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. 2019 Jul 3;6(13):1970080. doi: 10.1002/advs.201970080

Diseleno[3,2‐b:2′,3′‐d]selenophenes: Diseleno[3,2‐b:2′,3′‐d]selenophene‐Containing High‐Mobility Conjugated Polymer for Organic Field‐Effect Transistors (Adv. Sci. 13/2019)

Soo‐Young Jang 1,2, In‐Bok Kim 1, Minji Kang 1, Zuping Fei 2, Eunhwan Jung 3, Thomas McCarthy‐Ward 2, Jessica Shaw 2, Dae‐Hee Lim 4, Yeon‐Ju Kim 4, Sanjay Mathur 3, Martin Heeney 2, Dong‐Yu Kim 1,4
PMCID: PMC6662384

Abstract

In article number 1900245, Martin Heeney, Dong‐Yu Kim, and co‐workers describe an organic field‐effect transistor featuring a semiconducting polymer, PDSSTV, in its channel layer. The newly developed unit of three‐fused selenophenes enables the polymer to have a strong intermolecular interaction caused by large and polarizable orbitals of selenium. The PDSSTV demonstrates its maximum hole mobility of 2.1 cm2 V−1 s−1 at a low operating voltage, –30 V.

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Keywords: conjugated polymers; diseleno[3,2‐b:2′, 3′‐d]selenophenes; intermolecular interactions; organic field‐effect transistors


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