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. 2019 Oct 30;24(21):3922. doi: 10.3390/molecules24213922

Table 1.

Chemical shift values of the anomeric protons in the 1H NMR spectra and chemical shift values of the Ar- and CH2CN bearing carbons of the pyrazole ring in the 13C NMR spectra of the isomeric pyrazolyl nucleosides 3ae, 4ae, 5ae, and 6ae in CDCl3 on a Bruker Avance 300 spectrometer.

Compound C-1′ H Shift in the 1H NMR Spectrum (ppm) Ar- Bearing C Shifts in the 13C NMR Spectrum (ppm) –CH2CN Bearing C Shifts in the 13C NMR Spectrum (ppm)
Series 3 Series 5 Series 3 Series 5 Series 3 Series 5
a 6.13 5.99 144.6 145.9 141.7 142.0
b 6.10 6.02 146.2 145.8 144.0 141.8
c 6.05 5.97 145.4 144.9 141.9 141.9
d 6.05 6.00 145.2 144.7 143.7 141.9
e 6.05 6.00 145.6 143.9 142.3 141.1
Series 4 Series 6 Series 4 Series 6 Series 4 Series 6
a 6.17 6.13 151.0 150.2 137.9 137.7
b 6.16 6.19 150.8 150.7 133.0 133.7
c 6.17 6.16 152.5 149.8 135.8 135.8
d 6.19 6.17 144.1 149.6 134.3 134.6
e 6.17 6.18 149.8 149.2 133.5 134.9