Table II:
temp (°C) | τ1 (ns) | α1 | τ2 (ns) | α2 | τ3 (ns) | α3 | χR2 |
---|---|---|---|---|---|---|---|
10 | 5.34 | 1.0 | 82.8 | ||||
6.11 | 0.792 | 1.38 | 0.208 | 2.2 | |||
6.61 | 0.597 | 3.80 | 0.261 | 0.85 | 0.143 | 1.6 | |
20 | 4.92 | 1.0 | 89.4 | ||||
5.69 | 0.777 | 1.31 | 0.223 | 2.1 | |||
6.27 | 0.520 | 3.79 | 0.313 | 0.84 | 0.157 | 1.5 | |
25 | 4.54 | 1.0 | 142.7 | ||||
5.35 | 0.749 | 1.00 | 0.251 | 2.1 | |||
6.06 | 0.461 | 3.77 | 0.334 | 0.73 | 0.205 | 1.5 | |
30 | 3.89 | 1.0 | 311.1 | ||||
4.82 | 0.669 | 1.75 | 0.331 | 2.6 | |||
5.31 | 0.482 | 2.92 | 0.233 | 0.55 | 0.285 | 1.3 | |
35 | 2.67 | 1.0 | 599.2 | ||||
3.71 | 0.550 | 0.53 | 0.450 | 2.2 | |||
4.35 | 0.284 | 2.76 | 0.294 | 0.46 | 0.422 | 1.1 | |
40 | 1.84 | 1.0 | 583.1 | ||||
2.74 | 0.485 | 0.44 | 0.515 | 3.3 | |||
3.59 | 0.162 | 2.07 | 0.362 | 0.34 | 0.476 | 1.4 | |
45 | 1.45 | 1.0 | 558.0 | ||||
2.12 | 0.475 | 0.31 | 0.525 | 5.1 | |||
3.27 | 0.090 | 1.69 | 0.417 | 0.24 | 0.493 | 1.1 |
Global Analysis | ||||||
---|---|---|---|---|---|---|
Ea,1 (kcal/mol) | A1 (ns−1) | Ea,2 (kcal/mol) | A2 (ns−1) | Ea,3 (kcal/mol) | A3 (ns−1) | χR2 |
〈1.0〉 | 0.977 | 1.88 | 9.66 | 〈4.0〉 | 1901 | 4.2 |
All χR2 are calculated with δϕ = 2.0° and δm = 0.004. For the global analysis, Ea,1 and Ea,3 were fixed. The α1 and α3 for the global analysis are given in Figure 10 as the open symbols.