, while the appearance of Mo-O and Te-O bonds in the uncapped device suggests significant oxidation of MoTe₂ to form MoO₃ and TeO₂ phases.

Electrical Measurements of Uncapped and BN-capped devices

To determine the effect of an a-BN capping layer on the retaining charge transport characteristics and MoTe₂ based FET device performance upon exposure to elevated temperature in air back-gated FET devices were fabricated from few-layer thick MoTe₂ flakes on SiO₂ using electron beam lithography. This amorphous BN layer was previously determined to be pin-hole free dielectric material with breakdown characteristic and dielectric constant exceeding CVD grown h-BN films, approaching that of mechanically exfoliated h-BN^30,31. Such deposition method is ideal for a cost-effective application of dielectric BN layer for 2D heterostructures as compared with other 2D BN growth methods²⁶. In the recent studies of PLD grown amorphous BN it was found that the dielectric properties were close to that of h-BN and be as smooth as underlying substrates, where graphene, MoS₂, WS₂ and a variety of metal and ceramic substrates were tested with an equal result in a-BN smoothness and pin-hole free morphology over several cm² areas^30,31,39. While there were no systematic studies to determine a-BN inertness, the earlier explorations with a-BN/graphene heterostructures had shown a significant increase of mobility in graphene monolayers when it was sandwiched with a-BN, relating this to a-BN inertness, similar to monolayer thin h-BN³². Stabilization of charge transport characteristics of epitaxially grown graphene in air by the application of a capping a-BN layer was also reported^40,41. We then reasonably expected a similar effect with MoTe₂ devices, and such is explored for the first time in this study at elevated temperatures in air. Back-gated FET device schematic made from MoTe₂ and including a BN capping layer is depicted in Fig. 4a and an example of such fabricated device is shown in an optical image of Fig. 4b.

Figure 4.

(a) Schematic cross-section of FET back-gated device with BN capped MoTe₂. (b) Optical image of typical MoTe₂ few-layer flake with Ti/Au source drain contacts deposited by EBL. (c) Examples of drain current measurements as a function of gate voltage for a backdated MoTe₂ device. The drain voltage was maintained at 1 VDC. Uncovered MoTe₂ device shows initial n-type semiconducting behavior that switches to p-type after 150 °C. (d) The BN/MoTe₂ device maintains a much greater degree of stability through 100 °C and exhibits a polarity switch to p-type behavior much later at 200 °C.

Electrical performance of back-gated FET devices annealed from room temperature to 300 °C is shown in Fig. 4. MoTe₂/BN and MoTe₂ as-exfoliated devices underwent the side by side elevated temperature in air exposure and were held for 1 min at the target temperature in atmospheric conditions before cooling down and measuring their performance. Figure 4c presents a semi-log plot of drain current (I_dc) versus gate voltage (V_g) for a MoTe₂ device as the annealing temperature was systematically increased from room temperature to 300 °C at 50 °C increments. The device initially exhibits n-type behavior as indicated by the positive slope, with the maximum current decreasing slightly as the temperature is increased to 100 °C. At 150 °C (pink curve) the polarity switches to p-type behavior as indicated by the negative slope. At 200 °C, the device operates as a p-type but also exhibits semi-metallic behavior as indicated by the linear slope. For few-layer materials, this temperature is sufficient to sublime Te directly into the vapor state, leaving behind Mo atoms which would contribute to metallic properties.

A semi-log I_dc - V_g plot for a MoTe₂/BN device is presented in Fig. 4d. The drain current curve remains very stable up to 100 °C. At 150 °C there is a sharp decline in current, however the device remains n-type, as indicated by the drain current curve slope for positive gate voltages. However, after heat treatment at 200 °C, the drain current switches to negative gate voltages and decreases for positive gate voltages, indicating a switch to p-type semiconductor operation. Once temperatures reached 250 °C we noticed the channel lost semiconductor properties and was unresponsive to gate voltage variation, which suggests degradation of MoTe₂. At 300 °C, the Ti/Au contacts themselves failed and further temperature increase was not performed. Scanning electron microscopy studies of the contacts had shown dewetting of these thin metal films (Supplementary data Figure S3), resulting in a failure of conductive pathways. Such dewetting is expected for thin electrode materials due to the low melting point of gold, and experiments at higher temperatures may require other electrode materials.

Field effect mobility was calculated from the I_dc - V_g curves and is shown at various annealing temperatures in Table 1. Before performing any temperature exposure, the measurements of as fabricated devices (23 °C in Table 1) clearly indicate that the capping MoTe₂ with BN has a significant effect on the mobility improvement as the measured values for MoTe₂/BN devices were five times greater than that of uncapped MoTe₂. The absolute values of the room temperature mobility measurements in the literature vary between 0.03 and 20 cm²V⁻¹s^{−1,11,12,14,42,43}. While our results are within this reported range, our study demonstrates the effect of a-BN capping layer on the device stability during heating as discussed below.

Table 1.

Mobility of uncapped (MoTe₂) and BN-capped (BN/MoTe₂) devices as a function of temperature with carrier type.

	23 °C	50 °C	100 °C	150 °C	200 °C
MoTe2/BN	1.077, n-type	0.870, n-type	0.837, n-type	0.204, n-type	0.442, p-type
MoTe2	0.235, n-type	0.157, n-type	0.103, n-type	0.133, p-type	0.212, p-type

Values were calculated from data in Fig. 4. Mobility units are in cm² (V s)⁻¹.

The field-effect mobility of BN capped MoTe₂ (red) is maintained around 0.8–1 cm² (V s)⁻¹ until 150 °C where it experiences a sharp drop to 0.2 cm² (V s)⁻¹. Furthermore, after 200 °C the mobility values are shown to switch polarity from n- to p-type. The un-coated MoTe₂ in contrast, has a much lower initial mobility and undergoes its polarity switch already at 150 °C. Finally, at 200 °C the mobility absolute value increases slightly. The switch from initial n-type behavior to p-type can be linked to the oxygen incorporation in MoTe₂ layers found from XPS studies (Fig. 3). Previous reports of DFT simulations of oxygen interactions with MoTe₂ and formation of Mo-O and Te-O bonds can lead to the formation of deep-level trap states located 0.4 eV below the conduction band minimum⁴⁴. Such states may act as acceptor sites, effectively resulting in a switch to the p-type behavior as the number of oxygen substitutes for tellurium in MoTe₂ lattice is increased at higher temperatures in air. This is further supported by the delayed polarity switching of our experiments with BN covered device which protects MoTe₂ from oxygen diffusion and subsequent substitution in Te sites.

To study the effects of the BN layer for improved endurance of MoTe₂ device characteristics in oxidizing environments, the FET devices were held at a constant temperature of 100 °C for incrementally increased times from 5 min to up to one hour. I_dc-V_g curves displaying the change in electrical properties of MoTe₂ and MoTe₂/BN over increased time of exposure to 100 °C in air are displayed as semi-log plots in Fig. 5a,b, respectively. The uncapped MoTe₂ devices (Fig. 5a) exhibit a significant decrease in maximum drain current after the first 5 minutes, suggesting that the surface oxidation occurs almost immediately. Initially the device is active in the positive gate voltage region, indicating n-type behavior. However, as the heating time increases, the maximum drain currents decrease and transitions to the negative gate voltage region, indicating p-type behavior. Along this n- to p-type transition (about 10–15 min) the devices exhibit ambipolar behavior. For MoTe₂/BN devices, (Fig. 5b), the maximum drain current also declines with greater heating times but more steadily and remains non-zero even after 60 minutes exposure to 100 °C in air. In addition, the MoTe₂/BN devices do not undergo a polarity switch to p-type and never lose the n-type behavior (Fig. 5b).

Figure 5.

Current-voltage measurements of (a) MoTe₂ and (b) BN/MoTe₂ back-gated FET devices, which were held at 100 °C in air for consecutive time increments as shown in data labels. The drain voltage was maintained at 1 VDC. (c) Mobility of MoTe₂ and MoTe₂/BN devices, shown as a ratio to their initial mobility and plotted as a function of the time for device exposure to 100 °C in air. After 30 minutes, the electron mobility of the uncapped MoTe₂ device had dropped below the measurement noise level and thus is not continued in the plot. (d) Semilog plot comparing on/off ratios of MoTe₂ and MoTe₂/BN devices. The BN-coated device maintains a significantly higher ratio throughout the experiment while the uncapped devices rapidly decreases.

In Fig. 5c, the field effect mobility determined after heating to 100 °C in air is plotted to investigate MoTe₂ FET device endurance and the protective effect of the a-BN capping layer. The initial (before heating to 100 °C in air) values for electron-based mobility were used to normalize the data plot in order to demonstrate the rate of change of the device performance over time. Both MoTe₂ and MoTe₂/BN devices undergo a rapid mobility decline relative to their initial mobility after first 10 minutes before leveling off at 20 min to 60 min, suggesting that surface changes to MoTe₂ occur very quickly. The uncapped MoTe₂ devices show a larger decline in field effect mobility compared to MoTe₂/BN devices. In addition, the MoTe₂/BN devices retain their n-type performance over the entire test period without failing, confirming that the a-BN capping is a good choice for improving long-term device performance in addition to the improved overall mobility values discussed earlier. The on/off ratio change with exposure to 100 °C in air is presented in Fig. 5d. The MoTe₂/BN device maintains a significantly higher ratio of around 10² throughout the entire 60 min experiment time, while the on/off ratio for uncapped MoTe₂ device rapidly decreases.

In conclusion, durability of future 2D TMD devices will rely on solutions to prevent material degradation during their fabrication and operation. Moderate heating of uncapped exfoliated 2H-MoTe₂ in air shows a considerable oxidation of few-layer thick MoTe₂ surface resulting in deterioration of the FET device performance. The oxidation can be substantially mitigated by capping the 2H-MoTe₂ with a 10 nm thick a-BN layer, applied by pulsed laser deposition. For uncapped 2H-MoTe₂, the temperature induced oxidation leads to MoTe₂ structural defects with oxygen incorporation and appearance of Mo-O and Te-O bonding in XPS spectra. However, the absence of MoO₃ structure in the Raman data signals that partial oxidation occurred in the form of oxygen defects in Te vacancy sites or physio-absorption to Te surface sites. This is accompanied by the reduction in the field effect mobility and an eventual switch from an n- to p-type semiconductor behavior at around 150 °C. Devices consisting of 2H-MoTe₂ with an a-BN passivation layer were shown to have improved field effect mobility characteristics and significantly suppress material degradation via oxidation from heating in air. For fabricated MoTe₂/BN FET devices, the oxidation induced polarity switch was delayed to a temperature of 200 °C and as such, retained their n-type mobility and stabilized on/off ratio in extended exposure to 100 °C in air. Hence, amorphous BN was found to be an effective approach for preventing 2H-MoTe₂ oxidation and improving the 2D FET device endurance and overall performance. Considering a large area scalability, room temperature growth and versatility of the PLD produced a-BN passivation layer, the explored 2H-MoTe₂/a-BN structures can be beneficial for electronic and optoelectronic device applications.

Methods

Preparation of 2H-MoTe₂

2H-MoTe₂ single-crystals were produced by the chlorine-assisted chemical vapor transport (CVT) method. In brief, a vacuum-sealed quartz ampoule with polycrystalline MoTe₂ powder and a small amount of TeCl₄ (4 mg/cm³) was placed in a furnace containing a temperature gradient so that the MoTe₂ charge was kept at 800 °C, and the temperature at the opposite end of the ampoule was about 710 °C. The ampoule was slowly cooled after 7 days of growth. The 2 H phase of the obtained MoTe₂ flakes was confirmed by powder X-ray diffraction and transmission electron microscopy studies.

MoTe₂ Device Fabrication

2H-MoTe₂ flakes were then later mechanically exfoliated onto heavily p-doped silicon wafers with a 270 nm silicon oxide surface layer using conventional adhesive tape methods, the details of which have been reported previously⁴⁵. Candidate 2D flakes were identified using optical microscopy since the SiO₂/Si substrate provides a clear optical contrast for single, double, and few-layer flakes compared to bulk¹⁰. Flake thickness was estimated using Raman spectroscopy and further confirmed using atomic force microscopy (AFM). Back-gated FETs with channel widths of 2 µm were fabricated by evaporating Ti/Au (20 nm/20 nm) contacts onto the MoTe₂ flakes defined by electron beam lithography (EBL) and lift-off.

a-BN Deposition

Some of the devices were covered, post device fabrication, by an ultrathin amorphous BN layer. This a-BN capping layer of 10 nm thickness, was deposited by pulsed laser deposition using a BN target (99.999%), ablated with a focused 248 nm KrF laser in nitrogen background gas under processing parameters optimized for a fully dense, pin-hole free, and stoichiometric BN film growth as reported previously^30,39. The a-BN capping layer growth covered the entire device and was deposited at room temperature. We did not notice an effect to the crystallinity of the MoTe₂ or deposited Ti/Au electrodes.

Electrical Measurements of Heated Devices

The electrical measurements were performed using an Agilent B2902A system equipped with a probe station. The 10 nm a-BN layer was completely pierced by the contact probes to make good metal contact with source and drains electrodes of the devices.

Heat treatment experiments were conducted using a hotplate in laboratory air of about 50% relative humidity. Two sets of heating experiments were performed: i) temperature dependent measurements where samples were heated from room temperature (≈23 °C) to 300 °C with a 50 °C increment and held for 1 min before cooling, and ii) time dependent measurements where samples were held at 100 °C with 5-min time increments up to 60 min before cooling down. Back-gated FET devices with both open and a-BN-capped MoTe₂ surfaces were heated simultaneously to ensure experimental consistency. Before taking I-V characteristics, the devices were allowed to cool to room temperature to prevent thermal effects on the measured results and allow direct comparisons of device performances after heat treatment.

Author Contributions

A.A.V. managed the project and overlooked all experiments. B.S. performed MoTe₂ material exfoliation, device fabrication via EBL, and all material characterization and electrical testing. N.G. performed the a-BN coating using PLD. S.K. and A.V.D. synthesized the bulk 2H-MoTe₂ materials via iodine-assisted CVT technique. All authors took part in the discussion and writing of this manuscript.

Competing Interests

The authors declare no competing interests.