Umbilicaxanthoside B (CDCl3) | ||
---|---|---|
Position | δC | δH (J in Hz) |
1 | 151.0 | - |
1–OH | - | 13.30 (s) (1H) |
2 | 117.8 | - |
3 | 119.4 | 6.47 (s) (1H) |
4 | 143.2 | - |
4–OCH3 | 56.3 | 3.75 (s) (3H) |
4a | 141.3 | - |
5 | 147.1 | - |
6 | 103.7 | 6.23 (s) (1H) |
7 | 153.2 | - |
8 | 118.4 | - |
8a | 129.6 | - |
9 | 183.1 | - |
9a | 114.6 | - |
10a | 135.7 | - |
1′ | 25.4 | 3.38 (d, 7.2) (2H) |
2′ | 123.8 | 5.39 (td, 7.2, 1.2) (1H) |
3′ | 130.9 | - |
4′ | 26.2 | 1.65 (s) (3H) |
5′ | 18.4 | 1.79 (s) (3H) |
1″ | 26.1 | 4.19 (d, 6.8) (2H) |
2″ | 124.8 | 5.37 (td, 6.8, 1.5) (1H) |
3″ | 132.0 | - |
4″ | 25.9 | 1.67 (s) (3H) |
5″ | 18.0 | 1.84 (s) (3H) |
1‴ | 99.8 | 5.05 (d, 8.1) (1H) |
2‴ | 74.2 | 3.52 (dd, 8.9, 8.1) (1H) |
3‴ | 76.9 | 3.58 (t, 8.9) (1H) |
4‴ | 78.2 | 3.12 (dd, 9.3, 8.9) (1H) |
5‴ | 78.7 | 3.45 (m) (1H) |
6‴ | 62.6 | 3.93 (dd, 12.1, 2.3) (1H) |
3.72 (dd, 12.1, 5.2) (1H) | ||
1’’’’ | 104.1 | 5.15 (d, 8.0) (1H) |
2’’’’ | 73.8 | 3.52 (dd, 9.0, 8.0) (1H) |
3’’’’ | 76.5 | 3.58 (t, 9.0) (1H) |
4’’’’ | 69.7 | 3.41 (t, 9.0) (1H) |
5’’’’ | 76.9 | 3.45 (m) (1H) |
6’’’’ | 62.6 | 3.93 (dd, 12.1, 2.2) (1H) |
3.72 (dd, 12.1, 5.2) (1H) |