Table 3.
Rates, rate constants (kobs) and half-lives for methyl red degradation using ClInOCPc/PAN and MNP-ClInOCPc/PAN.
| [MR] ×10−5 mol/L | kobs (min−1) |
Initial rate (×10−7 mol L−1 min−1 |
Half-life (min) |
||||||
|---|---|---|---|---|---|---|---|---|---|
| ClInOCPc/PAN | MNP-ClInOCPc/PAN | MNP-ClInOCPc/PAN (re-used) | ClInOCPc/PAN | MNP-ClInOCPc/PAN | MNP-ClInOCPc/PAN (re-used) | ClInOCPc/PAN | MNP-ClInOCPc/PAN | MNP-ClInOCPc/PAN (re-used) | |
| 4.5 | 0.0166 | 0.0235 | 0.0183 | 7.5 | 10.6 | 8.3 | 41.8 | 29.5 | 37.9 |
| 7.9 | 0.009 | 0.0126 | 0.0094 | 7.1 | 9.9 | 7.4 | 77.0 | 55.0 | 73.7 |
| 12.7 | 0.0023 | 0.0041 | 0.0032 | 2.9 | 5.2 | 4.1 | 301.4 | 169.1 | 216.6 |
| 15.3 | 0.002 | 0.0022 | 0.0017 | 3.1 | 3.8 | 2.6 | 346.6 | 315.1 | 407.7 |
| 17.2 | 0.0011 | 0.0009 | 0.0012 | 1.9 | 1.5 | 0.7 | 630.1 | 770.2 | 577.6 |