Table 1.
Compound | Conjugation | Fresh | 100 °C 10 min | 100 °C 20 min | 100 °C 30 min | 100 °C 40 min | 115 °C 20 min | 121 °C 20 min |
---|---|---|---|---|---|---|---|---|
Ferulic acid | free | 2.98 ± 0.01 a | 2.91 ± 0.01 b | 2.93 ± 0.01 b | 2.83 ± 0.01 c | 2.83 ± 0.01 c | 2.92 ± 0.03 b | 2.73 ± 0.01 d |
bound | 2.92 ± 0.43 e | 3.57 ± 0.01 bc | 3.24 ± 0.02 c,d | 4.16 ± 0.05 a | 4.10 ± 0.01 a | 3.88 ± 0.01 a,b | 3.58 ± 0.01 b,c | |
Chlorogenic acid | free | 18.28 ± 0.14 d | 15.16 ± 0.13 e | 18.80 ± 0.12 c | 18.81 ± 0.08 c | 22.42 ± 0.01 a | 21.13 ± 0.28 b | 21.17 ± 0.16 b |
bound | ND | ND | ND | ND | ND | ND | ND | |
Gallic acid | free | 9.76 ± 0.30 d | 9.61 ± 0.09 d | 12.93 ± 0.06 a | 11.72 ± 0.03 c | 12.54 ± 0.02 b | 4.99 ± 0.11 e | 5.32 ± 0.01 e |
bound | 5.55 ± 0.01 a | 2.86 ± 0.01 e | 2.92 ± 0.01 d | 2.85 ± 0.01 e | 2.86 ± 0.01 e | 3.94 ± 0.01 c | 5.47 ± 0.01 b | |
Vanillic acid | free | 6.38 ± 0.14 b | 6.47 ± 0.01 a,b | 6.38 ± 0.01 b | 6.54 ± 0.01 a,b | 6.65 ± 0.01 a | 6.47 ± 0.11 a,b | 6.52 ± 0.04 a,b |
bound | ND | ND | ND | ND | ND | ND | ND | |
Syringate | free | 3.95 ± 0.06 a | 2.74 ± 0.02 e | 3.43 ± 0.02 b | 3.26 ± 0.09 c | 2.97 ± 0.05 d | 3.19 ± 0.07 c | 2.72 ± 0.01 e |
bound | ND | ND | ND | ND | ND | ND | ND | |
Quercetin | free | 1.70 ± 0.11 a | 0.40 ± 0.01 d | 0.53 ± 0.01 c,d | 0.59 ± 0.04 c,d | 0.37 ± 0.01 d | 1.39 ± 0.19 b | 0.63 ± 0.01 c |
bound | 0.90 ± 0.01 c | 1.62 ± 0.01 a | 1.13 ± 0.10 b | 0.75 ± 0.06 d | 0.99 ± 0.05 b,c | 0.84 ± 0.01 c,d | 1.58 ± 0.07 a | |
p-Coumaric acid | free | 2.38 ± 0.01 c,d | 2.39 ± 0.01 c | 2.39 ± 0.01 c | 2.39 ± 0.01 c | 2.37± 0.01 d | 2.43± 0.01 b | 2.52± 0.01 a |
bound | 2.41 ± 0.01 d,e | 2.77 ± 0.01 a | 2.42 ± 0.01 c,d | 2.43 ± 0.01 c | 2.41± 0.01 d,e | 2.43± 0.01 c | 2.46 ± 0.01 b |
Notes: Unit, mg/100 g FW. Turkey tests were carried out in each row and significant differences (p < 0.05) exist among those with different letters. ND means not detected.