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. 2010 Aug 27;15(9):5866–5877. doi: 10.3390/molecules15095866

Table 2.

1H- and 13C-NMR data for compounds 1-2 (CDCl3, δ in ppm and J in Hz).

Position 1 2
δH δC δH δC
1a 1.39 (m) 32.1 38.5
1b 167 (m)
2 1.49 (m) 27.5 2.24 ddd (14.3, 14, 6.4) 35.1
1.85 (m) 2.75 ddd (14.3, 3.6, 3.4)
3 4.68 (s br) 78.3 216.8; 216.7
4 36.9 47.9
5 1.79 (m) 46.1 1.82 (m) 52.5; 52.4
6 1.73 (m) 22.9 1.70 (m) 23.3
7 5.23 (d, 2.4) 118.2; 118.1 5.28 br 118.2; 118.1
8 146.0; 145.9 145.8; 145.6
9 2.30 (t, 7.6); 2.2 (t, 7.6) 49.7; 48.8 49.6; 48.4
10 34.9 34.9
11 1.54 (m) 17.4 17.8
12a 1.53 (m) 35.3 35.2
12b 1.98 (m)
13 43.8; 43.6 43.8; 43.6
4 50.9; 50.4 50.8; 50.5
15 1.55 (m) 34.2 34.3
16 1.61 (m) 27.5; 27.1 27.5; 27.3
17 2.01 (m); 2.04 (m) 47.1; 45.2 2.03 (m); 2.06 (m) 47.1; 45.2
18 0.90 (s) 23.9 0.80 (s); 085 (s) 24.6
19 0.76 (s) 13.0 12.8
20 1.71 (m) 33.8; 31.7 33.8; 31.7
21 5.33 (d, 2.8); 5.29 (d,2.8) 101.8; 97.8 101.8; 97.8
22 1.98 (m) 31.5; 31.3 31.5; 31.3
23 3.89 (m); 3.83 (m) 78.5; 77.0 3.88 (m); 3.84 (m) 78.5; 77.1
24 2.82 (d, 7.6); 2.67(d,7.6) 67.8; 65.3 2.81 (d, 7.6); 2.67 (d, 7.6) 67.8; 65.4
25 58.0; 57.2 58.0; 57.2
26a) 1.29 (s); 1.28 (s) 25.0; 24.9 1.29(s); 1.28 (s) 25.0; 24.9
27a) 1.27 (s) 19.4; 19.2 1.26 (s) 19.5; 19.2
28 0.81 (s) 27.6 0.97 (s) 24.4
29 0.95 (s) 21.4 0.98 (s) 21.6
30 0.98 (s); 0.96 (s) 22.6; 22.3 1.00 (s); 1.07 (s) 22.6
1′ 167.5
2′ 129.2
3′ 6.80 (qq, 6.8, 1.6) 136.6
4′ 1.75 (d, 6.8) 14.4
5′ 1.81 (s) 12.2

a) values within any column may be interchanged.