Table 1.
Analysis of the iron oxidation kinetics in HuHF, HL, and HosF shown in Figures 1 and 2. The experimental conditions are provided in the caption of Figure 1.
| HuHF | (Assuming 24 H) | ||||
| FeII/shell added | Experimentally calculated [FeII] | Remaining [FeII] in solution | [FeIII] at the transition point (between Phase I and Phase II) | FeIII/shell at transition | FeIII/H-chain at transition |
| 500 | 249 ± 13 | 214 ± 11 | 36 ± 2 | 71 ± 5 | 2.9 ± 0.2 |
| 400 | 211 ± 2 | 172 ± 3 | 39 ± 1 | 79 ± 2 | 3.3 ± 0.1 |
| 300 | 155 ± 2 | 122 ± 4 | 33 ± 2 | 66 ± 4 | 2.7 ± 0.1 |
| 200 | 101 ± 3 | 77 ± 1 | 24 ± 3 | 48 ± 5 | 2.0 ± 0.1 |
| 100 | 50 ± 2 | 30 ± 1 | 20 ± 1 | 41 ± 1 | 2.5 ± 0.1 |
| -- | Average | 2.6 ± 0.4 | |||
| HL | -- | (Assuming 21 H) | |||
| 500 | 284 ± 37 | 256 ± 35 | 28 ± 2 | 56 ± 3 | 2.6 ± 0.1 |
| 400 | 195 ± 3 | 171 ± 2 | 24 ± 2 | 48 ± 3 | 2.2 ± 0.1 |
| 300 | 148 ± 5 | 120 ± 1 | 27 ± 5 | 55 ± 10 | 2.5 ± 0.4 |
| 250 | 122 ± 10 | 99 ± 3 | 23 ± 6 | 47 ± 13 | 2.1 ± 0.5 |
| 200 | 105 ± 1 | 83 ± 1 | 22 ± 1 | 43 ± 3 | 2.0 ± 0.2 |
| 150 | 73 ± 1 | 52 ± 3 | 21 ± 3 | 41 ± 6 | 1.9 ± 0.3 |
| -- | Average | 2.2 ± 0.3 | |||
| HosF | -- | (Assuming 3.3 H) | |||
| 40 | 212 ± 6 | 157 ± 6 | 55 ± 1 | 11 ± 1 | 3.3 ± 0.03 |
| 32 | 172 ± 4 | 115 ± 1 | 57 ± 3 | 11 ± 1 | 3.3± 0.18 |
| 24 | 126 ± 2 | 77 ± 1 | 49 ± 1 | 10 ± 1 | 3.0 ± 0.003 |
| 16 | 94 ± 1 | 55 ± 4 | 38 ± 3 | 8 ± 1 | 2.4 ± 0.21 |
| Average | 3.0 ± 0.5 |