Table 2.
Entry | Substrate | Time (min) | Conversion (%) | Sulfoxide b | Yield (%)c |
---|---|---|---|---|---|
1 | 80 | 100 | 99 | ||
2 | 120 | 100 | 93 | ||
3 | 75 | 100 | 94 | ||
4 | 50 | 100 | 92 | ||
5 | 35 | 100 | 90 | ||
6 | 70 | 100 | 93 | ||
7 | 50 | 100 | 91 | ||
8 | 60 | 100 | 92 | ||
9 | 48 | 100 | 90 | ||
10 | 30 | 100 | 96 | ||
11 | 26 | 100 | 93 | ||
12 | 45 | 100 | 91 |
a 2 mmol of substrate at room temperature and 8 mmol of 30% aqueous H2O2, in glacial acetic acid (2 mL) at room temperature.
b The products were identified by comparison of physical and spectroscopic properties with authentic compounds.
c Isolated yields on the basis of the weight of the pure product obtained.