Table 2.
Reaction Time [h] | |||||||
---|---|---|---|---|---|---|---|
0.5 | 1.0 | 1.5 | 2.0 | 2.5 | 3.0 | 24 | |
Temperature 0 °C | |||||||
S1,2-EL | 68 | 57 | 28 | 11 | 11 | 4 | 4 |
Sdiol of 1,2-EL | 6 | 7 | 10 | 12 | 12 | 13 | 13 |
Scarvone | 5 | 10 | 19 | 13 | 13 | 9 | 8 |
Scarveol | 0 | 0 | 0 | 0 | 0 | 3 | 5 |
Sperillyl alcohol | 21 | 26 | 43 | 64 | 64 | 71 | 70 |
Climonene | 5 | 5 | 6 | 6 | 6 | 18 | 18 |
Sorg.comp./H2O2 | 8 | 9 | 10 | 10 | 10 | 27 | 27 |
Temperature 40 °C | |||||||
S1,2-EL | 48 | 29 | 13 | 9 | 6 | 3 | 3 |
Sdiol of 1,2-EL | 6 | 7 | 10 | 10 | 11 | 11 | 11 |
Scarvone | 13 | 14 | 14 | 14 | 14 | 16 | 16 |
Scarveol | 1 | 4 | 4 | 5 | 5 | 5 | 5 |
Sperillyl alcohol | 32 | 46 | 59 | 62 | 64 | 65 | 65 |
Climonene | 9 | 13 | 15 | 21 | 22 | 37 | 40 |
Sorg.comp./H2O2 | 19 | 25 | 30 | 40 | 40 | 62 | 54 |
Temperature 80 °C | |||||||
S1,2-EL | 26 | 15 | 8 | 6 | 5 | 4 | 3 |
Sdiol of 1,2-EL | 8 | 10 | 11 | 11 | 11 | 13 | 13 |
Scarvone | 8 | 12 | 12 | 13 | 15 | 16 | 17 |
Scarveol | 2 | 2 | 2 | 2 | 2 | 2 | 3 |
Sperillyl alcohol | 56 | 61 | 67 | 68 | 67 | 65 | 64 |
Climonene | 17 | 22 | 29 | 33 | 36 | 42 | 46 |
Sorg. comp./H2O2 | 36 | 43 | 52 | 52 | 54 | 59 | 64 |
Temperature 120 °C | |||||||
S1,2-EL | 20 | 11 | 5 | 5 | 3 | 2 | 0 |
Sdiol of 1,2-EL | 10 | 10 | 11 | 11 | 12 | 12 | 12 |
Scarvone | 12 | 14 | 16 | 16 | 17 | 17 | 19 |
Scarveol | 2 | 2 | 3 | 3 | 3 | 4 | 4 |
Sperillyl alcohol | 56 | 63 | 65 | 65 | 65 | 65 | 65 |
Climonene | 23 | 29 | 32 | 35 | 40 | 52 | 52 |
Sorg.comp./H2O2 | 30 | 34 | 37 | 41 | 46 | 59 | 57 |
EL—epoxylimonene, S—selectivities of the appropriate products, C—conversion, Sorg.comp./H2O2 selectivity of transformation to organic compounds in relation to hydrogen peroxide consumed.