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. 2007 Mar 3;12(3):304–311. doi: 10.3390/12030304

Table 2.

Oxidation of sulfides to sulfoxides with hydrogen peroxide a.

Entry Substrate Time (min) Conversion (%) Sulfoxide b Yield (%)c
1 graphic file with name molecules-12-00304-i001.jpg 80 100 graphic file with name molecules-12-00304-i002.jpg 99
2 graphic file with name molecules-12-00304-i003.jpg 120 100 graphic file with name molecules-12-00304-i004.jpg 93
3 graphic file with name molecules-12-00304-i005.jpg 75 100 graphic file with name molecules-12-00304-i006.jpg 94
4 graphic file with name molecules-12-00304-i007.jpg 50 100 graphic file with name molecules-12-00304-i008.jpg 92
5 graphic file with name molecules-12-00304-i009.jpg 35 100 graphic file with name molecules-12-00304-i010.jpg 90
6 graphic file with name molecules-12-00304-i011.jpg 70 100 graphic file with name molecules-12-00304-i012.jpg 93
7 graphic file with name molecules-12-00304-i013.jpg 50 100 graphic file with name molecules-12-00304-i014.jpg 91
8 graphic file with name molecules-12-00304-i015.jpg 60 100 graphic file with name molecules-12-00304-i016.jpg 92
9 graphic file with name molecules-12-00304-i017.jpg 48 100 graphic file with name molecules-12-00304-i018.jpg 90
10 graphic file with name molecules-12-00304-i019.jpg 30 100 graphic file with name molecules-12-00304-i020.jpg 96
11 graphic file with name molecules-12-00304-i021.jpg 26 100 graphic file with name molecules-12-00304-i022.jpg 93
12 graphic file with name molecules-12-00304-i023.jpg 45 100 graphic file with name molecules-12-00304-i024.jpg 91

a 2 mmol of substrate at room temperature and 8 mmol of 30% aqueous H2O2, in glacial acetic acid (2 mL) at room temperature.

b The products were identified by comparison of physical and spectroscopic properties with authentic compounds.

c Isolated yields on the basis of the weight of the pure product obtained.