Table 2.
No. b | Regression Equation c | r2 | Linear Range (µg/mL) | LOD (µg/mL) | LOQ (µg/mL) | Precision (RSD, %) | Stability (RSD, %) | Recovery (n = 6) | ||
---|---|---|---|---|---|---|---|---|---|---|
Intraday (n = 6) | Interday (n = 18) | Mean, % | RSD, % | |||||||
1 | y = 392.6x − 49.916 | 0.9954 | 0.524–26.2 | 0.0586 | 0.1953 | 2.97 | 3.99 | 3.98 | 102.5 | 3.19 |
2 | y = 630x + 57.152 | 0.9948 | 0.616–30.8 | 0.0177 | 0.0588 | 2.77 | 4.93 | 4.85 | 99.9 | 1.29 |
3 | y = 180160x + 97682 | 0.9970 | 0.425–21.3 | 0.0001 | 0.0004 | 2.16 | 4.14 | 4.02 | 102.6 | 4.81 |
4 | y = 11809x + 4671.1 | 0.9952 | 0.452–22.6 | 0.0018 | 0.0061 | 2.41 | 4.08 | 4.76 | 103.8 | 3.08 |
5 | y = 363.6x + 120.5 | 0.9995 | 0.472–23.6 | 0.0611 | 0.2036 | 2.97 | 4.8 | 4.19 | 104.6 | 1.32 |
6 | y = 3139.2x + 2525 | 0.9963 | 0.472–23.6 | 0.0068 | 0.0227 | 2.41 | 4.53 | 4.59 | 102.7 | 3.89 |
7 | y = 141382x + 94037 | 0.9974 | 0.560–28.0 | 0.0002 | 0.0005 | 3.09 | 3.65 | 4.05 | 104.9 | 2.50 |
8 | y = 3774.2x + 1124.3 | 0.9998 | 0.508–25.4 | 0.0059 | 0.0197 | 2.57 | 4.62 | 4.27 | 103.1 | 4.08 |
9 | y = 4960.3x + 4375.9 | 0.9965 | 0.572–28.6 | 0.0045 | 0.0149 | 2.23 | 4.49 | 4.24 | 104.2 | 2.35 |
10 | y = 5863.7x + 298.23 | 0.9999 | 0.540–27.0 | 0.0038 | 0.0128 | 3.15 | 3.87 | 3.81 | 104.4 | 3.95 |
11 | y = 891.7x + 849.87 | 0.9991 | 0.480–24.0 | 0.0245 | 0.0817 | 3.09 | 4.09 | 4.17 | 103.5 | 3.74 |
12 | y = 905.2x + 781.29 | 0.9991 | 0.476–23.8 | 0.0242 | 0.0807 | 3.92 | 4.2 | 4.44 | 97.8 | 1.20 |
13 | y = 187.1x + 11.88 | 0.9933 | 0.472–23.6 | 0.1181 | 0.3933 | 3.45 | 4.12 | 4.81 | 96.4 | 4.59 |
14 | y = 961.0x − 72.951 | 0.9948 | 0.496–24.8 | 0.0243 | 0.0809 | 2.34 | 4.17 | 4.28 | 95.2 | 2.78 |
15 | y = 210.9x − 44.971 | 0.9980 | 0.480–24.0 | 0.1088 | 0.3623 | 2.89 | 3.09 | 3.24 | 102 | 3.11 |
16 | y = 338x − 21.961 | 0.9968 | 0.447–22.4 | 0.0668 | 0.2224 | 3.02 | 3.45 | 3.66 | 98.6 | 2.82 |
17 | y = 618x − 5.3866 | 0.9996 | 0.424–21.2 | 0.0364 | 0.1213 | 3.22 | 3.4 | 3.27 | 105.7 | 1.62 |
18 | y = 735x − 23.523 | 0.9967 | 0.480–24.0 | 0.0315 | 0.1048 | 3.16 | 3.78 | 4.03 | 104.5 | 3.80 |
19 | y = 3232.4x + 849.76 | 0.9992 | 0.584–29.2 | 0.0068 | 0.0227 | 3.23 | 4.85 | 4.33 | 97.7 | 3.16 |
20 | y = 11236x − 5692 | 0.9967 | 0.588–29.4 | 0.0020 | 0.0067 | 2.18 | 4.34 | 4.68 | 99.8 | 1.01 |
21 | y = 2574.4x + 2231.2 | 0.9994 | 0.620–31.0 | 0.0086 | 0.0285 | 3.2 | 3.75 | 3.61 | 97.5 | 4.05 |
22 | y = 5387.7x − 845.81 | 0.9957 | 0.504–25.2 | 0.0041 | 0.0138 | 2.09 | 3.63 | 3.73 | 101.1 | 3.41 |
23 | y = 135.8x + 173.86 | 0.9958 | 0.628–31.4 | 0.1607 | 0.5352 | 2.62 | 3.58 | 3.18 | 95.5 | 4.88 |
24 | y = 402.8x + 122.7 | 0.9989 | 0.488–24.4 | 0.0559 | 0.186 | 2.31 | 3.87 | 3.94 | 98.9 | 2.49 |
25 | y = 548.0x − 5.2532 | 0.9970 | 0.504–25.2 | 0.0419 | 0.1394 | 3.48 | 4.24 | 4.26 | 98.2 | 3.08 |
26 | y = 283.7x + 154.16 | 0.9994 | 0.744–37.2 | 0.0789 | 0.2627 | 2.34 | 3.76 | 3.45 | 97.2 | 3.31 |
27 | y = 860x − 3.1856 | 0.9992 | 0.700–35.0 | 0.0263 | 0.0875 | 2.76 | 3.65 | 3.45 | 100.5 | 2.62 |
28 | y = 1042x + 83.479 | 0.9980 | 0.752–37.6 | 0.0212 | 0.0705 | 2.64 | 4.13 | 2.16 | 100.0 | 1.17 |
29 | y =518x + 31.816 | 0.9980 | 0.588–29.4 | 0.04308 | 0.1435 | 2.81 | 4.42 | 4.38 | 99.3 | 4.94 |
30 | y = 136x + 100.17 | 0.9999 | 0.708–35.4 | 0.1625 | 0.5412 | 3.23 | 4.87 | 4.91 | 103.2 | 1.69 |
31 | y = 861x + 98.616 | 0.9962 | 0.524–26.2 | 0.0253 | 0.0843 | 2.59 | 3.9 | 3.55 | 98 | 3.40 |
32 | y = 539x − 15.987 | 0.9973 | 0.628–31.4 | 0.0416 | 0.1385 | 2.59 | 3.33 | 3.75 | 97.5 | 2.71 |
33 | y = 295.7x + 241.23 | 0.9972 | 0.592–29.6 | 0.0749 | 0.2494 | 2.38 | 3.63 | 3.52 | 102.5 | 2.08 |
34 | y = 550.3x + 519.33 | 0.9901 | 0.640–32.0 | 0.0412 | 0.1373 | 2.66 | 4.79 | 4.40 | 105.4 | 2.92 |
35 | y = 780x + 24.97 | 0.9984 | 0.816–40.8 | 0.0272 | 0.0905 | 2.75 | 4.78 | 4.18 | 97.4 | 2.88 |
36 | y = 940x − 21.517 | 0.9999 | 0.704–35.2 | 0.0178 | 0.0592 | 2.9 | 4.39 | 4.83 | 96.2 | 3.80 |
37 | y = 368x − 19.204 | 0.9985 | 0.596–29.8 | 0.0624 | 0.2079 | 2.79 | 4.71 | 4.73 | 97.7 | 3.56 |
38 | y = 465x + 432.16 | 0.9979 | 0.560–28.0 | 0.0465 | 0.1548 | 2.94 | 3.89 | 3.96 | 98.5 | 4.06 |
39 | y = 266.5x + 5.1122 | 1.000 | 0.720–36.0 | 0.0845 | 0.2813 | 2.15 | 3.12 | 3.27 | 96.5 | 3.13 |
40 | y = 162x − 17.799 | 0.9999 | 0.492–24.6 | 0.1457 | 0.4852 | 2.99 | 3.24 | 3.41 | 105.0 | 4.00 |
a The sample was prepared from No. 1; b The 40 analytes was the same as in Table 1; c x is the concentration of each compound in µg/mL; y is the peak area of the respective compound.