. 2012 Jan 4;17(1):420–432. doi: 10.3390/molecules17010420

Table 1.

MS data for icariin, baohuoside I, epimedin A, epimedin C and their metabolites after zebrafish exposure for 24 h.

Compounds	Retention time (min)	quasi-molecular ions				MW	Metabolite presumed	Zebrafish		Current metabolism (references)
Compounds	Retention time (min)	[M−H]⁻	[M+HCOO]⁻	[M+H]⁺	[M+Na]⁺	MW	Metabolite presumed	solution	body	Current metabolism (references)
Icariin	19.81	675.26	721.70	677.88	699.58	676	Icariin	+	+
	25.91	513.91		515.83	537.81	514	Baohuoside I	+	+	[10,11]
Baohuoside I	25.91	513.84		515.76	537.88	514	Baohuoside I	+	+	[11]
Epimedin A	19.00	837.73	883.62	839.72	861.84	838	Epimedin A	+
	25.88	513.84		515.76	537.88	514	Baohuoside I	+
Epimedin C	19.41	821.79	867.68	823.71	845.49	822	Epimedin C	+
	24.51	659.74		661.87	683.71	660	2" -O-rhamnosylicariside II	+		[13]

+ detected.