Abstract
This document presents the physical-chemical parameters with the objective of evaluating and analyzing the drinking water quality in the Azogues city applying the water quality index (WQI) and to research the water stability in the distribution network using corrosion indexes. Thirty samples were collected monthly for six months throughout the drinking water distribution network; turbidity, temperature, electric conductivity, pH, total dissolved solids, total hardness, calcium, magnesium, alkalinity, chlorides, nitrates, sulfates and phosphates were determined; the physical-chemical parameters were measured using standard methods. The processed data revealed that the average values of LSI, RSI and PSI were 0.5 (±0.34), 6.76 (±0.6), 6.50 (±0.99) respectively. The WQI calculation indicated that 100% of the samples are considered excellent quality water. According to the Langelier, Ryznar and Pukorius indexes showed that drinking water in Azogues is corrosive. The quality of drinking water according to the WQI is in a good and excellent category.
Specifications table
Subject area | Environmental Engineering |
More specific subject area | Water treatment |
Type of data | Table and figure |
How data was acquired | In 30 points of the drinking water network for six months, 176 water samples were collected, stored and transferred to the lab using standard methods and the drinking water quality; turbidity, pH, temperature, total dissolved solids, total hardness, calcium hardness, alkalinity, nitrate, phosphate, chloride, sulfate and free chlorine were measured. Alkalinity, total hardness and calcium hardness were measured by titration method; the hydrogen ion concentration (pH), temperature and total dissolved solids were analyzed with the HACH Multiparameter HQ 40d. Turbidity were measured with turbidimeter (model P2100 HACH); nitrate, phosphate, chloride, and sulfate were determined with HACH DR 2500 spectrophotometer, free chlorine were measured with HACH DR890 and compared with internal standards. |
Data format | Raw, analyzed |
Experimental factors | The mentioned parameters above, in abstract section, were analyzed according to the standards for water and wastewater treatment handbook. |
Experimental features | The levels of physical and chemical parameters drinking water were determined. |
Data source location | Azogues, Ecuador 2°44'22" S, 78°50'54" O |
Data accessibility | Data are available in the article. |
Value of the data
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The dates presented are used to calculate the water quality indexes, as well as the corrosion and scaling indexes, emphasizing the importance of continuous monitoring of water quality. Determine the corrosion potential and quality of drinking water in all distribution systems is important to avoid adverse effects on health and economic losses due to deterioration of the infrastructure.
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The water quality indexes (WQI) serve to provide a clear picture of the quality of water distributed and used for human consumption, therefore, these data could be useful for communities, or cities that have similar drinking water quality.
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The pipes, fittings and valves in the distribution networks deteriorate due to corrosive water and cause some health, aesthetic and economic problems. Then, the determination of the corrosion and incrustation potential of drinking water allows decision making and adoption of guidelines for the management of water quality by those who are related to engineering and water quality management.
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Sharing such data can allow a much earlier rectification of the problem of corrosion and scaling.
1. Data
The data presented in this article deals with the quality of drinking water distributed in the Azogues city, Ecuador. Data include in this document, indicate about the situation of drinking water saturation, three stability indexes were determined: Langelier, Ryznar, and Pockorius, were calculated using special equations that are summarized in Table 1. Other data parameters such as turbidity (Tur), pH, total dissolved solids (TDS), electrical conductivity (EC), total hardness (TH), calcium (Ca2+), magnesium (Mg2+), alkalinity (Alk), sulfate (SO42−), chloride (Cl−), nitrate (NO3−), phosphate (PO43−), free chlorine (Cl2). The physical and physical characteristics of drinking water are shown in Table 2, Table 3. The corrosion indexes values obtained are presented in Table 4.
Table 1.
Index | Equation | Description | Value | Water condition |
---|---|---|---|---|
Langelier | LSI = pH-pHs | LSI = Langelier Saturation Index | LSI > 0 | Tend to precipitate |
LSI | pH = pH measured in situ. | |||
pHs = pH at saturation | ||||
pHs = 9.3 + A + B - C - D | LSI = 0 | Equilibrium | ||
B = [−13.12log10(273 °C+T)]+34.55 C = log10[mg/L as ]−0.4 | LSI < 0 | Tend to corrosion | ||
D = log10 [Alk. mg/L as ] | ||||
TDS = Total Dissolved Solids mg/L | ||||
Ryznar | RSI = 2 pHs-pH | RSI = Ryznar Stability Index | RSI < 5.5 | Highly scale-forming |
RSI | pHs = pH at saturation | |||
pH = pH measured in situ | 5.5 < RSI < 6.2 | Relatively scale-forming | ||
6.2 < RSI < 6.8 | Balanced | |||
6.8 < RSI < 8 | Low corrosion | |||
RSI > 8 | High corrosion | |||
Puckorius | PSI = 2pHs−pHeq | PSI < 5.5 | Tend to precipitate | |
PSI | pHs = pH at saturation | 5.5<PSI<6.5 | Optimal range | |
pHeq = 1.456 Log(Alk) + 4.54 | PSI > 6.5 | Tend to corrosion |
Table 2.
Number Sample | Turbidity NTU | pH | Temp. °C | TDS mg/L | EC µS/cm | Total hardness mg/L CaCO3 | Ca2+mg/L CaCO3 | Ca2+mg/L |
---|---|---|---|---|---|---|---|---|
S1 | 0.56 | 7.42 | 17.52 | 81.17 | 129.96 | 68.33 | 51.00 | 20.40 |
S2 | 0.55 | 7.38 | 19.13 | 82.17 | 131.83 | 70.00 | 52.17 | 20.87 |
S3 | 0.51 | 7.20 | 16.68 | 63.67 | 102.49 | 69.33 | 52.17 | 20.87 |
S4 | 0.61 | 7.17 | 20.09 | 80.67 | 129.49 | 78.00 | 57.83 | 23.13 |
S5 | 0.59 | 7.46 | 18.46 | 70.40 | 111.89 | 72.00 | 56.00 | 22.40 |
S6 | 0.57 | 7.26 | 17.32 | 73.60 | 117.62 | 75.60 | 58.00 | 23.20 |
S7 | 0.51 | 7.22 | 18.25 | 75.67 | 119.47 | 70.67 | 53.67 | 21.47 |
S8 | 0.50 | 7.21 | 16.78 | 75.60 | 120.82 | 74.00 | 56.00 | 22.40 |
S9 | 0.59 | 7.20 | 18.33 | 64.83 | 103.27 | 69.00 | 52.67 | 21.07 |
S10 | 0.47 | 7.20 | 16.88 | 66.17 | 106.09 | 69.83 | 52.00 | 20.80 |
S11 | 0.45 | 7.17 | 15.93 | 71.17 | 112.96 | 71.17 | 53.00 | 21.20 |
S12 | 0.49 | 7.22 | 15.30 | 66.83 | 106.33 | 71.50 | 52.67 | 21.07 |
S13 | 0.44 | 7.16 | 14.85 | 58.67 | 94.61 | 56.33 | 42.00 | 16.80 |
S14 | 0.54 | 7.26 | 18.13 | 72.00 | 115.01 | 70.83 | 55.00 | 22.00 |
S15 | 0.55 | 7.35 | 16.95 | 72.50 | 115.37 | 73.17 | 54.67 | 21.87 |
S16 | 0.55 | 7.16 | 19.75 | 74.83 | 119.11 | 72.00 | 54.33 | 21.73 |
S17 | 0.53 | 7.20 | 17.20 | 71.00 | 112.89 | 71.10 | 53.50 | 21.40 |
S18 | 0.54 | 7.22 | 18.10 | 70.17 | 111.16 | 72.42 | 54.75 | 21.90 |
S19 | 0.50 | 7.23 | 17.32 | 69.00 | 110.58 | 74.83 | 55.67 | 22.27 |
S20 | 0.50 | 7.18 | 18.57 | 71.33 | 112.57 | 70.83 | 53.50 | 21.40 |
S21 | 0.52 | 7.22 | 17.62 | 55.67 | 88.36 | 55.50 | 42.17 | 16.87 |
S22 | 0.50 | 7.19 | 17.53 | 64.17 | 103.92 | 65.17 | 50.83 | 20.33 |
S23 | 0.48 | 7.27 | 17.03 | 66.50 | 106.29 | 69.83 | 54.00 | 21.60 |
S24 | 0.48 | 7.24 | 19.08 | 68.83 | 109.29 | 68.00 | 52.67 | 21.07 |
S25 | 0.47 | 7.22 | 16.75 | 63.67 | 99.96 | 65.67 | 50.50 | 20.20 |
S26 | 0.47 | 7.26 | 18.58 | 67.50 | 106.85 | 65.33 | 49.33 | 19.73 |
S27 | 0.49 | 7.26 | 16.67 | 67.17 | 107.07 | 67.67 | 51.33 | 20.53 |
S28 | 0.47 | 7.28 | 15.72 | 66.83 | 106.08 | 67.33 | 50.67 | 20.27 |
S29 | 0.53 | 7.20 | 20.08 | 73.50 | 117.72 | 67.17 | 52.00 | 20.80 |
S30 | 0.50 | 7.27 | 17.97 | 55.67 | 88.68 | 58.50 | 44.17 | 17.67 |
Mean | 0.51 | 7.24 | 17.6 | 69.29 | 110.47 | 68.94 | 52.19 | 20.88 |
Min | 0.39 | 7.16 | 14.8 | 55.67 | 88.36 | 55.50 | 42.00 | 16.80 |
Max | 0.61 | 7.46 | 20.1 | 82.17 | 131.83 | 78.00 | 58.00 | 23.20 |
S.D. | 0.05 | 0.07 | 1.3 | 6.55 | 10.52 | 5.12 | 3.84 | 1.54 |
Table 3.
Number sample | Mg2+mg/L CaCO3 | Mg2+mg/L | Free chlorine mg/L | SO42−mg/L | Alkalinity mg/L CaCO3 | Cl−mg/L | NO3−mg/L | PO43−mg/L |
---|---|---|---|---|---|---|---|---|
S1 | 17.33 | 4.16 | 0.47 | 22.33 | 46.83 | 5.30 | 0.55 | 0.07 |
S2 | 17.83 | 4.28 | 0.59 | 21.00 | 50.00 | 5.58 | 0.58 | 0.07 |
S3 | 17.17 | 4.12 | 0.76 | 19.17 | 46.33 | 5.02 | 0.48 | 0.07 |
S4 | 20.17 | 4.84 | 0.82 | 23.00 | 48.67 | 5.22 | 0.37 | 0.07 |
S5 | 16.00 | 3.84 | 0.53 | 20.20 | 48.00 | 5.22 | 0.38 | 0.07 |
S6 | 17.60 | 4.22 | 0.71 | 19.80 | 54.80 | 5.24 | 0.44 | 0.07 |
S7 | 17.00 | 4.08 | 0.45 | 18.67 | 52.50 | 5.12 | 0.50 | 0.11 |
S8 | 18.00 | 4.32 | 0.75 | 18.90 | 56.60 | 5.88 | 0.50 | 0.09 |
S9 | 16.33 | 3.92 | 0.56 | 17.33 | 50.00 | 5.47 | 0.38 | 0.07 |
S10 | 17.83 | 4.28 | 0.69 | 18.00 | 51.33 | 5.65 | 0.42 | 0.07 |
S11 | 18.17 | 4.36 | 0.71 | 15.83 | 51.17 | 5.55 | 0.52 | 0.08 |
S12 | 18.83 | 4.52 | 0.90 | 16.50 | 53.33 | 4.88 | 0.43 | 0.06 |
S13 | 14.33 | 3.44 | 0.55 | 12.17 | 40.33 | 7.27 | 0.67 | 0.06 |
S14 | 15.83 | 3.80 | 0.62 | 20.67 | 47.67 | 5.25 | 0.58 | 0.06 |
S15 | 18.50 | 4.44 | 0.64 | 20.50 | 48.83 | 5.63 | 0.50 | 0.08 |
S16 | 17.67 | 4.24 | 0.75 | 21.83 | 45.83 | 5.28 | 0.35 | 0.24 |
S17 | 17.60 | 4.22 | 0.86 | 20.00 | 46.60 | 5.72 | 0.44 | 0.08 |
S18 | 17.67 | 4.24 | 0.86 | 19.33 | 50.00 | 5.55 | 0.47 | 0.07 |
S19 | 19.17 | 4.60 | 0.66 | 19.83 | 47.50 | 5.35 | 0.63 | 0.08 |
S20 | 17.33 | 4.16 | 0.80 | 18.67 | 46.68 | 5.75 | 0.53 | 0.08 |
S21 | 13.33 | 3.20 | 0.58 | 11.00 | 40.82 | 6.52 | 0.53 | 0.07 |
S22 | 14.33 | 3.44 | 0.84 | 17.83 | 46.33 | 5.85 | 0.37 | 0.07 |
S23 | 15.83 | 3.80 | 0.85 | 20.17 | 48.50 | 5.25 | 0.35 | 0.07 |
S24 | 15.33 | 3.68 | 0.78 | 18.00 | 46.50 | 5.90 | 0.50 | 0.07 |
S25 | 15.17 | 3.64 | 0.86 | 17.00 | 47.17 | 5.40 | 0.37 | 0.08 |
S26 | 16.00 | 3.84 | 0.82 | 16.17 | 48.83 | 5.88 | 0.38 | 0.09 |
S27 | 16.33 | 3.92 | 0.81 | 17.00 | 48.17 | 6.08 | 0.43 | 0.08 |
S28 | 16.67 | 4.00 | 0.86 | 16.67 | 50.67 | 6.15 | 0.65 | 0.10 |
S29 | 15.17 | 3.64 | 0.77 | 17.00 | 49.33 | 5.67 | 0.60 | 0.08 |
S30 | 14.33 | 3.44 | 0.48 | 10.17 | 40.33 | 6.43 | 0.47 | 0.08 |
Mean | 16.75 | 4.02 | 0.71 | 18.12 | 48.25 | 5.64 | 0.48 | 0.08 |
Min | 13.33 | 3.20 | 0.5 | 10.17 | 40.33 | 4.88 | 0.35 | 0.06 |
Max | 20.17 | 4.84 | 0.9 | 23.00 | 56.60 | 7.27 | 0.67 | 0.24 |
S.D. | 1.60 | 0.38 | 0.1 | 3.02 | 3.70 | 0.50 | 0.09 | 0.03 |
Table 4.
Number sample | Langelier index LSI | Ryznar index RSI | Puckorius index PSI |
---|---|---|---|
S1 | −1.25 | 9.92 | 10.38 |
S2 | −1.22 | 9.81 | 10.19 |
S3 | −1.42 | 10.04 | 10.21 |
S4 | −1.38 | 9.92 | 10.09 |
S5 | −1.15 | 9.76 | 10.25 |
S6 | −1.28 | 9.82 | 10.00 |
S7 | −1.35 | 9.93 | 10.11 |
S8 | −1.34 | 9.89 | 10.00 |
S9 | −1.39 | 9.98 | 10.16 |
S10 | −1.42 | 10.04 | 10.21 |
S11 | −1.46 | 10.09 | 10.23 |
S12 | −1.41 | 10.03 | 10.20 |
S13 | −1.68 | 10.52 | 10.79 |
S14 | −1.35 | 9.97 | 10.26 |
S15 | −1.26 | 9.88 | 10.23 |
S16 | −1.44 | 10.03 | 10.23 |
S17 | −1.44 | 10.08 | 10.32 |
S18 | −1.36 | 9.94 | 10.15 |
S19 | −1.39 | 10.01 | 10.26 |
S20 | −1.43 | 10.04 | 10.25 |
S21 | −1.55 | 10.32 | 10.65 |
S22 | −1.47 | 10.12 | 10.34 |
S23 | −1.35 | 9.98 | 10.26 |
S24 | −1.37 | 9.98 | 10.24 |
S25 | −1.44 | 10.10 | 10.34 |
S26 | −1.36 | 9.99 | 10.25 |
S27 | −1.39 | 10.04 | 10.31 |
S28 | −1.37 | 10.03 | 10.29 |
S29 | −1.37 | 9.93 | 10.13 |
S30 | −1.48 | 10.23 | 10.61 |
Also in this document the drinking water quality indexes (WQI) are presented, to evaluate the water quality through WQI, the recommended standards by the World Health Organization (WHO) 2011 were considered [1] the relative weight (Wi) was assigned for water quality parameters according to their relative importance to water quality for consumption purposes (Table 5). The calculation obtained from WQI for drinking water samples is presented in Table 7. The classification of drinking water quality based on WQI values is shown in Table 8. Azogues city where the study was realized is shown in Fig. 1.
Table 5.
Chemical parameter | Unit | Factor weight (wi) | WHO standard (si) | Relative weights (Wi) |
---|---|---|---|---|
Turbidity | NTU | 5 | 0.5 | 0.12 |
pH | 4 | 8.5 | 0.10 | |
TDS | mg/L | 3 | 500 | 0.07 |
Total Hardness | mg/L | 2 | 200 | 0.05 |
Calcium Ca2 + | mg/L | 3 | 75 | 0.07 |
Magnesium Mg2+ | mg/L | 2 | 50 | 0.05 |
Sulfate | mg/L | 4 | 250 | 0.10 |
Alkalinity | mg/L | 3 | 200 | 0.07 |
Chloride | mg/L | 3 | 250 | 0.07 |
Nitrate | mg/L | 5 | 50 | 0.12 |
Phosphate | mg/L | 2 | 0.5 | 0.05 |
Free Chlorine | mg/L | 5 | 1 | 0.12 |
Table 7.
N° sample | Tur. | pH | TDS | TH | Ca | Mg | SO42− | Alk | Cl− | NO3− | PO43− | Cl2 | WQI |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
S1 | 13.66 | 8.52 | 1.19 | 1.67 | 1.99 | 0.41 | 0.87 | 1.71 | 0.16 | 0.13 | 0.63 | 0.03 | 30.96 |
S2 | 13.41 | 8.47 | 1.20 | 1.71 | 2.04 | 0.42 | 0.82 | 1.83 | 0.16 | 0.14 | 0.65 | 0.04 | 30.89 |
S3 | 12.44 | 8.26 | 0.93 | 1.69 | 2.04 | 0.40 | 0.75 | 1.70 | 0.15 | 0.12 | 0.70 | 0.05 | 29.22 |
S4 | 14.88 | 8.23 | 1.18 | 1.90 | 2.26 | 0.47 | 0.90 | 1.78 | 0.15 | 0.09 | 0.72 | 0.05 | 32.61 |
S5 | 14.39 | 8.56 | 1.03 | 1.76 | 2.19 | 0.37 | 0.79 | 1.76 | 0.15 | 0.09 | 0.72 | 0.03 | 31.84 |
S6 | 13.90 | 8.33 | 1.08 | 1.84 | 2.26 | 0.41 | 0.77 | 2.00 | 0.15 | 0.11 | 0.68 | 0.04 | 31.60 |
S7 | 12.44 | 8.29 | 1.11 | 1.72 | 2.09 | 0.40 | 0.73 | 1.92 | 0.15 | 0.12 | 1.02 | 0.03 | 30.02 |
S8 | 12.20 | 8.28 | 1.11 | 1.80 | 2.19 | 0.42 | 0.74 | 2.07 | 0.17 | 0.12 | 0.84 | 0.05 | 29.98 |
S9 | 14.39 | 8.26 | 0.95 | 1.68 | 2.06 | 0.38 | 0.68 | 1.83 | 0.16 | 0.09 | 0.68 | 0.03 | 31.20 |
S10 | 11.46 | 8.26 | 0.97 | 1.70 | 2.03 | 0.42 | 0.70 | 1.88 | 0.17 | 0.10 | 0.72 | 0.04 | 28.45 |
S11 | 10.98 | 8.23 | 1.04 | 1.74 | 2.07 | 0.43 | 0.62 | 1.87 | 0.16 | 0.13 | 0.73 | 0.04 | 28.03 |
S12 | 11.95 | 8.29 | 0.98 | 1.74 | 2.06 | 0.44 | 0.64 | 1.95 | 0.14 | 0.11 | 0.60 | 0.05 | 28.96 |
S13 | 10.73 | 8.22 | 0.86 | 1.37 | 1.64 | 0.34 | 0.47 | 1.48 | 0.21 | 0.16 | 0.59 | 0.03 | 26.10 |
S14 | 13.17 | 8.33 | 1.05 | 1.73 | 2.15 | 0.37 | 0.81 | 1.74 | 0.15 | 0.14 | 0.59 | 0.04 | 30.27 |
S15 | 13.41 | 8.44 | 1.06 | 1.78 | 2.13 | 0.43 | 0.80 | 1.79 | 0.16 | 0.12 | 0.73 | 0.04 | 30.91 |
S16 | 13.41 | 8.22 | 1.10 | 1.76 | 2.12 | 0.41 | 0.85 | 1.68 | 0.15 | 0.09 | 2.31 | 0.05 | 32.14 |
S17 | 12.93 | 8.26 | 1.04 | 1.73 | 2.09 | 0.41 | 0.78 | 1.70 | 0.17 | 0.11 | 0.80 | 0.05 | 30.08 |
S18 | 13.17 | 8.29 | 1.03 | 1.77 | 2.14 | 0.41 | 0.75 | 1.83 | 0.16 | 0.11 | 0.70 | 0.05 | 30.41 |
S19 | 12.20 | 8.30 | 1.01 | 1.83 | 2.17 | 0.45 | 0.77 | 1.74 | 0.16 | 0.15 | 0.76 | 0.04 | 29.58 |
S20 | 12.20 | 8.24 | 1.04 | 1.73 | 2.09 | 0.41 | 0.73 | 1.71 | 0.17 | 0.13 | 0.75 | 0.05 | 29.23 |
S21 | 12.68 | 8.29 | 0.81 | 1.35 | 1.65 | 0.31 | 0.43 | 1.49 | 0.19 | 0.13 | 0.70 | 0.04 | 28.07 |
S22 | 12.20 | 8.25 | 0.94 | 1.59 | 1.98 | 0.34 | 0.70 | 1.70 | 0.17 | 0.09 | 0.63 | 0.05 | 28.63 |
S23 | 11.71 | 8.34 | 0.97 | 1.70 | 2.11 | 0.37 | 0.79 | 1.77 | 0.15 | 0.09 | 0.70 | 0.05 | 28.76 |
S24 | 11.71 | 8.31 | 1.01 | 1.66 | 2.06 | 0.36 | 0.70 | 1.70 | 0.17 | 0.12 | 0.70 | 0.05 | 28.54 |
S25 | 11.46 | 8.29 | 0.93 | 1.60 | 1.97 | 0.36 | 0.66 | 1.73 | 0.16 | 0.09 | 0.76 | 0.05 | 28.06 |
S26 | 11.46 | 8.33 | 0.99 | 1.59 | 1.92 | 0.37 | 0.63 | 1.79 | 0.17 | 0.09 | 0.86 | 0.05 | 28.27 |
S27 | 11.95 | 8.33 | 0.98 | 1.65 | 2.00 | 0.38 | 0.66 | 1.76 | 0.18 | 0.11 | 0.80 | 0.05 | 28.86 |
S28 | 11.46 | 8.36 | 0.98 | 1.64 | 1.98 | 0.39 | 0.65 | 1.85 | 0.18 | 0.16 | 0.96 | 0.05 | 28.66 |
S29 | 12.93 | 8.26 | 1.08 | 1.64 | 2.03 | 0.36 | 0.66 | 1.80 | 0.17 | 0.15 | 0.81 | 0.05 | 29.93 |
S30 | 12.20 | 8.34 | 0.81 | 1.43 | 1.72 | 0.34 | 0.40 | 1.48 | 0.19 | 0.11 | 0.80 | 0.03 | 27.84 |
Table 8.
WQI range | Type of water | Explanation |
---|---|---|
< 50 | Excellent Water | Good for human health |
50.1–100 | Good Water | Fit for human consumption |
100.1–200 | Poor Water | Water not in good condition |
200.1–300 | Very Poor Water | Need attention before use |
> 300.1 | Inappropriate | Need too much attention |
From Fig. 2, Fig. 3, Fig. 4 the variation of the physical-chemical parameters in the 30 sampling points is shown. Fig. 5 shows the variation of the corrosion indexes in the 30 sampling points. Fig. 6 show the Water Quality Indexes at the 30 sampling points.
2. Experimental design, materials and methods
2.1. Study area description
The Azogues city is located south of the Republic of Ecuador, its geographic coordinates are: latitude 2° 44'22 "S, longitude: 78° 50'54" W, they cover an area of approximately 1200 km2, the average altitude of the city is 2518 m above sea level, the average temperature is 17 °C.
Fig. 7 shows the location of the drinking water network.
2.2. Collection of samples and analytical procedures
Monthly samples were collected at 30 points of the drinking water network for six months, 180 samples in total were collected, stored and transferred to the laboratory using standard methods and drinking water quality; turbidity, pH, temperature, total dissolved solids, total hardness, calcium hardness, alkalinity, nitrate, phosphate, chloride, sulfate and free chlorine were measured. Fig. 7 shows the study area and the sampling locations, the samples were collected in polyethylene bottles (1 L) and transported immediately at 4 °C to the central laboratory of the drinking water company. The alkalinity, total hardness and hardness of calcium were measured by the titration method; concentration of hydrogen ion (pH), temperature and total dissolved solids were analyzed with HACH Multiparameter HQ 40d, turbidity was measured using turbidimeter (model P2100 HACH); nitrate, phosphate, chloride and sulfate were determined with the HACH DR 2500 spectrophotometer, free chlorine was measured with HACH DR 890. All the water samples were analyzed according to the standard methods for the analysis of drinking water [5], [6], [7]. The data obtained after the laboratory analysis is presented in Table 2, Table 3.
2.3. Drinking water stability indexes calculation
Table 1 presents the equations and criteria to calculate and categorize the water stability indexes. The Langelier saturation index, Ryznar saturation index, and the Puckorius scale index were calculated and classified into three categories: scale, stabilized and corrosive [2], [3], [4]. The results are presented in Table 4.
2.4. Water quality index calculation
For calculation of WQI, the following four steps have been taken into account [8], [9], [10], [11]. In the first step, each of the analyzed parameters has been assigned a weight (wi) according to its relative importance in the overall quality of water for drinking purposes (Table 5). In the second step, the relative weight (Wi) is calculated as per the established method as follows.
Where ‘Wi’ is the relative weight, ‘wi’ is the weight of each parameter and ‘n’ is the number of parameters. In the third step a quality rating scale (qi) for each parameter is calculated by following equation (Table 6);
Where ‘Ci‘ is the concentration of each chemical parameter in each water sample and ‘si’ is the standard value for each chemical parameter according to the Guide lines of WHO. In the fourth step the sub index (Sli) of each chemical parameter is estimated by using the equation;
Table 6.
Number sample | Tur. | pH | TDS | TH | Ca2 + | Mg2 + | SO42− | Alk. | Cl− | NO3− | PO43− | Cl2 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
S1 | 112 | 87.29 | 16.23 | 34.17 | 27.20 | 8.32 | 8.93 | 23.42 | 2.12 | 1.10 | 13.00 | 0.23 |
S2 | 110 | 86.82 | 16.43 | 35.00 | 27.83 | 8.56 | 8.40 | 25.00 | 2.23 | 1.17 | 13.33 | 0.29 |
S3 | 102 | 84.71 | 12.73 | 34.67 | 27.83 | 8.24 | 7.67 | 23.17 | 2.01 | 0.97 | 14.33 | 0.38 |
S4 | 122 | 84.35 | 16.13 | 39.00 | 30.84 | 9.68 | 9.20 | 24.33 | 2.09 | 0.73 | 14.67 | 0.41 |
S5 | 118 | 87.76 | 14.08 | 36.00 | 29.87 | 7.68 | 8.08 | 24.00 | 2.09 | 0.76 | 14.80 | 0.26 |
S6 | 114 | 85.41 | 14.72 | 37.80 | 30.93 | 8.45 | 7.92 | 27.40 | 2.10 | 0.88 | 14.00 | 0.35 |
S7 | 102 | 84.94 | 15.13 | 35.34 | 28.63 | 8.16 | 7.47 | 26.25 | 2.05 | 1.00 | 21.00 | 0.23 |
S8 | 100 | 84.82 | 15.12 | 37.00 | 29.87 | 8.64 | 7.56 | 28.30 | 2.35 | 1.00 | 17.20 | 0.37 |
S9 | 118 | 84.71 | 12.97 | 34.50 | 28.09 | 7.84 | 6.93 | 25.00 | 2.19 | 0.77 | 14.00 | 0.28 |
S10 | 94 | 84.71 | 13.23 | 34.92 | 27.73 | 8.56 | 7.20 | 25.67 | 2.26 | 0.83 | 14.67 | 0.34 |
S11 | 90 | 84.35 | 14.23 | 35.59 | 28.27 | 8.72 | 6.33 | 25.58 | 2.22 | 1.03 | 15.00 | 0.35 |
S12 | 98 | 84.94 | 13.37 | 35.75 | 28.09 | 9.04 | 6.60 | 26.67 | 1.95 | 0.87 | 12.33 | 0.45 |
S13 | 88 | 84.24 | 11.73 | 28.17 | 22.40 | 6.88 | 4.87 | 20.17 | 2.91 | 1.33 | 12.00 | 0.27 |
S14 | 108 | 85.41 | 14.40 | 35.42 | 29.33 | 7.60 | 8.27 | 23.83 | 2.10 | 1.17 | 12.00 | 0.31 |
S15 | 110 | 86.47 | 14.50 | 36.59 | 29.16 | 8.88 | 8.20 | 24.42 | 2.25 | 1.00 | 15.00 | 0.32 |
S16 | 110 | 84.24 | 14.97 | 36.00 | 28.97 | 8.48 | 8.73 | 22.92 | 2.11 | 0.70 | 47.33 | 0.37 |
S17 | 106 | 84.71 | 14.20 | 35.55 | 28.53 | 8.45 | 8.00 | 23.30 | 2.29 | 0.88 | 16.40 | 0.43 |
S18 | 108 | 84.94 | 14.03 | 36.21 | 29.20 | 8.48 | 7.73 | 25.00 | 2.22 | 0.93 | 14.33 | 0.43 |
S19 | 100 | 85.06 | 13.80 | 37.42 | 29.69 | 9.20 | 7.93 | 23.75 | 2.14 | 1.27 | 15.67 | 0.33 |
S20 | 100 | 84.47 | 14.27 | 35.42 | 28.53 | 8.32 | 7.47 | 23.34 | 2.30 | 1.07 | 15.33 | 0.40 |
S21 | 104 | 84.94 | 11.13 | 27.75 | 22.49 | 6.40 | 4.40 | 20.41 | 2.61 | 1.07 | 14.33 | 0.29 |
S22 | 100 | 84.59 | 12.83 | 32.59 | 27.11 | 6.88 | 7.13 | 23.17 | 2.34 | 0.73 | 13.00 | 0.42 |
S23 | 96 | 85.53 | 13.30 | 34.92 | 28.80 | 7.60 | 8.07 | 24.25 | 2.10 | 0.70 | 14.33 | 0.43 |
S24 | 96 | 85.18 | 13.77 | 34.00 | 28.09 | 7.36 | 7.20 | 23.25 | 2.36 | 1.00 | 14.33 | 0.39 |
S25 | 94 | 84.94 | 12.73 | 32.84 | 26.93 | 7.28 | 6.80 | 23.58 | 2.16 | 0.73 | 15.67 | 0.43 |
S26 | 94 | 85.41 | 13.50 | 32.67 | 26.31 | 7.68 | 6.47 | 24.42 | 2.35 | 0.77 | 17.67 | 0.41 |
S27 | 98 | 85.41 | 13.43 | 33.84 | 27.37 | 7.84 | 6.80 | 24.08 | 2.43 | 0.87 | 16.33 | 0.40 |
S28 | 94 | 85.65 | 13.37 | 33.67 | 27.03 | 8.00 | 6.67 | 25.33 | 2.46 | 1.30 | 19.67 | 0.43 |
S29 | 106 | 84.71 | 14.70 | 33.59 | 27.73 | 7.28 | 6.80 | 24.67 | 2.27 | 1.20 | 16.67 | 0.38 |
S30 | 100 | 85.53 | 11.13 | 29.25 | 23.56 | 6.88 | 4.07 | 20.17 | 2.57 | 0.93 | 16.33 | 0.24 |
The data obtained of SI are presented in Table 7. The overall Water Quality Index was calculated by adding together each sub index values of each water samples as follows;
The WQI values presented in the last column of Table 7 were compared with the standard values of Table 8. The WQI values at the 30 sampling sites clearly indicate that drinking water in all areas of Azogues is safe to drink. Therefore, based on the general results, drinking water in Azogues is of excellent quality.
Acknowledgements
The authors thank the Manager of EMAPAL EP (Eng. Xavier Ramírez) for allowing this study in the drinking water company.
Footnotes
Supplementary data associated with this article can be found in the online version at doi:10.1016/j.dib.2018.03.007.
Transparency document. Supplementary material
.
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