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. 2019 Sep 12;4(13):15729–15733. doi: 10.1021/acsomega.9b02406

Converting Waste Polyethylene into ZnCCo3 and ZnCNi3 by a One-Step Thermal Reduction Process

Liangbiao Wang †,*, Weicheng Dai †, Qinglin Cheng †, Kailong Zhang †,*, Tinghai Yang †, Tao Mei ‡,*, Zhiwei Xu †, Fuyu Chen †, Longwei Zhu †, Yitai Qian §
PMCID: PMC6761740  PMID: 31572876

Abstract

graphic file with name ao9b02406_0008.jpg

Plastic products have brought us great convenience in our daily life and work. But in the meantime, waste plastics have become solid pollutants in the environment due to its poor degradability. The resource utilization of waste plastic can decrease environmental pollution. Here, a thermal reduction method for the conversion of waste polyethylene to ZnCCo3 and ZnCNi3 in a stainless-steel autoclave under mild conditions has been reported. X-ray powder diffraction patterns indicate that the obtained samples are anti-perovskite-structured ternary carbides (ZnCCo3 and ZnCNi3) with good crystallinity. Moreover, the formation mechanism of ternary carbides has been briefly discussed. This method can be developed into an effective method for disposal of other waste plastics.

1. Introduction

Since the remarkable discovery of superconductivity at 8 K in MgCNi3,1 the anti-perovskite-structured compounds (ternary carbides and nitrides) have attracted great attention due to their excellent physical properties such as giant magnetoresistance effect,2,3 negative thermal expansion,4 nearly zero temperature resistivity coefficient,5−7 giant barocaloric effect,8 magnetostriction,9 spin-glass behavior,10−13 phase separation,14 and magnetocaloric effect.15

Up to now, considerable efforts have been made to explore new methods to synthesize ternary carbides with anti-perovskite structure, including repeated sintering,1 self-propagating high-temperature synthesis,16 the mechanical alloying method,17 and conventional powder metallurgy.18 Xia and co-workers have synthesized MgCNi3 bulk materials at 850 °C for several tens of minutes through a hybrid microwave heating method.19 Single crystalline MgCNi3 of several hundred micrometers in size can also be successfully synthesized by heat treatment of a mixture of carbon, metallic Mg, and Ni powders under high-pressure (4.25 GPa) conditions at 1200 °C for 1 h.20 Rana and co-workers have synthesized ternary carbides (MgCNi3 or MgCxCo3) encapsulated in carbon nanoflasks by using metallic Mg–EtOH powder and Ni(CO)4 or cobalt tricarbonyl nitrosyl as starting materials at 1000 °C for 3 h.21,22 Y3AlCx (x = 0.8, 1, 1.2, and 1.5) samples can also be synthesized by arc-melting and subsequent annealing.23 Tong and his co-workers have synthesized a series of ternary carbides with anti-perovskite structure from the corresponding elements by a direct solid-state reaction.2,7,12 However, as we have seen, there are few research studies on the preparation and properties of ZnCCo3 and ZnCNi3. In this paper, a facile procedure for the preparation of ZnCCo3 and ZnCNi3 by a chemical reaction under mild conditions has been reported.

Plastic products have been used widely in the industrial fields and in daily life due to their excellent properties such as light, high transparency, low cost, durability, and good corrosion resistance. However, solid pollutants caused by waste plastics have become more and more serious with the increasing use of plastic products. Thus, resource utilization of waste plastics is helpful for environmental protection. Recently, some effort has been made to convert waste plastics into valuable carbon-based materials. Different forms of carbon materials have been prepared by utilizing waste plastic (poly(ethylene terephthalate), poly(tetrafluoroethylene), polyethylene (PE), etc.) as a carbon source.24−29 Waste plastic can also be used as a carbon source to prepare carbide materials (SiC, TiC, ZrC, VC, NbC, Cr3C2, Cr2AlC, etc.).30−36 You and co-workers have synthesized NiO nanorods, monolayer graphene, and SiC nanowires from waste materials through a green chemical vapor method.37 The above approaches of converting waste plastic to valuable materials can deliver important significance in environmental protection.

Herein, a one-step thermal reduction process is designed to produce ZnCCo3 and ZnCNi3 by using waste PE as a carbon source in a stainless-steel autoclave at 800 °C. This study provides a simple and effective route for converting waste plastics into high-value carbide materials. The reaction temperature used in our method for the production of ternary carbides is lower than those of the reported methods.

2. Results and Discussion

The Fourier transform infrared (FTIR) spectrum was used to investigate the chemical structure of waste plastic bags. From the FTIR spectrum (Figure 1), the main chemical composition was high-density polyethylene. The phase structure and purity of the obtained sample were investigated by X-ray powder diffraction (XRD). Figure 2 shows the XRD pattern of the ZnCCo3 sample. Three diffraction peaks in the XRD pattern located at 2θ = 41.97, 48.91, and 71.61° could be indexed as the (111), (200), and (220) diffraction planes of the cubic phase ZnCCo3 with a lattice constant of a = 3.734 Å, which is in agreement with the reported data (JCPDS cards No. 29-0524, a = 3.730 Å). All of the above results prove that the obtained sample is anti-perovskite-structured ZnCCo3. The yield of ZnCCo3 is calculated to be about 56%, according to the quality of ZnCCo3 and raw material (metallic cobalt).

Figure 1.

Figure 1

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FTIR spectrum of waste plastic bags.

Figure 2.

Figure 2

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Typical XRD pattern of the obtained ZnCCo3 sample.

The morphology, microstructure, and composition of the obtained ZnCCo3 sample were further investigated with scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), and energy-dispersive X-ray (EDX). The SEM image of the obtained ZnCCo3 sample is shown in Figure 3a, which reveals that the ZnCCo3 sample is composed of particles with different sizes. A typical TEM image (shown in Figure 3b) shows that the size of ZnCCo3 particles is in the range of 50–200 nm. The HRTEM image (shown in Figure 3c) shows that the crystal lattice spacing of 0.37 nm corresponds to the d spacing values of the (100) and (010) planes of cubic phase ZnCCo3. A typical selected-area electron diffraction (SAED) pattern of the obtained ZnCCo3 particles (inset of Figure 3c) recorded along the ⟨001⟩ zone axis confirms that the obtained ZnCCo3 particles are well crystalline, and the diffraction spots can be indexed to the diffractions of cubic phase ZnCCo3, which is close to the result of the XRD pattern (Figure 2). The EDX spectrum taken from the obtained ZnCCo3 particles is shown in Figure 3d, which shows intense peaks of C, Cu, Zn, and Co. The Cu signals come from the TEM grid. The EDX spectrum indicates that the obtained ZnCCo3 particles consist of C, Zn, and Co.

Figure 3.

Figure 3

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(a) SEM image of the obtained ZnCCo3 sample; (b) a typical TEM image of the obtained ZnCCo3 sample; (c) HRTEM image of the obtained ZnCCo3 sample (inset shows the corresponding SAED pattern); and (d) EDX pattern.

All of the three diffraction peaks in Figure 4 (XRD pattern of the obtained ZnCNi3 sample) located at 2θ = 42.88, 49.93, and 73.27° could be indexed as the (111), (200), and (220) planes of anti-perovskite-structured ZnCNi3 with a lattice constant of a = 3.650 Å, which is consistent with the earlier report by Park and co-workers (a = 3.660 Å).38 The yield of ZnCNi3 is calculated to be about 68%, according to the quality of ZnCNi3 and raw material (metallic nickel). SEM image and TEM image are shown in Figure 5a,b, respectively, which clearly show that the ZnCNi3 sample consists of nanoparticles with an average particle size of 40 nm.

Figure 4.

Figure 4

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Typical XRD pattern of the obtained ZnCNi3 sample.

Figure 5.

Figure 5

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(a) SEM image and (b) TEM image of the obtained ZnCNi3 sample.

The magnetic behavior is of great importance for the practical applications of materials. The magnetic properties of the ternary carbides were investigated at room temperature. The magnetic hysteresis curves for the obtained ZnCCo3 and ZnCNi3 samples are shown in Figure 6a,b, respectively. The hysteresis loop of ZnCCo3 and ZnCNi3 exhibits a ferromagnetic behavior. The magnetization, magnetic coercivity, and remanent magnetization of ZnCCo3 particles are 2.73 emu/g, 68 Oe, and 0.14 emu/g, respectively. The magnetization, magnetic coercivity, and remnant magnetization of ZnCNi3 nanoparticles are 0.11 emu/g, 173.9 Oe, and 0.02 emu/g, respectively. Due to the lack of preparation methods of the anti-perovskite-structured carbides, the magnetic properties of the pure ZnCCo3 and ZnCNi3 have not been reported. Therefore, further work of the magnetic properties is underway to understand the relationship between nanostructure and magnetism in those materials.

Figure 6.

Figure 6

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Magnetization data (M–H) of the obtained sample: (a) the obtained ZnCCo3 sample and (b) the obtained ZnCNi3 sample.

In our present approach to synthesize the anti-perovskite-structured ternary carbide, a possible formation mechanism is proposed. With the temperature increasing, metallic sodium reacts with zinc chloride to produce nascent zinc (Zn*) and sodium chloride (eq 1) Meanwhile, waste PE decomposed generating nascent carbon (C*) and H2 (eq 2). The nascent Zn and nascent C (with high reactivity) can react with transition metal (cobalt or nickel) to produce ternary carbides (ZnCCo3 or ZnCNi3) at a low temperature of 800 °C [eq 3]. Based on free-energy calculations, reaction 1 is thermodynamic, spontaneous (ΔrGm = −379.28 kJ/mol), and highly exothermic (ΔrHm = −405.93 kJ/mol). From the ΔrHm value of reaction 1, it can be seen that a large amount of heat has been generated from reaction 1, which is conducive to the formation of ternary carbides at low temperature. Therefore, the possible formation process of MgCNi3 can be described as follows

2. 1
2. 2
2. 3

All of the total reaction process could also be represented as follows

2.

3. Conclusions

In this study, anti-perovskite-structured ZnCCo3 and ZnCNi3 have been successfully synthesized by a facile one-step chemical reaction at a relatively low temperature of 800 °C. This work provides an effective method to convert waste PE to valuable ternary carbide with anti-perovskite structure. The magnetic behaviors of the obtained samples have been briefly investigated. This synthesis method can be applied to prepare other ternary carbides.

4. Experimental Section

4.1. Reagents

Waste polyethylene used in our experiments was recovered from plastic bags (main components: PE). All of the other reagents were of analytical purity and purchased from Sinopharm Chemical Reagent Co., Ltd.

4.2. Preparation of ZnCCo3 Particles

In a typical synthesis process, zinc chloride (2.70 g), cobalt metal (1.80 g), waste polyethylene (1.00 g) and sodium metal (2.00 g) were added into a stainless-steel autoclave of about 20 mL capacity. After sealing tightly, the autoclave was heated in an electronic furnace from room temperature to 10 °C/min at 800 °C and maintained at 800 °C for 10 h. After the autoclave was naturally cooled to room temperature, a black sample was collected from the autoclave and washed with anhydrous alcohol to remove excess metallic sodium. The sample was then washed with diluted hydrochloric acid and distilled water to remove other impurities. Finally, the obtained sample was dried at 50 °C under vacuum for further identification.

4.3. Preparation of ZnCNi3 Nanoparticles

The experimental procedure for the preparation of ZnCNi3 is similar to that employed to produce ZnCNi3, except that metallic cobalt was substituted by metallic nickel (1.80 g). The preparation procedures are summarized diagrammatically in Scheme 1.

Scheme 1. Procedures for the Preparation of ZnCCo3 and ZnCNi3.

Scheme 1

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4.4. Samples’ Characterization

The phase of the obtained samples was investigated by X-ray powder diffraction (XRD), using a Philips X’pert X-ray diffractometer (Cu Kα λ = 1.54178 Å). The microstructures of the obtained samples were derived from scanning electron microscopy images (FESEM, JEOL-JSM-6700F). The magnetic hysteresis loop was determined by a vibrating sample magnetometer (VSM, BHV-55). Transmission electron microscopy (TEM) image, high-resolution transmission electron microscopy (HRTEM) image, selected-area electron diffraction (SAED) pattern, and energy-dispersive X-ray spectrum (EDX) analysis were carried out on a JEOL-2010 transmission electron microscope (at an accelerating voltage of 200 kV). The magnetic properties were investigated on a SQUID magnetometer.

Acknowledgments

We acknowledge the financial support from the Natural Science Foundation of Jiangsu Province (Grant no. BK20160292), National Natural Science Foundation of China (Grant nos. 21701061, 51872129, 21831006), and the Changzhou Sci&Tech Program (Grant No. CJ20179015).

The authors declare no competing financial interest.

References

  1. He T.; Huang Q.; Ramirez A. P.; Wang Y.; Regan K. A.; Rogado N.; Hayward M. A.; Haas M. K.; Slusky J. S.; Inumara K.; Zandbergen H. W.; Ong N. P.; Cava R. J. Superconductivity in the Non-oxide Perovskite MgCNi3. Nature 2001, 411, 54–56. 10.1038/35079229. [DOI] [PubMed] [Google Scholar]
  2. Wang B. S.; Tong P.; Sun Y. P.; Li L. J.; Tang W.; Lu W. J.; Zhu X. B.; Yang Z. R.; Song W. H. Enhanced Giant Magnetoresistance in Ni-doped Antipervoskite Compounds GaCMn3-xNix (x = 0.05, 0.10). Appl. Phys. Lett. 2009, 95, 222509 10.1063/1.3268786. [DOI] [Google Scholar]
  3. Kamishima K.; Goto T.; Nakagawa H.; Miura N.; Ohashi M.; Mori N.; Sasaki T.; Kanomata T. Giant Magnetoresistance in the Intermetallic Compound Mn3GaC. Phys. Rev. B 2000, 63, 024426 10.1103/PhysRevB.63.024426. [DOI] [Google Scholar]
  4. Iikubo S.; Kodama K.; Takenaka K.; Takagi H.; Takigawa M.; Shamoto S. Local Lattice Distortion in the Giant Negative Thermal Expansion Material Mn3Cu1-xGexN. Phys. Rev. Lett. 2008, 101, 205901 10.1103/PhysRevLett.101.205901. [DOI] [PubMed] [Google Scholar]
  5. Ding L.; Wang C.; Chu L. H.; Yan J.; Na Y. Y.; Huang Q. Z.; Chen X. L. Near Zero Temperature Coefficient of Resistivity in Antiperovskite Mn3Ni1-xCuxN. Appl. Phys. Lett. 2011, 99, 251905 10.1063/1.3671183. [DOI] [Google Scholar]
  6. Chi E. O.; Kim W. S.; Hur N. H. New Mg-based Antiperovskites PnNMg3 (Pn = As, Sb). Solid State Commun. 2001, 120, 307–97. 10.1016/S0038-1098(01)00395-7. [DOI] [Google Scholar]
  7. Lin S.; Wang B. S.; Lin J. C.; Huang Y. N.; Lu W. J.; Zhao B. C.; Tong P.; Song W. H.; Sun Y. P. Tunable Room-temperature Zero Temperature Coefficient of Resistivity in Antiperovskite Compounds Ga1-xCFe3 and Ga1-yAlyCFe3. Appl. Phys. Lett. 2012, 101, 011908 10.1063/1.4732785. [DOI] [Google Scholar]
  8. Matsunami D.; Fujita A.; Takenaka K.; Kano M. Giant Barocaloric Effect Enhanced by the Frustration of the Antiferromagnetic Phase in Mn3GaN. Nat. Mater. 2015, 14, 73–78. 10.1038/nmat4117. [DOI] [PubMed] [Google Scholar]
  9. Asano K.; Koyama K.; Takenaka K. Magnetostriction in Mn3CuN. Appl. Phys. Lett. 2008, 92, 161909 10.1063/1.2917472. [DOI] [Google Scholar]
  10. Sun Y.; Wang C.; Huang Q. Z.; Guo Y. F.; Chu L. H.; Arai M.; Yamaura K. Neutron Diffraction Study of Unusual Phase Separation in the Antiperovskite Nitride Mn3ZnN. Inorg. Chem. 2012, 51, 7232–7236. 10.1021/ic300978x. [DOI] [PubMed] [Google Scholar]
  11. Song B.; Jian J. K.; Bao H. Q.; Lei M.; Li H.; Wang G.; Xu Y. P.; Chen X. L. Observation of Spin-glass Behavior in Antiperovskite Mn3GaN. Appl. Phys. Lett. 2008, 92, 192511 10.1063/1.2931058. [DOI] [Google Scholar]
  12. Wang B. S.; Tong P.; Sun Y. P.; Zhu X. B.; Yang Z. R.; Song W. H.; Dai J. M. Observation of Spin-glass Behavior in Antiperovskite Compound SnCFe3. Appl. Phys. Lett. 2010, 97, 042508 10.1063/1.3469924. [DOI] [Google Scholar]
  13. Zhang X. H.; Yuan Q.; Han J. C.; Zhao J. G.; Jian J. K.; Zhang Z. H.; Song B. Observation of Spin-glass Behavior in Antiperovskite Compound Mn3Cu0.7Ga0.3N. Appl. Phys. Lett. 2013, 103, 022405 10.1063/1.4813412. [DOI] [Google Scholar]
  14. Dhar S.; Brandt O.; Trampert A.; Friedland K. J.; Sun Y. J.; Ploog K. H. Observation of Spin-glass Behavior in Homogeneous (Ga,Mn)N Layers Grown by Reactive Molecular-beam Epitaxy. Phys. Rev. B 2003, 67, 165205 10.1103/PhysRevB.67.165205. [DOI] [Google Scholar]
  15. Yan J.; Sun Y.; Wu H.; Huang Q. Z.; Wang C.; Shi Z. X.; Deng S. H.; Shi K. W.; Lu H. Q.; Chu L. H. Phase Transitions and Magnetocaloric Effect in Mn3Cu0.89N0.96. Acta Mater. 2014, 74, 58–65. 10.1016/j.actamat.2014.04.005. [DOI] [Google Scholar]
  16. Paolone A.; Castellano C.; Palumbo O.; Cordero F.; Cantelli R.; Martinelli A.; Ferretti M. Local Structure Characterization of Superconducting MgCNi3 Prepared by SHS Technique. Phys. C 2007, 454, 77–81. 10.1016/j.physc.2007.01.015. [DOI] [Google Scholar]
  17. Wang H.; Ouyang L. Z.; Zeng M. Q.; Zhu M. Direct Synthesis of MgCNi3 by Mechanical Alloying. Scr. Mater. 2004, 50, 1471–1474. 10.1016/j.scriptamat.2004.03.002. [DOI] [Google Scholar]
  18. Xia Q.-L.; Yi J.-H.; Peng Y.-D.; Luo S.-D.; Wang H.-Z.; Li L.-Y. Synthesis of Superconductor MgCNi3 with Carbon Nanotubes. Chin. Phys. B 2008, 17, 1421–1424. 10.1088/1674-1056/17/4/045. [DOI] [Google Scholar]
  19. Xia Q. L.; Yi J. H.; Huang J. W.; Ye T. M.; Peng Y. D.; Li L. Y. Hybrid Microwave Synthesis of MgCNi3 Superconductor. Supercond. Sci. Technol. 2006, 19, 1282–1284. 10.1088/0953-2048/19/12/011. [DOI] [Google Scholar]
  20. Lee H. S.; Jang D. J.; Lee H. G.; Lee S. I.; Choi S. M.; Kim C. J. Growth of Single Crystals of MgCNi3. Adv. Mater. 2007, 19, 1807–1809. 10.1002/adma.200602194. [DOI] [Google Scholar]
  21. Rana R. K.; Pol V. G.; Felner I.; Meridor E.; Frydman A.; Gedanken A. Encapsulating a Superconducting Material, MgCNi3, in Carbon Nanoflask. Adv. Mater. 2004, 16, 972–975. 10.1002/adma.200306590. [DOI] [Google Scholar]
  22. Rana R. K.; Xu X. N.; Yeshurun Y.; Gedanken A. Fabrication of the MgCxCo3 Ternary Phase Encapsulated in Carbon Nanoflasks. Adv. Mater. 2003, 15, 926–930. 10.1002/adma.200304690. [DOI] [Google Scholar]
  23. Ghule S. S.; Garde C. S.; Ramakrishnan S.; Singh S.; Rajarajan A. K.; Laad M. Synthesis, Physical Properties and Band Structure of Non-magnetic Y3AlC. Phys. B 2016, 498, 98–103. 10.1016/j.physb.2016.06.027. [DOI] [Google Scholar]
  24. Zhang J.; Zhang L.; Yang H.; Kong W.; Liu Y.; Yuan A. Sustainable Processing of Waste Polypropylene to Produce High Yield Valuable Fe/carbon Nanotube Nanocomposites. CrystEngComm 2014, 16, 8832–8840. 10.1039/C4CE01064G. [DOI] [Google Scholar]
  25. Zhang J.; Kong Q.; Yang L.; Wang D. Y. Few Layered Co(OH)2 Ultrathin Nanosheet-based Polyurethane Nanocomposites with Reduced Fire Hazard: from Eco-friendly Flame Retardance to Sustainable Recycling. Green Chem. 2016, 18, 3066–3074. 10.1039/C5GC03048J. [DOI] [Google Scholar]
  26. Zhang J.; Yan B.; Wan S.; Kong Q. Converting Polyethylene Waste into Large Scale One-Dimensional Fe3O4@C Composites by a Facile One-Pot Process. Ind. Eng. Chem. Res. 2013, 52, 5708–5712. 10.1021/ie4004392. [DOI] [Google Scholar]
  27. Su D.; Tang Z.; Xie J.; Bian Z.; Zhang J.; Yang D.; Zhang D.; Wang J.; Liu Y.; Yuan A.; Kong Q. Co, Mn-LDH nanoneedle arrays grown on Ni foam for high performance supercapacitors. Appl. Surf. Sci. 2019, 469, 487–494. 10.1016/j.apsusc.2018.10.276. [DOI] [Google Scholar]
  28. Wei L.; Yan N.; Chen Q. Converting Poly(ethyleneterephthalate) Waste into Carbon Microspheres in a Supercritical CO2 System. Environ. Sci. Technol. 2011, 45, 534–539. 10.1021/es102431e. [DOI] [PubMed] [Google Scholar]
  29. Kong Q.; Wu T.; Zhang J.; Wang D. Y. Simultaneously Improving Flame Retardancy and Dynamic Mechanical Properties of Epoxy Resin Nanocomposites through Layered Copper Phenylphosphate. Compos. Sci. Technol. 2018, 154, 136–144. 10.1016/j.compscitech.2017.10.013. [DOI] [Google Scholar]
  30. Wang L.; Dai W.; Zhao D.; Zhang F.; Zhang K.; Cheng Q.; Luo Z.; He H.; Qian Y. A Simple Route for the Direct Conversion of Waste Plastic to Hafnium Carbide Nanoparticles at Low Temperature. Nanosci. Nanotechnol. Lett. 2019, 11, 1027–1031. 10.1166/nnl.2019.2979. [DOI] [Google Scholar]
  31. Wang L.; Zhang F.; Dai W.; Cheng Q.; Lu J.; Zhang K.; Lin M.; Shen M.; Wang D. One Step Transformation of Waste Polyvinyl chloride to Tantalum Carbide@Carbon Nanocomposite at Low Temperature. J. Am. Ceram. Soc. 2019, 102, 6455–6462. 10.1111/jace.16650. [DOI] [Google Scholar]
  32. Wang L.; Cheng Q.; Qin H.; Li Z.; Lou Z.; Lu J.; Zhang J.; Zhou Q. Synthesis of Silicon Carbide Nanocrystals from Waste Polytetrafluoroethylene. Dalton Trans. 2017, 46, 2756–2759. 10.1039/C6DT04865J. [DOI] [PubMed] [Google Scholar]
  33. Wang L.; Dai W.; Zhang K.; Mei T.; Zhuang H.; Song S.; Yang S.; Zhou Q.; Qian Y. One step Conversion of Waste Polyethylene to Cr3C2 Nanorods and Cr2AlC Particles under Mild Conditions. Inorg. Chem. Front. 2018, 5, 2893–2897. 10.1039/C8QI00856F. [DOI] [Google Scholar]
  34. Wang L.; Li Q.; Mei T.; Shi L.; Zhu Y.; Qian Y. A Thermal Reduction Route to Nanocrystalline Transition Metal Carbides from Waste Polytetrafluoroethylene and Metal Oxides. Mater. Chem. Phys. 2012, 137, 1–4. 10.1016/j.matchemphys.2012.08.008. [DOI] [Google Scholar]
  35. Dai W.; Lu L.; Han Y.; Wang L.; Wang J.; Hu J.; Ma C.; Zhang K.; Mei T. Facile Synthesis of Mo2C Nanoparticles from Waste Polyvinyl Chloride. ACS Omega. 2019, 4, 4896–4900. 10.1021/acsomega.8b02856. [DOI] [PMC free article] [PubMed] [Google Scholar]
  36. Wang L.; Zhang F.; Dai W.; Cheng Q.; Zhang K.; Wu Y.; Xiong Y.; Lu Y.; Wu Q.; He H. The Synthesis of Zirconium Carbide Nanoparticles by Lithium Thermal Reduction of Zirconium Dioxide and Waste Plastic. Chem. Lett. 2019, 48, 604–606. 10.1246/cl.190075. [DOI] [Google Scholar]
  37. You Y.; Mayyas M.; Xu S.; Mansuri I.; Gaikwad V.; Munroe P.; Sahajwalla V.; Joshi P. K. Growth of NiO Nanorods, SiC Nanowires and Monolayer Graphene via a CVD Method. Green Chem. 2017, 19, 5599–5607. 10.1039/C7GC02523H. [DOI] [Google Scholar]
  38. Park M. S.; Giim J.; Park S. H.; Lee Y. W.; Lee S. I.; Choi E. J. Physical properties of ZnCNi3: comparison with superconducting MgCNi3. Supercond. Sci. Technol. 2004, 17, 274–277. 10.1088/0953-2048/17/2/007. [DOI] [Google Scholar]

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