Table 2.
Epoxy Resins and Incorporated Non Phosphorus FR * | wt.% | TTI (s) | pHRR (kW.m−2) | THR (MJ·m−2) | FRI | LOI | UL94 | Ref. |
---|---|---|---|---|---|---|---|---|
0 | 11 | 781 | 142 | — | 21.8 | [169] | ||
(2,4,6-tris(4-boronic-2-thiophene)-1,3,5-triazine (3TT-3BA) | 20 | 17 | 454 | 108 | 3.49 | 31.2 | V-0 | [169] |
0 | 32 | 827 | 116 | — | 21.8 | NR | [28] | |
graphene nanosheet (GN) | 3 | 35 | 560 | 113 | 1.65 | 26.7 | NR | [28] |
0 | 32 | 781 | 107 | — | 21.8 | NR | [29] | |
multiwalled carbon nanotube (MWCNT) | 0.8 | 40 | 473 | 97 | 2.27 | 21.2 | NR | [29] |
0 | 32 | 781 | 107 | — | 21.8 | NR | [30] | |
Organically modified montmorillonite (DK4:two longchain alkyl ammonium modified montmorillonite) (OMMT) | 7 | 40 | 576 | 98 | 1.85 | 23.7 | NR | [30] |
0 | 32 | 781 | 107 | — | 21.8 | NR | [31] | |
organomodified magnesium aluminium layered double hydroxide (OLDH) | 1 | 35 | 543 | 121 | 1.39 | 21.9 | NR | [31] |
organomodified magnesium aluminium layered double hydroxide (OLDH) | 5 | 35 | 521 | 104 | 1.68 | 23.6 | V-0 | [31] |
organomodified magnesium aluminium layered double hydroxide (OLDH) | 10 | 49 | 391 | 106 | 3.08 | 22.1 | V-0 | [31] |
0 | 71 | 1146 | 56 | — | 21.2 | NR | [170] | |
magnesium aluminium layered double hydroxide (MgAl-LDH) | 2 | 63 | 865 | 49 | 1.34 | 23.8 | NR | [170] |
zeolitic imidazolate framework8 (ZIF8) | 2 | 58 | 886 | 41 | 1.44 | 23.3 | NR | [170] |
zeolitic imidazolate framework8 decorated magnesium aluminium layered double hydroxide (ZIF8@MgAl-LDH) | 2 | 54 | 562 | 39 | 2.22 | 24.7 | V-1 | [170] |
zeolitic imidazolate framework67 (ZIF67) | 2 | 62 | 817 | 42 | 1.63 | 23.6 | NR | [170] |
zeolitic imidazolate framework67 decorated MgAl-layered double hydroxide (ZIF67@MgAl-LDH) | 2 | 56 | 432 | 34 | 3.44 | 25.5 | V-1 | [170] |
0 | 61 | 1208 | 77.3 | — | 22.5 | NR | [52] | |
triazine-based flame retardant (TAT) | 20 | 42 | 1030 | 75.8 | 0.82 | 24.1 | NR | [52] |
35 | 1065 | 80.3 | — | 22.9 | NR | [171] | ||
2,4,6-tris-(4-boronphenoxy)-(1,3,5)-triazine (TNB) | 1 | 23 | 686 | 68.1 | 1.20 | 26.1 | V-1 | [171] |
2,4,6-tris-(4-boronphenoxy)-(1,3,5)-triazine (TNB) | 5 | 22 | 427 | 64.1 | 1.96 | 28.3 | V-1 | [171] |
2,4,6-tris-(4-boronphenoxy)-(1,3,5)-triazine (TNB) | 10 | 20 | 324 | 59.3 | 2.54 | 29.4 | V-1 | [171] |
2,4,6-tris-(4-boronphenoxy)-(1,3,5)-triazine (TNB) | 15 | 22 | 309 | 58.3 | 2.98 | 30.4 | V-0 | [171] |
2,4,6-tris-(4-boronphenoxy)-(1,3,5)-triazine (TNB) | 20 | 22 | 305 | 58 | 3.03 | 31.2 | V-0 | [171] |
53 | 1121 | 102 | — | 20 | NR | [55] | ||
Cuprous oxide (Cu2O) | 21 | 47 | 1007 | 86 | 1.17 | 22 | NR | [55] |
45 | 1091 | 83 | — | 22.8 | NR | [56] | ||
magnesium hydroxide (MH) | 3 | 38 | 751 | 80 | 1.27 | 25.2 | NR | [56] |
60 | 873 | 88.5 | — | 22.5 | NR | [63] | ||
2,4,6-triphenoxy-1,3,5-triazine (TN) | 3.42 | 25 | 943 | 78.4 | 0.43 | 29 | NR | [63] |
58 | 1208 | 80.6 | — | 22.5 | NR | [66] | ||
expandable graphite (EG) | 20 | 49 | 225 | 63.3 | 5.77 | 31 | NR | [66] |
57 | 1557 | 94.5 | — | 24.5 | NR | [67] | ||
nucleophilic substitution reaction between N-(4-hydroxyphenyl) maleimide & cyanuric chloride (TMT) | 8 | 52 | 1395 | 88.4 | 1.08 | 27 | NR | [67] |
61 | 1208 | 80.6 | — | 22.5 | NR | [68] | ||
nucleophilic substitution reaction between N-(4-hydroxyphenyl) maleimide & cyanuric chloride (TMT) | 7 | 61 | 858 | 73.5 | 1.54 | 25.5 | NR | [68] |
56 | 1420 | 140 | — | 26 | NR | [77] | ||
organically modified montmorillonite (OMMT) | 1 | 39 | 1540 | 116 | 0.77 | 29.3 | NR | [77] |
69 | 966 | 93.9 | — | 22.5 | NR | [78] | ||
triallyl isocyanurate (TAIC) | 10 | 61 | 1306 | 123 | 0.50 | 23.6 | NR | [78] |
52 | 995 | 93.3 | — | 22.5 | NR | [81] | ||
Triphenoxy-1,3,5-triazine (TPT) | 14 | 48 | 964 | 88.7 | 1.00 | 24.5 | NR | [81] |
67 | 950 | 98 | — | 24.1 | NR | [172] | ||
Halloysite nanotube (HNT) | 5 | 65 | 1170 | 93 | 0.83 | 26.1 | NR | [172] |
Halloysite nanotube (HNT) | 10 | 65 | 1002 | 95 | 0.94 | 25.4 | NR | [172] |
biomimetic polydopamine nanocoating functionalized Halloysite nanotube (HNT@PDA) | 5 | 65 | 1088 | 104 | 0.79 | 25.6 | NR | [172] |
biomimetic polydopamine nanocoating functionalized Halloysite nanotube (HNT@PDA) | 10 | 67 | 881 | 91 | 1.16 | 25.6 | NR | [172] |
biomimetic polydopamine nanocoating functionalized Halloysite nanotube and ultrafine Fe(OH)3 nanoparticles (HNT@PDA@Fe(OH)3) | 5 | 61 | 695 | 90 | 1.35 | 33.9 | V-1 | [172] |
biomimetic polydopamine nanocoating functionalized Halloysite nanotube and ultrafine Fe(OH)3 nanoparticles (HNT@PDA@Fe(OH)3) | 10 | 58 | 698 | 88 | 1.31 | 33.8 | NR | [172] |
50 | 860 | 133 | — | 23 | NR | [94] | ||
Montmorillonite (MMT) | 6 | 49 | 792 | 100 | 1.41 | 26 | NR | [94] |
45 | 855 | 112 | — | 25 | NR | [102] | ||
octaphenyl polyhedral oligomeric silsesquioxane (OPS) | 5 | 60 | 712 | 103 | 1.74 | 31.1 | NR | [102] |
45 | 855 | 112 | — | 25 | NR | [103] | ||
Octaphenyl silsesquioxane (OPS) | 4.1 | 55 | 626 | 112 | 1.66 | 27.2 | NR | [103] |
Polyphenyl silsesquioxane (PPSQ) | 4.1 | 50 | 925 | 116 | 0.99 | 27.1 | NR | [103] |
45 | 855 | 112 | — | 25 | NR | [104] | ||
Octaphenyl silsesquioxane (OPS) | 4.1 | 55 | 626 | 112 | 1.66 | 27.2 | NR | [104] |
Octaaminophenylsilsesquioxane (OAPS) | 4.6 | 57 | 635 | 110 | 1.73 | 27 | NR | [104] |
50 | 860 | 112 | — | 23 | NR | [106] | ||
Octaphenyl polyhedral oligomeric silsesquioxane (OPS) | 4.1 | 55 | 626 | 112 | 1.51 | 25 | NR | [106] |
57 | 459 | 55.2 | — | 19.5 | NR | [173] | ||
aluminum trihydroxide (ATH) | 40 | 68 | 231 | 41.2 | 3.17 | 23.6 | NR | [173] |
Colemanite (C) | 40 | 58 | 158 | 34.3 | 4.75 | 23.6 | NR | [173] |
Ulexite (U) | 40 | 62 | 171 | 38.2 | 4.21 | 22.6 | NR | [173] |
boric acid (BA) | 40 | 76 | 132 | 32.1 | 7.97 | 28.5 | V-0 | [173] |
boric oxide (BO) | 40 | 68 | 82 | 20.6 | 17.89 | 24.2 | NR | [173] |
melamine borate (MB) | 30 | 78 | 107 | 26.9 | 12.05 | 24.5 | V-0 | [173] |
guanidinium nonaborate (GB) | 30 | 65 | 105 | 26.8 | 10.27 | 23.6 | NR | [173] |
64 | 821 | 94 | — | 23.2 | NR | [115] | ||
polyhedral oligomeric octadiphenylsulfonylsilsesquioxane (ODPSS) | 5 | 59 | 417 | 74 | 2.30 | 24.3 | NR | [115] |
60 | 920 | 90.5 | — | 22.7 | NR | [116] | ||
Magnesium-Aluminum layered double hydroxide (Mg-Al LDH) | 4 | 53 | 835 | 89.6 | 0.98 | 24.3 | NR | [116] |
108 | 1634 | 78 | — | 19.8 | NR | [174] | ||
Trisilanolisobutyl Polyhedral oligomeric silsesquioxane (T8POSS) | 10 | 99 | 774 | 56 | 2.69 | 20.7 | NR | [174] |
triglycidyl isocyanurate (TGIC) | 10 | 86 | 1190 | 67 | 1.27 | 19.9 | NR | [174] |
0 | 51 | 1914 | 81.9 | — | 22 | NR | [121] | |
reduced graphene oxide (RGO) | 1 | 47 | 1356 | 67.6 | 1.57 | 23.5 | NR | [121] |
21 | 1910 | 84.4 | — | 22.1 | NR | [120] | ||
halloysite nano-tube (HNT) | 2 | 20 | 1591 | 90.7 | 1.06 | 19.5 | NR | [120] |
layered double hydroxide (LDH) | 2 | 21 | 803 | 87.5 | 2.29 | 21.6 | NR | [120] |
layered double hydroxide (LDH) | 4 | 22 | 861 | 85.4 | 2.29 | 20. 6 | NR | [120] |
layered double hydroxide (LDH) | 6 | 20 | 791 | 82.9 | 2.34 | 19.7 | NR | [120] |
epoxy novolac resin | 0 | 51 | 682 | 110 | — | — | NR | [124] |
Boehmite (AlO(OH)) | 30 | 69 | 535 | 88 | 2.15 | — | V-1 | [124] |
0 | 50 | 992 | 91 | — | — | NR | [125] | |
activated carbon spheres (ACS) | 2 | 56 | 898 | 91 | 1.23 | — | — | [125] |
activated carbon spheres@SnO2 hybrid (ACS@SnO2) | 2 | 50 | 761 | 98 | 1.21 | — | — | [125] |
activated carbon spheres@SnO2@NiO hybrid (ACS@SnO2@NiO) | 2 | 56 | 839 | 92 | 1.31 | — | NR | [125] |
0 | 50 | 986 | 91 | — | — | NR | [125] | |
activated carbon spheres@SnO2@NiO hybrid (ACS@SnO2@NiO) | 5 | 51 | 823 | 88 | 1.26 | — | NR | [125] |
63 | 1321 | 157 | — | — | NR | [129] | ||
octapropylglycidylether polyhedral oligomeric silsesquioxane (OGPOSS) | 15 | 60 | 1026 | 145 | 1.32 | — | NR | [129] |
0 | 19 | 1325 | 95.7 | — | 19.2 | HB | [33] | |
Expandable graphite (EG) | 15 | 34 | 1015 | 85.3 | 2.61 | 25.4 | HB | [33] |
100 | 733 | 141 | — | 21 | HB | [130] | ||
Silicate glass (CP) | 10 | 101 | 315 | 139 | 2.38 | 25 | HB | [130] |
Silicate glass (CP) | 15 | 89 | 268 | 132 | 2.60 | 24 | HB | [130] |
47 | 891 | 151 | — | 21 | HB | [130] | ||
Silicate glass (CP) | 10 | 44 | 408 | 136 | 2.27 | 25 | HB | [130] |
Silicate glass (CP) | 15 | 46 | 346 | 134 | 2.84 | 24 | HB | [130] |
22 | 1196 | 147 | — | 21 | HB | [130] | ||
Silicate glass (CP) | 10 | 20 | 565 | 137 | 2.06 | 25 | HB | [130] |
Silicate glass (CP) | 15 | 19 | 585 | 129 | 2.01 | 24 | HB | [130] |
0 | 58 | 1126 | 100 | — | 26.1 | — | [132] | |
strontium hydroxystannate nanorod (SrSn(OH)6) | 3 | 55 | 889 | 92.6 | 1.30 | 28.4 | — | [132] |
0 | 73 | 1054 | 39.1 | — | 22.4 | — | [175] | |
silica nanoparticles (SiO2) | 2 | 65 | 727 | 34.4 | 1.46 | 26 | — | [175] |
Zeolitic imidazolate framework-8 nanocrystals (ZIF8) | 2 | 60 | 431 | 25.3 | 3.10 | 26.9 | — | [175] |
Zeolitic imidazolate framework-8 coated with SiO2 (ZIF8@SiO2) | 2 | 68 | 254 | 23.9 | 6.32 | 28.1 | — | [175] |
0 | 69 | 1150 | 54.7 | — | 22 | — | [176] | |
molybdenum disulfide (MoS2) | 2 | 65 | 854 | 41.7 | 1.66 | 25.7 | — | [176] |
titanium dioxide nanotube (TNT) | 2 | 58 | 815 | 39.5 | 1.64 | 25.5 | — | [176] |
molybdenum disulfide decorated titanium dioxide nanotube (MoS2-TNT) | 1 | 63 | 859 | 43.7 | 1.53 | 25.1 | — | [176] |
molybdenum disulfide decorated titanium dioxide nanotube (MoS2-TNT) | 2 | 60 | 701 | 37.1 | 2.10 | 26.8 | — | [176] |
molybdenum disulfide decorated titanium dioxide nanotube (MoS2-TNT) | 3 | 61 | 627 | 32.1 | 2.76 | 28.1 | — | [176] |
45 | 1193 | 76 | — | 23.8 | — | [177] | ||
Sepiolite (Sep) | 2 | 49 | 1288 | 78 | 0.98 | 29.8 | — | [177] |
Sepiolite (Sep) | 4 | 61 | 963 | 101 | 1.26 | 30.1 | — | [177] |
Fe3O4-doped sepiolite (Fe3o4–Sep) | 2 | 42 | 1093 | 83 | 0.93 | 33.8 | — | [177] |
Fe3O4-doped sepiolite (Fe3o4–Sep) | 4 | 45 | 883 | 89 | 1.15 | 36.7 | — | [177] |
45 | 1193 | 76 | — | 23.8 | — | [178] | ||
oxidized graphene nanoplatelets (GNO) | 1 | 49 | 1204 | 81 | 1.01 | 25.2 | — | [178] |
oxidized graphene nanoplatelets (GNO) | 3 | 47 | 1244 | 72 | 1.05 | 25.6 | — | [178] |
Cu-doped graphene (GN-Cu) | 1 | 45 | 825 | 66 | 1.66 | 25.8 | — | [178] |
Cu-doped graphene (GN-Cu) | 3 | 47 | 786 | 64 | 1.88 | 26.4 | — | [178] |
0 | 54 | 1068 | 76 | — | 21 | — | [147] | |
Boehmite (AlO(OH)) | 20 | 49 | 870 | 65 | 1.30 | — | — | [147] |
54 | 1068 | 75.8 | — | — | HB | [127] | ||
Boehmite (AlO(OH)) | 20 | 49 | 870 | 65.5 | 1.28 | — | HB | [127] |
amorphous silicon dioxide (SiO2) | 20 | 41 | 907 | 57.6 | 1.17 | — | HB | [127] |
Bisphenol-A | 0 | 22 | 1680 | 79 | — | — | — | [179] |
α-Manganese dioxide nanosheets (α-MnO2) | 0.5 | 25 | 1701 | 77 | 1.15 | — | — | [179] |
α-Manganese dioxide nanosheets (α-MnO2) | 1 | 24 | 1480 | 73 | 1.34 | — | — | [179] |
α-Manganese dioxide nanosheets (α-MnO2) | 2 | 23 | 1400 | 67 | 1.47 | — | — | [179] |
δ-Manganese dioxide nanosheets (δ-MnO2) | 0.5 | 25 | 1617 | 74 | 1.26 | — | — | [179] |
δ-Manganese dioxide nanosheets (δ-MnO2) | 1 | 26 | 1547 | 74 | 1.37 | — | — | [179] |
δ-Manganese dioxide nanosheets (δ-MnO2) | 2 | 27 | 1358 | 64 | 1.87 | — | — | [179] |
0 | 60 | 2187 | 124 | — | — | — | [140] | |
molybdenum disulfide nanoflower (MoS2) | 2 | 49 | 1457 | 98 | 1.55 | — | — | [140] |
0 | 47.7 | 1308 | 86.8 | — | — | — | [180] | |
Aminopropylisobutyl polyhedral oligomeric silsesquioxane (AI-POSS) | 7.2 | 44.3 | 880 | 83.6 | 1.43 | — | — | [180] |
Aminopropylisobutyl polyhedral oligomeric silsesquioxane (AI-POSS) | 21.8 | 36.3 | 585 | 97.7 | 1.51 | — | — | [180] |
Aminopropylisobutyl polyhedral oligomeric silsesquioxane (AI-POSS) | 54 | 32.2 | 616 | 65.3 | 1.90 | — | — | [180] |
0 | 5 | 986 | 113 | — | — | — | [181] | |
Expandable graphite (EG) | 9 | 10 | 152 | 110 | 13.33 | — | — | [181] |
halloysite nanotube (HNT) | 9 | 5 | 969 | 110 | 1.04 | — | — | [181] |
0 | 117 | 1184 | 95.3 | — | — | — | [182] | |
Boron Nitride with D50 = 2 μm (BN 2 μm) | 45 | 175 | 767 | 71.5 | 3.07 | — | — | [182] |
Boehmite with D50 = 2 μm (BT 2 μm) | 45 | 140 | 674 | 72.2 | 2.77 | — | — | [182] |
0 | 22 | 1650 | 80 | — | — | — | [183] | |
Manganese dioxide (MnO2) | 2 | 27 | 1443 | 71 | 1.58 | — | — | [183] |
Manganese dioxide@zinc hydroxystannate binary hybrid (MnO2@ZHS) | 0.5 | 24 | 1487 | 56 | 1.72 | — | — | [183] |
Manganese dioxide@zinc hydroxystannate binary hybrid (MnO2@ZHS) | 1 | 25 | 1275 | 49 | 2.40 | — | — | [183] |
Manganese dioxide@zinc hydroxystannate binary hybrid (MnO2@ZHS) | 2 | 23 | 989 | 61 | 2.28 | — | — | [183] |
Diglycidyl ether of bisphenol-F epoxy | 0 | 66 | 1197 | 82.7 | — | — | — | [184] |
ionic liquid flame retardant (ILFR) | 5 | 55 | 753 | 62.5 | 1.75 | — | — | [184] |
boron nitride nanosheets (BN) | 5 | 70 | 813 | 68.2 | 1.89 | — | — | [184] |
ionic liquid flame retardant functionalized boron nitride nanosheets (ILFR-fBN) | 5 | 104 | 689 | 51.5 | 4.39 | — | — | [184] |
63 | 1397 | 81.3 | — | — | — | [143] | ||
thiol-functionalized mesoporous silica (SH-mSiO2) | 2 | 65 | 1117 | 77.8 | 1.34 | — | — | [143] |
52 | 972 | 99 | — | — | — | [185] | ||
short carbon fiber (SCF) | 0.5 | 69 | 793 | 92 | 1.75 | — | — | [185] |
short carbon fiber (SCF) | 0.7 | 80 | 723 | 88 | 2.32 | — | — | [185] |
short carbon fiber (SCF) | 1 | 62 | 840 | 89 | 1.53 | — | — | [185] |
short carbon fiber (SCF) | 1.5 | 98 | 793 | 101 | 2.26 | — | — | [185] |
24 | 1002 | 104 | — | — | — | [146] | ||
halloysite nanotube (HNT) | 20 | 43 | 790 | 75.2 | 3.14 | — | — | [146] |
38 | 1542 | 76.2 | — | — | — | [186] | ||
nanomer I.28E organoclay (m-Clay) | 2.5 | 58 | 1298 | 56.6 | 2.44 | — | — | [186] |
Deoxyribonucleic Acid modified clay (d-Clay) | 2.5 | 55 | 1220 | 52.4 | 2.66 | — | — | [186] |
22 | 1032 | 49.2 | — | — | — | [187] | ||
Layered double hydroxide (LDH) | 3 | 27 | 968 | 49.6 | 1.29 | — | — | [187] |
β-Iron oxyhydroxide (β-FeOOH) | 3 | 25 | 857 | 48 | 1.40 | — | — | [187] |
Layered double hydroxide nanosheet-wrapped β-Iron oxyhydroxide rod hybrid (LDH-β-FeOOH) | 3 | 20 | 736 | 44.8 | 1.40 | — | — | [187] |
47 | 1083 | 45.7 | — | — | — | [188] | ||
amorphous hydrous TiO2 solid spheres (AHTSS) | 0.5 | 52 | 1125 | 46 | 1.05 | — | — | [188] |
amorphous hydrous TiO2 solid spheres (AHTSS) | 2 | 53 | 951 | 43.6 | 1.34 | — | — | [188] |
urchin-like mesoporous TiO2 hollow spheres (UMTHS) | 0.5 | 52 | 827 | 43.3 | 1.52 | — | — | [188] |
urchin-like mesoporous TiO2 hollow spheres (UMTHS-2) | 2 | 52 | 706 | 38.5 | 2.01 | — | — | [188] |
65 | 1592 | 39.7 | — | — | — | [189] | ||
chitosan-modified molybdenum disulfide nanosheets (CS-MoS2) | 0.5 | 71 | 1243 | 35.9 | 1.54 | — | — | [189] |
chitosan-modified molybdenum disulfide nanosheets (CS-MoS2) | 1 | 74 | 1107 | 28.6 | 2.27 | — | — | [189] |
chitosan-modified molybdenum disulfide nanosheets (CS-MoS2) | 2 | 75 | 902 | 33.9 | 2.38 | — | — | [189] |
molybdenum disulfide nanosheets (MoS2) | 2 | 72 | 1178 | 40.1 | 1.48 | — | — | [189] |
74 | 1915 | 108 | — | — | — | [148] | ||
silica nanospheres (SiO2) | 1 | 74 | 1777 | 95.6 | 1.21 | — | — | [148] |
38 | 943 | 60.3 | — | — | — | [150] | ||
carbon nanotube (CNT) | 1 | 26 | 673 | 53.8 | 1.07 | — | — | [150] |
chemical treatment carbon nanotube (CCNT) | 1 | 32 | 837 | 57.4 | 0.99 | — | — | [150] |
thermal treatment carbon nanotube (TCNT) | 1 | 25 | 585 | 56.6 | 1.13 | — | — | [150] |
layered double hydroxide (LDH) | 5 | 35 | 578 | 58.4 | 1.55 | — | — | [150] |
Hydrogenated fatty acid modified layered double hydroxide (OLDH) | 5 | 38 | 453 | 66.5 | 1.88 | — | — | [150] |
Montmorillonite (MMT) | 5 | 38 | 717 | 58.6 | 1.35 | — | — | [150] |
Quaternary ammonium salt modified montmorillonite (OMMT) | 5 | 33 | 823 | 61.7 | 0.97 | — | — | [150] |
aluminium trihydroxide (ATH) | 5 | 35 | 617 | 59.2 | 1.43 | — | — | [150] |
65 | 993 | 141 | — | — | — | [190] | ||
Expanded graphite (EG) | 5 | 68 | 1188 | 125 | 0.98 | — | — | [190] |
Expanded graphite (EG) | 10 | 80 | 1487 | 113 | 1.02 | — | — | [190] |
Expanded graphite (EG) | 15 | 102 | 1911 | 124 | 0.92 | — | — | [190] |
Expanded graphite (EG) | 23 | 116 | 1992 | 102 | 1.23 | — | — | [190] |
Expanded graphite (EG) | 50 | 132 | 1800 | 81 | 1.95 | — | — | [190] |
141 | 932 | 74.3 | — | — | — | [191,192] | ||
Bentonite (BT) | 3 | 150 | 1094 | 74 | 0.91 | — | — | [191,192] |
Bentonite (BT) | 5 | 158 | 1192 | 88.1 | 0.73 | — | — | [191,192] |
6-(4-butylphenyl)21,3,5-triazine-2,4-diamine modified bentonite (BFTDA-BT) | 3 | 140 | 966 | 74.1 | 0.96 | — | — | [191,192] |
6-(4-butylphenyl)21,3,5-triazine-2,4-diamine modified bentonite (BFTDA-BT) | 5 | 145 | 998 | 82.2 | 0.86 | — | — | [191,192] |
11-amino-N-(pyridine-2yl)undecanamide modified bentonite (APUA-BT) | 3 | 138 | 772 | 74.7 | 1.17 | — | — | [191,192] |
11-amino-N-(pyridine-2yl)undecanamide modified bentonite (APUA-BT) | 5 | 139 | 814 | 74.2 | 1.13 | — | — | [191,192] |
68 | 1730 | 113 | — | — | — | [193] | ||
graphene nanosheets (GN) | 2 | 86 | 980 | 65.1 | 3.87 | — | — | [193] |
Ni–Fe layered double hydroxide (Ni–Fe LDH) | 2 | 80 | 1070 | 58.9 | 3.65 | — | — | [193] |
49 | 1261 | 114 | — | — | — | [194] | ||
octaammonium polyhedral oligomeric silsesquioxane-modified montmorillonite (OAPOSS-MMT) | 2 | 42 | 1207 | 103 | 0.99 | — | — | [194] |
octaammonium polyhedral oligomeric silsesquioxane-modified montmorillonite (OAPOSS-MMT) | 4 | 48 | 1095 | 94 | 1.36 | — | — | [194] |
octaammonium polyhedral oligomeric silsesquioxane-modified montmorillonite (OAPOSS-MMT) | 6 | 50 | 982 | 88 | 1.69 | — | — | [194] |
31 | 1933 | 146 | — | — | — | [195] | ||
Sodium magadiite (Na-magadiite) | 3 | 39 | 1283 | 116 | 2.38 | — | — | [195] |
Sodium magadiite reaction with silane coupling agent (S-Na-magadiite) | 3 | 38 | 1641 | 120 | 1.75 | — | — | [195] |
protonated magadiite reaction with silane coupling agent (S-H-magadiite) | 3 | 38 | 1416 | 114 | 2.14 | — | — | [195] |
organo-modified magadiite (OM-magadiite) | 3 | 29 | 1332 | 105 | 1.88 | — | — | [195] |
silane grafting organo modified magadiite (S-OM-magadiite) | 3 | 34 | 1273 | 103 | 2.36 | — | — | [195] |
— | 32 | 2572 | 184 | — | — | — | [154] | |
tetrabromobisphenol-A (TBBA) | 17 | 17 | 1390 | 92 | 1.96 | — | — | [154] |
90 | 1653 | 130 | — | — | — | [196] | ||
graphene sheet (GN) | 2 | 84 | 1156 | 108 | 1.60 | — | — | [196] |
Ce-doped MnO2 (Ce–MnO2) | 2 | 79 | 920 | 96.7 | 2.11 | — | — | [196] |
Ce-doped MnO2 decorated graphene sheets (Ce–MnO2–GN) | 2 | 100 | 765 | 83.8 | 3.72 | — | — | [196] |
89 | 1473 | 87.8 | — | — | — | [197] | ||
mesoporous silica (m-SiO2) | 2 | 107 | 1191 | 96.5 | 1.35 | — | — | [197] |
Co−Al layered double hydroxide (Co−Al LDH) | 2 | 103 | 1188 | 84.3 | 1.49 | — | — | [197] |
mesoporous silica@Co−Al layered double hydroxide (m-SiO2@Co−Al LDH) | 2 | 110 | 894 | 56 | 3.19 | — | — | [197] |
65 | 1653 | 130 | — | — | — | [198] | ||
Zinc sulfide (ZnS) | 2 | 88 | 1213 | 119 | 2.00 | — | — | [198] |
graphene sheet (GN) | 2 | 70 | 1141 | 108 | 1.88 | — | — | [198] |
Zinc sulfide decorated Graphene sheets (ZnS-GN) | 2 | 87 | 879 | 94.2 | 3.47 | — | — | [198] |
55 | 1298 | 97.6 | — | — | — | [199] | ||
hydrated pre-treated sepiolite (sep idra) | 2 | 55 | 1370 | 101 | 0.91 | — | — | [199] |
hydrated pre-treated sepiolite (sep idra) | 5 | 65 | 1157 | 99.5 | 1.30 | — | — | [199] |
hydrated pre-treated sepiolite (sep idra) | 10 | 65 | 1072 | 95.7 | 1.45 | — | — | [199] |
dehydrated pre-treated sepiolite (sep anidra) | 2 | 55 | 1129 | 97 | 1.157 | — | — | [199] |
dehydrated pre-treated sepiolite (sep anidra) | 5 | 65 | 1114 | 107 | 1.26 | — | — | [199] |
dehydrated pre-treated sepiolite (sep anidra) | 10 | 65 | 958 | 108 | 1.45 | — | — | [199] |
94 | 1097 | 119 | — | — | — | [158] | ||
expandable graphite (EG) | 5 | 111 | 463 | 142 | 2.34 | — | — | [158] |
54 | 1327 | 99.1 | — | — | — | [159] | ||
chitosan modified montmorillonite intercalation iron compounds (CTS-Fe-OMMT) | 3 | 55 | 1168 | 91.4 | 1.25 | — | — | [159] |
cetyltrimethylammoniumbromide modified montmorillonite intercalation iron compounds (CTAB-Fe-OMMT) | 3 | 47 | 975 | 89.2 | 1.31 | — | — | [159] |
80.4 | 1111 | 140 | — | — | — | [200] | ||
aminated multiwalled carbon nanotubes supplied by the Polish company (A-MWCNT(Polish)) | 0.05 | 72.8 | 1161 | 93.6 | 1.29 | — | — | [200] |
aminated multiwalled carbon nanotubes supplied by the Polish company (A-MWCNT(Polish)) | 0.1 | 68.8 | 992 | 93.6 | 1.43 | — | — | [200] |
aminated multiwalled carbon nanotubes supplied by the Polish company (A-MWCNT(Polish)) | 0.5 | 74 | 926 | 96.9 | 1.59 | — | — | [200] |
aminated multiwalled carbon nanotubes supplied by the Polish company (A-MWCNT(Polish)) | 1 | 71.9 | 875 | 92.6 | 1.72 | — | — | [200] |
aminated multiwalled carbon nanotubes supplied by the Polish company (A-MWCNT(Polish)) | 5 | 78.3 | 1141 | 98.9 | 1.34 | — | — | [200] |
carboxylated multiwalled carbon nanotubes supplied by the Polish company (C-MWCNT(Polish)) | 0.05 | 78.7 | 1080 | 101 | 1.40 | — | — | [200] |
carboxylated multiwalled carbon nanotubes supplied by the Polish company (C-MWCNT(Polish)) | 0.1 | 72.6 | 1250 | 100 | 1.12 | — | — | [200] |
carboxylated multiwalled carbon nanotubes supplied by the Polish company (C-MWCNT(Polish)) | 0.5 | 80.2 | 1163 | 98.8 | 1.35 | — | — | [200] |
carboxylated multiwalled carbon nanotubes supplied by the Polish company (C-MWCNT(Polish)) | 1 | 81.2 | 945 | 102 | 1.63 | — | — | [200] |
carboxylated multiwalled carbon nanotubes supplied by the Belgian company (C-MWCNT(Belgian)) | 0.05 | 76.2 | 919 | 96.3 | 1.66 | — | — | [200] |
carboxylated multiwalled carbon nanotubes supplied by the Belgian company (C-MWCNT(Belgian)) | 0.5 | 67.4 | 1110 | 99 | 1.19 | — | — | [200] |
carboxyammonium multiwalled carbon nanotubes supplied by the Polish company (CA-MWCNT(Polish)) | 0.05 | 83.9 | 1240 | 104 | 1.26 | — | — | [200] |
carboxyammonium multiwalled carbon nanotubes supplied by the Polish company (CA-MWCNT(Polish)) | 0.1 | 73.8 | 1162 | 99 | 1.24 | — | — | [200] |
carboxyammonium multiwalled carbon nanotubes supplied by the Polish company (CA-MWCNT(Polish)) | 0.5 | 76 | 1095 | 99.5 | 1.35 | — | — | [200] |
carboxyammonium multiwalled carbon nanotubes supplied by the Polish company (CA-MWCNT(Polish)) | 1 | 67.3 | 1192 | 97.8 | 1.12 | — | — | [200] |
carboxyammonium multiwalled carbon nanotubes supplied by the Polish company (CA-MWCNT(Polish)) | 5 | 69.7 | 1198 | 100 | 1.12 | — | — | [200] |
aminated multiwalled carbon nanotubes supplied by the Belgian company (A-MWCNT(Belgian)) | 0.05 | 77.4 | 1314 | 98.3 | 1.16 | — | — | [200] |
aminated multiwalled carbon nanotubes supplied by the Belgian company (A-MWCNT(Belgian)) | 0.1 | 80.2 | 1225 | 98.6 | 1.28 | — | — | [200] |
aminated multiwalled carbon nanotubes supplied by the Belgian company (A-MWCNT(Belgian)) | 0.5 | 56.6 | 1005 | 62.4 | 1.75 | — | — | [200] |
66 | 934 | 95 | — | — | — | [201] | ||
graphene oxide (GNO) | 1 | 76 | 811 | 133 | 0.94 | — | — | [201] |
41 | 1222 | 159 | — | — | — | [160] | ||
onium ion modified nanoclay (I.30E) | 3 | 32 | 1274 | 154 | 0.77 | — | — | [160] |
0 | 101 | 1348 | 87.1 | — | — | — | [202] | |
molybdenum disulfide (MoS2) | 2 | 96 | 1076 | 75.7 | 1.37 | — | — | [202] |
graphene (GN) | 2 | 92 | 965 | 70.1 | 1.58 | — | — | [202] |
molybdenum disulfide modified graphene (MoS2-GN) | 2 | 90 | 730 | 65.1 | 2.20 | — | — | [202] |
0 | 47 | 1630 | 82.3 | — | — | — | [161] | |
graphene oxide(GNO) | 1 | 41 | 1426 | 76.8 | 1.06 | — | — | [161] |
epoxy resin modified with (3-isocyanatopropyl)-triethoxysilane | 0 | 93 | 1331 | 63.8 | — | — | — | [203] |
hydroxylated hexagonal boron nitride (BNO) | 1 | 113 | 860 | 56.3 | 2.13 | — | — | [203] |
hydroxylated hexagonal boron nitride (BNO) | 3 | 117 | 765 | 55.5 | 2.51 | — | — | [203] |
— | 42 | 385 | 21.8 | — | 27.5 | — | [163,164] | |
cellulosic fibre containing polysilicic acid (Vis) a | 4.7 | 41 | 329 | 19.4 | 1.28 | 28.1 | — | [163,164] |
phenol–formaldehyde fibers (Ky) a | 4.7 | 51 | 367 | 28.8 | 0.96 | 27.7 | — | [163,164] |
44 | 818 | 28.8 | — | — | — | [204] | ||
Nanoclay (clay) b | 1 | 32 | 558 | 26.4 | 1.16 | — | — | [204] |
Nanoclay (clay) b | 3 | 32 | 570 | 25.5 | 1.18 | — | — | [204] |
Nanoclay (clay) b | 5 | 32 | 533 | 24.8 | 1.29 | — | — | [204] |
28 | 349 | 20.4 | — | — | — | [150] | ||
layered double hydroxide (LDH) c | 5 | 22 | 343 | 21.9 | 0.74 | — | — | [150] |
Hydrogenated fatty acid modified layered double hydroxide (OLDH) c | 5 | 21 | 310 | 23 | 0.74 | — | — | [150] |
carbon nanotube (CNT) c | 1 | 27 | 396 | 22.7 | 0.76 | — | — | [150] |
chemical treatment carbon nanotube (CCNT) c | 1 | 26 | 411 | 21.7 | 0.74 | — | — | [150] |
thermal treatment carbon nanotube (TCNT) c | 1 | 27 | 471 | 22.2 | 0.65 | — | — | [150] |
aluminium trihydroxide (ATH) c | 5 | 22 | 417 | 22.6 | 0.59 | — | — | [150] |
0 | 33 | 520 | 29.4 | — | — | — | [205] | |
magnesium hydroxide (Mg(OH)2) d | 1 | 28 | 518 | 37.4 | 0.67 | — | — | [205] |
magnesium hydroxide (Mg(OH)2) d | 7.5 | 30 | 550 | 28.4 | 0.89 | — | — | [205] |
magnesium hydroxide (Mg(OH)2) d | 15 | 30 | 392 | 31.2 | 1.13 | — | — | [205] |
magnesium hydroxide (Mg(OH)2) d | 25 | 35 | 476 | 41.7 | 0.81 | — | — | [205] |
aluminum hydroxide (Al(OH)3) d | 1 | 28 | 456 | 37.3 | 0.76 | — | — | [205] |
aluminum hydroxide (Al(OH)3) d | 7.5 | 28 | 585 | 35.3 | 0.62 | — | — | [205] |
aluminum hydroxide (Al(OH)3) d | 15 | 26 | 451 | 32.8 | 0.81 | — | — | [205] |
aluminum hydroxide (Al(OH)3) d | 25 | 32 | 396 | 31.6 | 1.18 | — | — | [205] |
Zinc borate (ZB) d | 1 | 26 | 572 | 35.9 | 0.58 | — | — | [205] |
Zinc borate (ZB) d | 7.5 | 32 | 427 | 42.7 | 0.81 | — | — | [205] |
Zinc borate (ZB) d | 15 | 27 | 458 | 36.3 | 0.75 | — | — | [205] |
Zinc borate (ZB) d | 25 | 37 | 352 | 30.6 | 1.59 | — | — | [205] |
46 | 568 | 23.2 | — | — | — | [206] | ||
Single-walled carbon nanotube Buckypaper (SWCNT-BP) e | 1.06 | 50 | 526 | 24.5 | 1.11 | — | — | [206] |
multiwalled carbon nanotube Buckypaper (MWCNT-BP) e | 1.34 | 64 | 258 | 13.2 | 5.38 | — | — | [206] |
carbon nanofiber (CNF) e | 1.57 | 59 | 508 | 24.8 | 1.34 | — | — | [206] |
0 | 39 | 456 | 38 | — | — | — | [167] | |
cellulosic fibre containing polysilicic acid (Vis) f | 5 | 46 | 451 | 37.2 | 1.21 | — | — | [167] |
cellulosic fibre containing polysilicic acid (Vis) f | 10 | 58 | 434 | 36.3 | 1.63 | — | — | [167] |
cellulosic fibre containing polysilicic acid (Vis) f | 15 | 55 | 321 | 31.1 | 2.44 | — | — | [167] |
46 | 568 | 23.2 | — | — | — | [207] | ||
Single-walled carbon nanotube Buckypaper (SWCNT-BP) g | 1.06 | 50 | 526 | 24.5 | 1.11 | — | — | [207] |
multiwalled carbon nanotube Buckypaper (MWCNT-BP) g | 1.34 | 64 | 258 | 13.2 | 5.38 | — | — | [207] |
125 | 857 | 50 | — | — | — | [174] | ||
Trisilanolisobutyl Polyhedral oligomeric silsesquioxane (T8POSS) h | 5 | 121 | 420 | 32 | 3.08 | — | — | [174] |
triglycidyl isocyanurate (TGIC) h | 5 | 108 | 620 | 47 | 1.27 | — | — | [174] |
a Matrix: eight layers of woven E-glass reinforced film of multifunctional epoxy resin; b Matrix: six layers of biaxial E-glass fabric reinforced epoxy; c Matrix: carbon fiber reinforced epoxy resin; d Matrix: eight plies of carbon fiber reinforced system HexFlow RTM6 (matrix) and HexForce G0939 (fabric); e Matrix: six layers of IM-7 carbon fiber fabrics reinforced epoxy; f Matrix: eight layers of woven E-glass reinforced epoxy; g Matrix: six layers of IM-7 carbon fiber fabrics reinforced epoxy; h Matrix: eight layers of woven glass Fiber Reinforced epoxy.