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. 2019 Dec 24;10(1):48. doi: 10.3390/nano10010048

A Novel Au@Cu2O-Ag Ternary Nanocomposite with Highly Efficient Catalytic Performance: Towards Rapid Reduction of Methyl Orange Under Dark Condition

Tong Wu 1,2, Yichuan Kou 1,2, Hui Zheng 1,2, Jianing Lu 1,2, Naveen Reedy Kadasala 3, Shuo Yang 4, Chenzi Guo 4, Yang Liu 1,2,*, Ming Gao 1,2,*
PMCID: PMC7023264  PMID: 31878173

Abstract

Au@Cu2O core-shell nanocomposites (NCs) were synthesized by reducing copper nitrate on Au colloids with hydrazine. The thickness of the Cu2O shells could be varied by adjusting the molar ratios of Au: Cu. The results showed that the thickness of Cu2O shells played a crucial role in the catalytic activity of Au@Cu2O NCs under dark condition. The Au@Cu2O-Ag ternary NCs were further prepared by a simple galvanic replacement reaction method. Moreover, the surface features were revealed by TEM, XRD, XPS, and UV–Vis techniques. Compared with Au@Cu2O NCs, the ternary Au@Cu2O-Ag NCs had an excellent catalytic performance. The degradation of methyl orange (MO) catalyzed by Au@Cu2O-Ag NCs was achieved within 4 min. The mechanism study proved that the synergistic effects of Au@Cu2O-Ag NCs and sodium borohydride facilitated the degradation of MO. Hence, the designed Au@Cu2O-Ag NCs with high catalytic efficiency and good stability are expected to be the ideal environmental nanocatalysts for the degradation of dye pollutants in wastewater.

Keywords: Au@Cu2O nanocomposites, Au@Cu2O-Ag nanocomposites, catalytic reduction, methyl orange

1. Introduction

Synthetic organic dyes and natural pigments with considerable coloring capacity are widely applied in paper, plastics, paints, cosmetics, food, textile, mining, and printing industries [1,2,3]. Azo dyes account for 60–70% of all dyes [4]. However, the direct discharge of wastewater containing azo dyes not only destroys the ecological environment but also poses a serious threat to human life and health, as reported in previous literature [4]. For example, when individuals are exposed to methyl orange (MO), a typical representative of azo dyes, it has been shown to cause physical discomfort such as increased heart rate, vomiting, and shock [5,6]. Thus, removal and degradation of azo dyes are critically important to prevent environmental pollution and protect human health [7,8].

Nowadays, a series of post/pre-treatment methods have been proposed to remove the azo dyes from the wastewater [1,9,10,11]. Porous/activated carbons have been applied as commercial adsorbents for the wastewater treatment thanks to their high capacity for adsorbing pollutants. For instance, Chen et al. prepared layered double hydroxides decorated biomass-derived porous carbons to reduce MO from aqueous solution [12]. Pargoletti et al. synthesized activated carbon-based MnO2 nanoparticles by hydrothermal method and realized the adsorption and degradation of MO [13]. Unfortunately, regeneration difficulties, high cost, high carbon emission, and large losses of carbon source restrict their practical application [9]. Alternatively, ZnO and TiO2 semiconductor photocatalysts have been extensively employed to catalyze and reduce azo dyes based on their superiority, such as nontoxicity, low cost, and availability [14]. Feng et al. synthesized Fe3O4/ZnO-graphene oxide composites by a mild hydrothermal process and achieved the photocatalytic degradation of MO [15]. Szeto et al. used TiO2 as photocatalysts to study the effects of different lighting and atmosphere conditions on MO destruction [16]. However, the disadvantage of semiconductor photocatalysts is that their catalytic efficiency is low [17]. Therefore, it is urgent to design a kind of efficient, environmentally friendly, and economical multifunctional nanocomposites (NCs) for removing MO from wastewater.

Recently, Au, Ag, Pt, and other noble metal nanocatalysts are recognized as promising catalysts for the removal of azo dyes by the virtue of high efficiency [18,19,20]. Among these noble metal nanomaterials, Au nanocrystals have been proven to be the optimal catalysts due to the excellent chemical and physical stability, tunable optical properties, high catalytic performances, and the surface plasmon resonance (SPR) properties [21,22,23,24]. However, to decrease surface energy, unmodified Au nanocrystals are prone to agglomerate, which impedes the catalytic active sites and leads to reduction of catalytic capacity [25]. In order to address this problem, it has been proposed to embed Au nanocrystals into specific shell matrices to form core-shell nanostructures. This not only avoids the chemical corrosion of Au nanocrystals to some extent, but also ensures that most of Au nanocrystals can take part in catalytic reaction as much as possible [26]. Noble metal-semiconductor core-shell structured NCs keep respective properties of individual components, while presenting novel properties owing to the synergistic interfacial interaction between noble metal and semiconductor [27,28,29,30]. It is unfortunate that ZnO and TiO2 semiconductors can only absorb and transport photons in the UV region of the solar spectrum [31]. In contrast, p-type Cu2O has an excellent visible light response [32,33]. A great deal of research so far has been done to improve the photocatalytic efficiencies of Au@Cu2O in the last few years [34]. Most studies were confined to the discussion of photocatalytic mechanism under the condition of visible light excitation. It is generally accepted that Au nanocrystals greatly promote the photocatalytic activity of Cu2O because Au nanocrystals can act as a charge separation booster to decrease the recombination of carriers and enhance the effective utilization of carriers under visible light irradiation [35]. Unfortunately, it is worth noting that little research work has been studied on the catalytic action of Au@Cu2O in complete darkness. In fact, the presence of Cu2O shells may also modify the catalytic features of Au cores by regulating the charge separation and transfer in the absence of light. From this point of view, the thickness of Cu2O shells surrounding Au cores is responsible for the catalytic abilities of Au@Cu2O. Apart from noble metal-semiconductor core-shell structured NCs, noble metal decorated semiconductor NCs, such as Cu2O-Ag, Cu2O@Au core/shell, Cu2O@Au yolk/shell, have been proposed and synthesized by the researchers to achieve the purpose of increasing the catalytic efficiency [36,37]. The generation of Schottky barrier at semiconductor and noble metal interface leads to the formation of the enriched electron regions, which improves the efficiency of electron transfer and realizes rapid degradation of the dyes [38]. More importantly, the inner semiconductor can adjust localized SPR of noble metal on the surface of semiconductor by plasmon-exciton coupling interaction, which may provide a quick route for carrier transfer and cause more active sites [39]. Hence, there is an opportunity to study the synthesis of Au@Cu2O-Ag NCs and their catalytic degradation of azo dyes in the absence of light.

In this paper, Au nanocrystals were prepared and then were coated with a Cu2O shell. The thickness of the Cu2O shells could be varied by changing the Au:Cu molar ratios. The influence of the thickness of Cu2O shells on catalytic activities and stabilities to MO with the assistance of NaBH4 under dark condition was investigated. Silver ions were further reduced on the Au@Cu2O surfaces by a galvanic replacement method and Ag nanocrystals were attached to the surfaces of Au@Cu2O to achieve Au@Cu2O-Ag NCs. Au@Cu2O-Ag NCs were also applied to the catalytic reduction of MO under dark condition. Furthermore, the corresponding catalytic mechanism was studied. This work introduces a new catalyst for the rapid and efficient wastewater treatment in the absence of light.

2. Materials and Methods

2.1. Materials

Copper nitrate trihydrate (Cu(NO3)2·3H2O), PVP, hydrazine monohydrate (N2H4·H2O), silver nitrate (AgNO3), trisodium citrate dehydrate (C6H5Na3O7·2H2O), methyl orange (MO), sodium borohydride (NaBH4), and chloroauric acid (HAuCl4·4H2O) were acquired from Sinopharm Chemical Reagent Co., Ltd. (Shanghai, China). All the chemicals were used without further purification.

2.2. Synthesis of Au@Cu2O NCs

Step I: Au colloid solution was prepared as described in the literature [40]. 100 mL of 0.01% HAuCl4·4H2O solution and 4 mL of 1% C6H5Na3O7·2H2O solution were heated under reflux for 10 min to achieve the Au colloid solution.

Step II: 0.5 g of PVP was dissolved in 50 mL of 0.005 M Cu(NO3)2 solution under stirring at 450 rpm. Then, a certain amount of (1, 3, 5, 7, 9, and 11 mL) Au colloid solution was added to the mixture. Subsequently, N2H4·H2O (34 μL, 17.5 wt%) was immediately introduced, and the mixture was stirred for 2 min. Then, the product obtained by centrifugation was washed with anhydrous ethanol and deionized water. Finally, Au@Cu2O NCs with different shell thickness were acquired, which were named as AC-1 NCs, AC-3 NCs, AC-5 NCs, AC-7 NCs, AC-9 NCs, and AC-11 NCs, respectively. The same procedure was used to prepare Cu2O nanocrystals but the Au colloid solution was not added.

2.3. Synthesis of Au@Cu2O-Ag NCs

The AC-1 NCs with the thickest Cu2O shell were chosen to deposit Ag nanocrystals on their surfaces. The AC-1 NCs were dispersed in 35 mL of deionized water. 200 μL of 0.004 M AgNO3 solution was then added to the solution with stirring. After stirring for 10 min, the prepared Au@Cu2O-Ag NCs were washed several times with anhydrous ethanol and deionized water. Au@Cu2O-Ag NCs were named as AC-1-Ag NCs.

2.4. Catalytic Activity Measurement

All the catalytic activity measurements were performed in the absence of light. 2.5 mg of catalyst was added to 2.5 mL of deionized water. The catalyst was uniformly dispersed in deionized water by ultrasonication. 100 mL of 10 mg/L MO solution and 9 mL of 3.78 mg/L NaBH4 solution were added to the beaker. The catalyst was added for catalytic reduction and magnetic stirring was maintained during the reaction to ensure uniform dispersion. During the catalytic reduction, 2 mL of solution was sampled from the suspended catalyst nanoparticles for measurement at certain time intervals. The catalytic process was monitored by measuring the change in absorbance of MO at 464 nm by ultraviolet–visible (UV–Vis) absorption spectroscopy. To investigate the repeatability, the samples were separated by centrifugation and then washed several times. Then, the same procedure for catalytic reduction of MO solution was repeated for four cycles. Figure 1 shows the preparation process and catalytic application for degradation of MO of AC-1-Ag NCs with assistance of NaBH4.

Figure 1.

Figure 1

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Scheme of the synthesis protocols of AC-1-Ag nanocomposites (NCs) and the degradation process for methyl orange (MO) by AC-1-Ag NCs with help of sodium borohydride (NaBH4).

2.5. Characterization

Transmission electron microscopy (TEM) images were obtained by using a Hitachi H-800 transmission electron microscope (JEOL Ltd., Tokyo, Japan) operating at an accelerating voltage of 200 kV. UV–Vis absorbance spectra were recorded on a Shimadzu UV 3600 spectrophotometer (Shimadzu Corporation, Tokyo, Japan) in the range of 350–800 nm. X-ray powder diffraction (XRD) analysis was conducted using a Rigaku D/MAX 3C X-ray diffractometer (Rigaku Corporation, Tokyo, Japan) with Cu Kα radiation (λ = 1.5418 Å). X-ray photoelectron spectra (XPS) analysis was performed using a Thermo Scientific ESACLAB 250 Xi A1440 system (Thermo Fisher Scientific, Waltham, MA, USA).

3. Results and Discussion

Figure 2 shows the TEM images of Au@Cu2O NCs with different Cu2O shell thicknesses. It is shown in Figure S1 that the average diameter of the Au core with quasi-spherical shape is about 13 nm. When the added volume of Au colloid solution is 1.00, 3.00, 5.00, and 7.00 mL, as depicted in Figure 2a–d, the Cu2O shell thickness of AC-1 NCs, AC-3 NCs, AC-5 NCs, and AC-7 NCs is about 82, 71, 53, and 30 nm, respectively. The surfaces of Au nanocrystals are coated by Cu2O to form a core-shell structure because the citrate ligands existing on the surfaces of the Au nanocrystals act as the binder and promote the contact of Cu2+ ions with the Au surfaces during the reduction process. The reduction of Cu2+ ions and the growth of Cu2O take place on the surfaces of Au cores [41]. As a result, Au@Cu2O NCs with core-shell structures are achieved. All of the four samples exhibit a relatively uniform spherical morphology and have good dispersion, which ensures that most of core-shell nanocrystals are involved in catalytic reactions. In addition, as different volumes of Au colloid solution are introduced into the Cu2+ reaction mixture with a fixed initial concentration, with the increase of molar ratio of Au to Cu2+, the Cu2O shell thickness attached to Au cores decreases. Similar results were found by other research groups [42,43]. Notably, when the volume of Au colloid solution is further increased to 9.00 mL, Cu2O shells on the surfaces of Au nanocrystals almost disappear. As for the sample of AC-11 NCs, this abnormal phenomenon is more evident. A large number of pure Au nanocrystals without Cu2O shells are observed, as depicted in Figure 2e,f. This is most probably because Au nanocrystals reach the supersaturation point so that there is not enough number of Cu2+ ions in the reaction system to form the Cu2O shells on the surfaces of Au nanocrystals [26].

Figure 2.

Figure 2

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TEM images of AC-1 NCs (a), AC-3 NCs (b), AC-5 NCs (c), AC-7 NCs (d), AC-9 NCs, (e) and AC-11 NCs (f).

A selected area electron diffraction (SAED) pattern of AC-1 NCs is shown in Figure 3a. The concentric diffraction rings are indexed to be the (110), (111), (200), (220), and (311) planes of pure Cu2O, and (111) plane of Au. The XRD patterns of pure Cu2O nanocrystals and prepared AC-1 NCs are shown in Figure S2. As for AC-1 NCs, apart from the characteristic diffraction peaks of Cu2O (JCPDS card no. 05-0667), the diffraction peaks appearing at 38.18, 64.57, and 77.54° are corresponding to (111), (220), and (311) of Au (JCPDS card no. 04-0784) [44,45]. Both of the SAED and XRD results confirm that the prepared AC-1 NCs consist of Cu2O and Au. Figure 3b shows the high-angle annular dark-field scanning TEM (HAADF-STEM) images and the corresponding energy-dispersive spectroscopy (EDS) elemental mapping images of AC-1 NCs. It is easily observed that the outer Cu2O completely cover the Au cores because the image contrast is brighter for the heavier element. In addition, EDS mapping images of Au, Cu, and O elements show that the Au element is located in the center of the core-shell structure, and Cu and O elements are uniformly distributed on the surfaces of Au nanocrystals [46].

Figure 3.

Figure 3

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SEAD pattern (a) and HAADF-STEM images (b) of AC-1 NCs with corresponding EDS elemental mapping images (Au, Cu, and O).

Figure 4 shows the UV–Vis absorption spectra of Au colloid solution, Cu2O nanocrystals, and Au@Cu2O NCs with different shell thicknesses. The pure Au colloid solution exhibits a prominent SPR absorption peak at 518 nm. A strong absorption peak of pure Cu2O nanocrystals appears at 464 nm. As for Au@Cu2O NCs, two broad absorption peaks are observed. The absorption peak located at 526–584 nm may be attributed to plasmon resonance of Au cores, while the peak at 406–432 nm is ascribed to Cu2O shells. The SPR peak of Au@Cu2O NCs shows a significant redshift compared with that of pure Au colloid solution. With the increase of the Cu2O thickness, the redshift of SPR peak becomes more obvious, and the SPR peak intensity becomes weaker. A possible explanation is that Cu2O shells have larger refractive index compared to that of the solvent [26]. Apart from the SPR peak, it is found that there is a blueshift in the wavelength centered at 406–432 nm for Au@Cu2O NCs compared with the absorption peak of pure Cu2O nanocrystals due to the interband transition in Cu2O and the scattering of Cu2O shells [47]. It is worth emphasizing that the absorption peak of AC-9 NCs and AC-11 NCs resulting from Cu2O shells is almost invisible because the Cu2O shells are not formed on the surfaces of these two samples. The inset of Figure 4 is an optical picture of the Au@Cu2O NCs. The color of the solution changes from yellow to dark purple with the decrease of the Cu2O shell thickness.

Figure 4.

Figure 4

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UV–Vis absorption spectra of Au colloid solution, Cu2O nanocrystals, AC-1 NCs, AC-3 NCs, AC-5 NCs, AC-7 NCs, AC-9 NCs, and AC-11 NCs. The inset is the photograph of AC-1 NCs, AC-3 NCs, AC-5 NCs, AC-7 NCs, AC-9 NCs, and AC-11 NCs.

XPS is employed to characterize the Cu oxidation state of Au@Cu2O NCs [48]. The high resolution XPS scans of Au@Cu2O NCs are presented in Figure 5. Cu 2p spectrum of AC-1 NCs exhibits two contributions assigned to Cu2O instead of Cu (0) or Cu (II) [49,50], which are Cu 2p3/2 and Cu 2p1/2 at 931.1 and 951.1 eV, respectively [51,52]. The peak positions of Cu 2p3/2 and Cu 2p1/2 slightly shift towards the higher binding energy side with the decrease of Cu2O thickness owing to the variation in the chemical environment, which demonstrates an interaction between Au and Cu2O [47]. In addition, because the XPS spectra intensity is directly proportional to the concentration of atoms, the binding energy intensity of Cu 2p decreases when the Cu2O thickness on the surfaces of Au decreases.

Figure 5.

Figure 5

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High resolution XPS scans of Cu 2p for AC-1 NCs, AC-3 NCs, AC-5 NCs, AC-7 NCs, AC-9 NCs, and AC-11 NCs.

In order to evaluate the catalytic activity of Au@Cu2O NCs in dark conditions, a model reaction for the degradation of MO in the presence of excess NaBH4 is executed by monitoring the change of the UV–Vis absorption peak at λ max = 464 nm. Au nanocrystals, AC-1 NCs, AC-3 NCs, AC-5 NCs, and AC-7 NCs are used to catalyze the reduction of MO solution. Figure 6a illustrates the ln(C/C0) versus reaction time plots, and the degradation of MO solution is completed in 42, 50, 48, 46, and 45 min, respectively. The catalytic activity of Au nanocrystals is higher than that of Au@Cu2O NCs. Unfortunately, Au nanocrystals often tend to agglomerate in order to minimize their surface energy, which restricts their real application [25]. The subtle difference in reduction rate of MO by Au@Cu2O NCs depends upon the differences of thickness of Cu2O shells and size of catalysts due to the size effect [53]. Therefore, the Cu2O shells on the surfaces of Au nanocrystals play a crucial role in catalyzing the degradation of MO. Since the stability is an important index in appraising the quality of catalysts, the stability of Au@Cu2O NCs is also evaluated [54]. Four-run recycle degradation experiments in Figure 6b demonstrate that the four samples can be used for at least four successive cycles. AC-1 NCs have the highest catalytic stability. UV–Vis absorption spectra for reduction of MO catalyzed by AC-1 NCs are displayed in Figure 6c. The absorption peak at 464 nm for MO shows a downward trend and disappears within 50 min. The pseudo-first-order kinetics equation is applied to evaluate the rate constant of the reaction. The rate coefficients are obtained by using the following equation:

ln(C/C0) = −kt, (1)

where C is the concentration of MO at reaction time t, C0 is the initial concentration of MO at t = 0 and k is the rate constant. As shown in Figure 6d, the relationship of ln(C/C0) versus reaction time indicates that the reduction of MO catalyzed by AC-1 NCs follows the pseudo-first-order kinetics. The correlation coefficient R2 and the rate constant k are 0.991 and 0.299 min−1, respectively.

Figure 6.

Figure 6

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Time-dependent efficiency (a) of degrading MO solution catalyzed by Au nanocrystals, AC-1 NCs, AC-3 NCs, AC-5 NCs, and AC-7 NCs and recycle experiments (b) of degrading MO solution by AC-1 NCs, AC-3 NCs, AC-5 NCs, and AC-7 NCs. Time-dependent UV–Vis absorption spectra (c) and corresponding pseudo-first-order kinetic reaction plots (d) for reduction of MO catalyzed by AC-1 NCs.

To enhance the catalytic performance, Ag nanocrystals are further deposited onto the surfaces of AC-1 NCs. Compared with AC-1 NCs, the TEM image of AC-1-Ag NCs in Figure 7a shows that there is no appreciable morphological change after coating with Ag nanocrystals. However, the SAED pattern of AC-1-Ag NCs in Figure 7b indicates that new diffraction rings appear, which are assigned to (111), (200), (220), and (311) crystal planes of Ag. XRD pattern of AC-1-Ag NCs in Figure S2 also confirms the existence of Ag nanocrystals. Four additional diffraction peaks located at 37.96, 44.2, 64.58, and 77.26° match the corresponding planes of Ag (JCPDS card no. 04-0783) [55,56,57]. HAADF-STEM and the corresponding EDS mapping images of AC-1-Ag NCs are presented in Figure 7c. It is observed that Ag elements are uniformly dispersed onto the surfaces of AC-1 NCs. High resolution XPS scans of Ag 3d for AC-1-Ag NCs are fitted by XPSPEAK41 software, as shown in Figure S3a. Binding energy peaks located at 368.1 and 374.1 eV with a spin-orbit splitting of 6.0 eV are ascribed to Ag 3d5/2 and Ag 3d3/2, which are consistent with the standard reference XPS spectrum of metallic Ag [58,59,60]. Figure S3b depicts UV–Vis absorption spectra of AC-1 NCs and AC-1-Ag NCs. By comparison, AC-1-Ag NCs have a strong and broad absorption peak between 310 and 480 nm, which is mainly caused by the SPR of Ag [61,62,63].

Figure 7.

Figure 7

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TEM image (a), SEAD pattern (b), HAADF-STEM image (c) of AC-1-Ag NCs with corresponding EDS elemental mapping images (Au, Cu, O, and Ag).

The catalytic activity of AC-1-Ag NCs in the reduction of MO is also investigated under dark condition. The UV–Vis absorption spectra and the corresponding ln(C/C0) versus reaction time plots of MO solution catalyzed by AC-1-Ag NCs are shown in Figure 8a,b. The complete degradation of MO solution can be realized within only 4 min. The linear relationship between logarithm of absorbance ln(C/C0) and reaction time (t) indicates that the reduction of MO by AC-1-Ag NCs follows pseudo-first-order kinetics. The rate constant of MO reduction is as high as 1.081 min−1. The above results show that the catalytic rate of AC-1-Ag NCs is significantly improved compared with that of AC-1 NCs owing to the presence of Ag nanocrystals on the surfaces of AC-1 NCs. The reusability of AC-1-Ag NCs for catalytic reduction of MO is also been evaluated, as shown in Figure 8c. The catalytic reactivity of AC-1-Ag NCs decreases slightly after four cycles, indicating that AC-1-Ag NCs are highly reusable. To better understand the possible mechanism for the reduction of MO by AC-1-Ag NCs with the help of excess NaBH4, MO is reduced by AC-1-Ag NCs without the addition of NaBH4 and by using NaBH4 alone. Figure 8d demonstrates negligible degradation of MO by adding only AC-1-Ag NCs and only NaBH4. From this point of view, both the catalysts and the electron donors (BH4− ions) originated from NaBH4 are essential to reduce MO. This strongly confirms the prominent catalytic effects of AC-1-Ag NCs in the presence of an excess amount of NaBH4 on the reduction of MO. In fact, the kinetic barrier between acceptor molecules (MO) and BH4− ions is too high to allow the reduction reaction of MO to proceed [64]. However, the addition of AC-1-Ag NCs provides a platform to attach BH4− ions and MO molecules to the surfaces of AC-1-Ag NCs. In addition, the catalytic activities of AC-1-Ag NCs and Cu2O-Ag nanocomposites are also compared, as presented in Figure S4. The results show that AC-1-Ag NCs has better catalytic activity. The Schottky barrier existing at the interfaces of the noble metal and the semiconductor enhances the collection efficiency of carriers, but more importantly Ag nanocrystals on the surfaces and internal Au cores of AC-1-Ag NCs jointly facilitate the charge transfer from BH4− to MO [65]. The synergistic effects of AC-1-Ag NCs and NaBH4 greatly promoted the catalytic efficiency of AC-1-Ag NCs. Therefore, AC-1-Ag NCs with good stability have the ability to efficiently catalyze the reduction of MO, which poses a great possibility as the hopeful nanocatalysts for application in water pollution treatment.

Figure 8.

Figure 8

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Time-dependent UV–Vis absorption spectra (a) and corresponding pseudo-first-order kinetic reaction plots (b) for reduction of MO catalyzed by AC-1-Ag NCs. Reusability of AC-1-Ag NCs for catalytic reduction of MO (c). Time-dependent degradation efficiency of MO solution catalyzed by AC-1-Ag NCs in different catalytic reaction conditions (d).

4. Conclusions

To sum up, we synthesized Au@Cu2O-Ag NCs by a simple galvanic replacement reaction method. The Au@Cu2O NCs with controllable shell thickness could be prepared by changing the amount of Au colloid solution. The results of the TEM images indicated that the shell thickness of Au@Cu2O NCs could be changed. It had been also demonstrated that Ag nanocrystals could be successfully compounded on Au@Cu2O NCs. Compared with Au@Cu2O NCs, the catalytic efficiency of Au@Cu2O-Ag NCs was significantly improved. Au@Cu2O-Ag NCs were capable of rapidly reducing MO within 4 min. In addition, Au@Cu2O-Ag NCs had good reusability and high stability. Therefore, the nanocatalysts we designed have great potential to remove organic dye pollutants from wastewater by catalytic degradation.

Supplementary Materials

Click here for additional data file. (647.6KB, pdf)

The following are available online at https://www.mdpi.com/2079-4991/10/1/48/s1. Figure S1: TEM image of the Au nanocrystals, the insert is the particle size distribution. Figure S2: XRD patterns of Cu2O nanocrystals, AC-1 NCs, and AC-1-Ag NCs. Figure S3: High resolution XPS scans of Ag 3d for AC-1-Ag NCs (a) and UV–Vis absorbance spectra (b) of AC-1 NCs and AC-1-Ag NCs. Figure S4: Time-dependent efficiency of degrading MO solution catalyzed by Au@Cu2O-Ag NCs and Cu2O-Ag NCs.

Author Contributions

Conceptualization, Y.L.; Software, S.Y.; Validation, M.G.; Formal Analysis, H.Z. and J.L.; Writing Draft, T.W. and Y.K.; Data curation, N.R.K. and C.G.; Supervision, Y.L.; Funding Acquisition, Y.L. All authors have read and agreed to the published version of the manuscript.

Funding

This work was supported by the National Natural Science Foundation of China (Grant Numbers 21676115).

Conflicts of Interest

The authors declare no conflict of interest.

References

  • 1.Muthu K., Priya S. Green synthesis, characterization and catalytic activity of silver nanoparticles using Cassia auriculata flower extract separated fraction. Spectrochim. Acta A. 2017;179:66–72. doi: 10.1016/j.saa.2017.02.024. [DOI] [PubMed] [Google Scholar]
  • 2.Zhou X., Xu M., Wang L., Liu X. The Adsorption of Methylene Blue by an Amphiphilic Block Co-Poly (Arylene Ether Nitrile) Microsphere-Based Adsorbent: Kinetic, Isotherm, Thermodynamic and Mechanistic Studies. Nanomaterials. 2019;9:1356. doi: 10.3390/nano9101356. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 3.Lutsyk P., Arif R., Hruby J., Bukivskyi A., Vinijchuk O., Shandura M., Yakubovskyi V., Kovtun Y., Rance G.A., Fay M., et al. A sensing mechanism for the detection of carbon nanotubes using selective photoluminescent probes based on ionic complexes with organic dyes. Light Sci. Appl. 2016;5:e16028. doi: 10.1038/lsa.2016.28. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 4.Hameed B.B., Ismail Z.Z. Decolorization, biodegradation and detoxification of reactive red azo dye using non-adapted immobilized mixed cells. Biochem. Eng. J. 2018;137:71–77. doi: 10.1016/j.bej.2018.05.018. [DOI] [Google Scholar]
  • 5.Zhao H., Zhang G., Zhang Q. MnO2/CeO2 for catalytic ultrasonic degradation of methyl orange. Ultrason. Sonochem. 2014;21:991–996. doi: 10.1016/j.ultsonch.2013.12.002. [DOI] [PubMed] [Google Scholar]
  • 6.Gong R., Ye J., Dai W., Yan X., Hu J., Hu X., Li S., Huang H. Adsorptive Removal of Methyl Orange and Methylene Blue from Aqueous Solution with Finger-Citron-Residue-Based Activated Carbon. Ind. Eng. Chem. Res. 2013;52:14297–14303. doi: 10.1021/ie402138w. [DOI] [Google Scholar]
  • 7.Cai R., Zhang B., Shi J., Li M., He Z. Rapid Photocatalytic Decolorization of Methyl Orange under Visible Light Using VS4/Carbon Powder Nanocomposites. ACS Sustain. Chem. Eng. 2017;5:7690–7699. doi: 10.1021/acssuschemeng.7b01137. [DOI] [Google Scholar]
  • 8.Li J., Zhao H., Ma C., Han Q., Li M., Liu H. Preparation of Fe3O4@polyoxometalates Nanocomposites and Their Efficient Adsorption of Cationic Dyes from Aqueous Solution. Nanomaterials. 2019;9:649. doi: 10.3390/nano9040649. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 9.Raj S.I., Jaiswal A., Uddin I. Tunable porous silica nanoparticles as a universal dye adsorbent. RSC Adv. 2019;9:11212–11219. doi: 10.1039/C8RA10428J. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 10.Li S., Zhang H., Hu S., Liu J., Zhu Q., Zhang S. Synthesis of Hierarchical Porous Carbon in Molten Salt and Its Application for Dye Adsorption. Nanomaterials. 2019;9:1098. doi: 10.3390/nano9081098. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 11.Zhang B., Wang Z., Peng X., Wang Z., Zhou L., Yin Q. A Novel Route to Manufacture 2D Layer MoS2 and g-C3N4 by Atmospheric Plasma with Enhanced Visible-Light-Driven Photocatalysis. Nanomaterials. 2019;9:1139. doi: 10.3390/nano9081139. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 12.Chen S., Huang Y., Han X., Wu Z., Lai C., Wang J., Deng Q., Zeng Z., Deng S. Simultaneous and efficient removal of Cr(VI) and methyl orange on LDHs decorated porous carbons. Chem. Eng. J. 2018;352:306–315. doi: 10.1016/j.cej.2018.07.012. [DOI] [Google Scholar]
  • 13.Pargoletti E., Pifferi V., Falciola L., Facchinetti G., Depaolini A.R., Davoli E., Marelli M., Cappelletti G. A detailed investigation of MnO2 nanorods to be grown onto activated carbon. High efficiency towards aqueous methyl orange adsorption/degradation. Appl. Surf. Sci. 2019;472:118–126. doi: 10.1016/j.apsusc.2018.03.170. [DOI] [Google Scholar]
  • 14.Ma X., Dai Y., Yu L., Huang B. Energy transfer in plasmonic photocatalytic composites. Light Sci. Appl. 2016;5:e16017. doi: 10.1038/lsa.2016.17. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 15.Feng Q., Li S., Ma W., Fan H.-J., Wan X., Lei Y., Chen Z., Yang J., Qin B. Synthesis and characterization of Fe3O4/ZnO-GO nanocomposites with improved photocatalytic degradation methyl orange under visible light irradiation. J. Alloys Compd. 2018;737:197–206. doi: 10.1016/j.jallcom.2017.12.070. [DOI] [Google Scholar]
  • 16.Szeto W., Li J., Huang H., Leung D.Y.C. VUV/TiO2 photocatalytic oxidation process of methyl orange and simultaneous utilization of the lamp-generated ozone. Chem. Eng. Sci. 2018;177:380–390. doi: 10.1016/j.ces.2017.10.008. [DOI] [Google Scholar]
  • 17.Liu Y., Zhang Y.Y., Kou Q., Chen Y., Han D.L., Wang D.D., Lu Z.Y., Chen L., Yang J.H., Xing S. Eco-friendly seeded Fe3O4-Ag nanocrystals: A new type of highly efficient and low cost catalyst for methylene blue reduction. RSC Adv. 2018;8:2209–2218. doi: 10.1039/C7RA11348J. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 18.Liu Y., Zhang Y., Kou Q., Chen Y., Sun Y., Han D., Wang D., Lu Z., Chen L., Yang J., et al. Highly Efficient, Low-Cost, and Magnetically Recoverable FePt-Ag Nanocatalysts: Towards Green Reduction of Organic Dyes. Nanomaterials. 2018;8:329. doi: 10.3390/nano8050329. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 19.Chen Y., Zhang Y., Kou Q., Liu Y., Han D., Wang D., Sun Y., Zhang Y., Wang Y., Lu Z., et al. Enhanced Catalytic Reduction of 4-Nitrophenol Driven by Fe3O4-Au Magnetic Nanocomposite Interface Engineering: From Facile Preparation to Recyclable Application. Nanomaterials. 2018;8:353. doi: 10.3390/nano8050353. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 20.Leteba G.M., Mitchell D.R.G., Levecque P.B.J., Lang C.I. Solution-Grown Dendritic Pt-Based Ternary Nanostructures for Enhanced Oxygen Reduction Reaction Functionality. Nanomaterials. 2018;8:462. doi: 10.3390/nano8070462. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 21.Xie P., Qi Y., Wang R., Wu J., Li X. Aqueous Gold Nanoparticles Generated by AC and Pulse-Power-Driven Plasma Jet. Nanomaterials. 2019;9:1488. doi: 10.3390/nano9101488. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 22.Pincella F., Isozaki K., Miki K. A visible light-driven plasmonic photocatalyst. Light Sci. Appl. 2014;3:e133. doi: 10.1038/lsa.2014.14. [DOI] [Google Scholar]
  • 23.Linnenbank H., Grynko Y., Fo¨rstner J., Linden S. Second harmonic generation spectroscopy on hybrid plasmonic/dielectric nanoantennas. Light Sci. Appl. 2016;5:e16013. doi: 10.1038/lsa.2016.13. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 24.Shan H., Ying Y., Wang X., Yang L., Zu S., Du B., Han T., Li B., Yu L., Wu J., et al. Direct observation of ultrafast plasmonic hot electron transfer in the strong coupling regime. Light Sci. Appl. 2019;8:9. doi: 10.1038/s41377-019-0121-6. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 25.Islam M.T., Jing H., Yang T., Zubia E., Goos A.G., Bernal R.A., Botez C.E., Narayan M., Chan C.K., Noveron J.C. Fullerene stabilized gold nanoparticles supported on titanium dioxide for enhanced photocatalytic degradation of methyl orange and catalytic reduction of 4-nitrophenol. J. Environ. Chem. Eng. 2018;6:3827–3836. doi: 10.1016/j.jece.2018.05.032. [DOI] [Google Scholar]
  • 26.Kuo M.Y., Hsiao C.F., Chiu Y.H., Lai T.H., Fang M.J., Wu J.Y., Chen J.W., Wu C.L., Wei K.H., Lin H.C., et al. Au@Cu2O core@shell nanocrystals as dual-functional catalysts for sustainable environmental applications. Appl. Catal. B Environ. 2019;242:499–506. doi: 10.1016/j.apcatb.2018.09.075. [DOI] [Google Scholar]
  • 27.Sai C.D., Ngac A.B. Effect of core-shell structure on optical properties of Au-Cu2O nanoparticles. Physica. B. 2018;532:216–220. doi: 10.1016/j.physb.2017.11.048. [DOI] [Google Scholar]
  • 28.Li D., Wang Z.L., Wang Z. Phase Separation Prior to Alloying Observed in Vacuum Heating of Hybrid Au/Cu2O Core-Shell Nanoparticles. J. Phys. Chem. C. 2017;121:1387–1392. doi: 10.1021/acs.jpcc.6b12502. [DOI] [Google Scholar]
  • 29.Pougin A., Dodekatos G., Dilla M., Tüysüz H., Strunk J. Au@TiO2 Core-Shell Composites for the Photocatalytic Reduction of CO2. Chemistry. 2018;24:12416–12425. doi: 10.1002/chem.201801796. [DOI] [PubMed] [Google Scholar]
  • 30.Jency D.A., Parimaladevi R., Umadevi M. Au-TiO2 Core Shell Motif Scavenger: Facile Synthesis, High SERS Effect, Synergistic Photocatalytic Activity. J. Clust. Sci. 2018;29:793–804. doi: 10.1007/s10876-018-1401-7. [DOI] [Google Scholar]
  • 31.Hamidi F., Aslani F. TiO2-based Photocatalytic Cementitious Composites: Materials, Properties, Influential Parameters, and Assessment Techniques. Nanomaterials. 2019;9:1444. doi: 10.3390/nano9101444. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 32.Kumar A., Kumar A., Sharma G., Al-Muhtaseb A.H., Naushad M., Ghfar A.A., Stadler F.J. Quaternary magnetic BiOCl/g-C3N4/Cu2O/Fe3O4 nano-junction for visible light and solar powered degradation of sulfamethoxazole from aqueous environment. Chem. Eng. J. 2018;334:462–478. doi: 10.1016/j.cej.2017.10.049. [DOI] [Google Scholar]
  • 33.Guo S., Wang Y., Zhang F., Gao R., Liu M., Dong L., Liu Y., Zhang Y., Chen L. In Situ Synthesis of Ag@Cu2O-rGO Architecture for Strong Light-Matter Interactions. Nanomaterials. 2018;8:444. doi: 10.3390/nano8060444. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 34.Zhu J., Lu N., Chen W., Kong L., Yang Y., Ma D., Huang S. Influence of Au Nanoparticle Shape on Au@Cu2O Heterostructures. J. Nanomater. 2015;16:1–9. doi: 10.1155/2015/389790. [DOI] [Google Scholar]
  • 35.Zhang L., Blom D.A., Wang H. Au-Cu2O Core-Shell Nanoparticles: A Hybrid Metal-Semiconductor Heteronanostructure with Geometrically Tunable Optical Properties. Chem. Mater. 2011;23 doi: 10.1021/cm202078t. [DOI] [Google Scholar]
  • 36.Sasmal A.K., Pal J., Sahoo R., Kartikeya P., Dutta S., Pal T. Superb Dye Adsorption and Dye Sensitized Change of Cu2O-Ag Crystal Faces in the Dark. J. Phys. Chem. C. 2016;120:21580–21588. doi: 10.1021/acs.jpcc.6b07300. [DOI] [Google Scholar]
  • 37.Chen R., Lu J., Liu S., Zheng M., Wang Z. The preparation of Cu2O@Au yolk/shell structures for efficient photocatalytic activity with a self-generated acid etching method. J. Mater. Sci. 2017;53:1781–1790. doi: 10.1007/s10853-017-1614-4. [DOI] [Google Scholar]
  • 38.Naz G., Shamsuddin M., Butt F.K., Bajwa S.Z., Khan W.S., Irfan M., Irfan M. Au/Cu2O core/shell nanostructures with efficient photoresponses. Chin. J. Phys. 2019;59:307–316. doi: 10.1016/j.cjph.2019.03.008. [DOI] [Google Scholar]
  • 39.Zhang X., Chen Y.L., Liu R.-S., Tsai D.P. Plasmonic photocatalysis. Rep. Prog. Phys. 2013;76:046401. doi: 10.1088/0034-4885/76/4/046401. [DOI] [PubMed] [Google Scholar]
  • 40.Polte J., Ahner T.T., Delissen F., Sokolov S., Emmerling F., Thunemann A.F., Kraehnert R. Mechanism of gold nanoparticle formation in the classical citrate synthesis method derived from coupled in situ XANES and SAXS evaluation. J. Am. Chem. Soc. 2010;132:1296–1301. doi: 10.1021/ja906506j. [DOI] [PubMed] [Google Scholar]
  • 41.Lin Y.K., Chiang Y.J., Hsu Y.J. Metal-Cu2O core-shell nanocrystals for gas sensing applications: Effect of metal composition. Sens. Actuators B Chem. 2014;204:190–196. doi: 10.1016/j.snb.2014.07.094. [DOI] [Google Scholar]
  • 42.Meir N., Plante I.J.L., Flomin K., Chockler E., Moshofsky B., Diab M., Volokh M., Mokari T. Studying the chemical, optical and catalytic properties of noble metal (Pt, Pd, Ag, Au)-Cu2O core-shell nanostructures grown via a general approach. J. Math. Chem. A. 2013;1:1763–1769. doi: 10.1039/C2TA00721E. [DOI] [Google Scholar]
  • 43.Lee C., Shin K., Lee Y.J., Jung C., Lee H.M. Effects of shell thickness on Ag-Cu2O core-shell nanoparticles with bumpy structures for enhancing photocatalytic activity and stability. Catal. Today. 2017;303:313. doi: 10.1016/j.cattod.2017.08.016. [DOI] [Google Scholar]
  • 44.Chen G., Niu M., Cui L., Bao F., Zhou L., Wang Y. Facile Synthesis and Formation Mechanism of Metal Chalcogenides Hollow Nanoparticles. J. Phys. Chem. C. 2009;113:7522–7525. doi: 10.1021/jp9012834. [DOI] [Google Scholar]
  • 45.Celorrio V., Montes de Oca M.G., Plana D., Moliner R., Lázaro M.J., Fermín D.J. Effect of Carbon Supports on Electrocatalytic Reactivity of Au-Pd Core-Shell Nanoparticles. J. Phys. Chem. C. 2012;116:6275–6282. doi: 10.1021/jp211747a. [DOI] [Google Scholar]
  • 46.Liu Y., Kou Q., Wang D., Chen L., Sun Y., Lu Z., Zhang Y., Wang Y., Xing S.G. Rational synthesis and tailored optical and magnetic characteristics of Fe3O4-Au composite nanoparticles. J. Mater. Sci. 2017;52:10163–10174. doi: 10.1007/s10853-017-1200-9. [DOI] [Google Scholar]
  • 47.Chen L., Liu M., Zhao Y., Kou Q., Wang Y., Liu Y., Zhang Y., Yang J., Jung Y.M. Enhanced catalyst activity by decorating of Au on Ag@Cu2O nanoshell. Appl. Surf. Sci. 2018;435:72–78. doi: 10.1016/j.apsusc.2017.11.082. [DOI] [Google Scholar]
  • 48.Lu C., Qi L., Yang J., Wang X., Zhang D., Xie J., Ma J. One-Pot Synthesis of Octahedral Cu2O Nanocages via a Catalytic Solution Route. Adv. Mater. 2005;17:2562–2567. doi: 10.1002/adma.200501128. [DOI] [Google Scholar]
  • 49.Du X., Luo S., Du H. Monodisperse and self-assembled Pt-Cu nanoparticles as an efficient electrocatalyst for the methanol oxidation reaction. J. Mater. Chem. A. 2016;4:1579–1585. doi: 10.1039/C5TA09261B. [DOI] [Google Scholar]
  • 50.Ranjith Kumar D., Manoj D., Santhanalakshmi J. Optimization of site specific adsorption of oleylamine capped CuO nanoparticles on MWCNTs for electrochemical determination of guanosine. Sens. Actuators B Chem. 2013;188:603–612. doi: 10.1016/j.snb.2013.07.067. [DOI] [Google Scholar]
  • 51.Chen L., Zhang F., Deng X., Xue X., Wang L., Sun Y., Feng J., Zhang Y., Wang Y., Jung Y.M. SERS study of surface plasmon resonance induced carrier movement in Au@Cu2O core-shell nanoparticles. Spectrochim. Acta A. 2018;189:608–612. doi: 10.1016/j.saa.2017.08.065. [DOI] [PubMed] [Google Scholar]
  • 52.Liao J., Feng Y., Wu S., Ye H., Zhang J., Zhang X., Xie F., Li H. Hexagonal CuCo2O4 Nanoplatelets, a Highly Active Catalyst for the Hydrolysis of Ammonia Borane for Hydrogen Production. Nanomaterials. 2019;9:360. doi: 10.3390/nano9030360. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 53.Lei M., Wu W., Yang S., Zhang X., Xing Z., Ren F., Xiao X., Jiang C. Design of Enhanced Catalysts by Coupling of Noble Metals (Au, Ag) with Semiconductor SnO2 for Catalytic Reduction of 4-Nitrophenol. Part. Part. Syst. Charact. 2016;33:212–220. doi: 10.1002/ppsc.201500128. [DOI] [Google Scholar]
  • 54.Chen Y., Wu T., Xing G., Kou Y., Li B., Wang X., Gao M., Chen L., Wang Y., Yang J., et al. Fundamental Formation of Three-Dimensional Fe3O4 Microcrystals and Practical Application in Anchoring Au as Recoverable Catalyst for Effective Reduction of 4-Nitrophenol. Ind. Eng. Chem. Res. 2019;58:15151–15161. doi: 10.1021/acs.iecr.9b02777. [DOI] [Google Scholar]
  • 55.Zhou Y., Liu F. Highly efficient visible light-driven Ag/FeOOH/MMT composite photo-catalyst for degrading phenol. Appl. Phys. A Mater. 2019;125 doi: 10.1007/s00339-019-2472-5. [DOI] [Google Scholar]
  • 56.Huang Y., Fang Y., Zhang Z., Zhu L., Sun M. Nanowire-supported plasmonic waveguide for remote excitation of surface-enhanced Raman scattering. Light Sci. Appl. 2014;3:e199. doi: 10.1038/lsa.2014.80. [DOI] [Google Scholar]
  • 57.Siampour H., Kumar S., Davydov V.A., Kulikova L.F., Agafonov V.N., Bozhevolnyi S.I. On-chip excitation of single germanium vacancies in nanodiamonds embedded in plasmonic waveguides. Light Sci. Appl. 2018;7:61. doi: 10.1038/s41377-018-0062-5. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 58.Kumar M., Deka S. Multiply twinned AgNi alloy nanoparticles as highly active catalyst for multiple reduction and degradation reactions. ACS Appl. Mater. Interfaces. 2014;6:16071–16081. doi: 10.1021/am503913y. [DOI] [PubMed] [Google Scholar]
  • 59.Yao J., Quan Y., Gao M., Gao R., Chen L., Liu Y., Lang J., Shen H., Zhang Y., Yang L., et al. AgNPs decorated Mg-doped ZnO heterostructure with dramatic SERS activity for trace detection of food contaminants. J. Math. Chem. C. 2019;7:8199–8208. doi: 10.1039/C8TC06588H. [DOI] [Google Scholar]
  • 60.Sun M., Zhang Z., Wang P., Li Q., Ma F., Xu H. Remotely excited Raman optical activity using chiral plasmon propagation in Ag nanowires. Light Sci. Appl. 2013;2:e112. doi: 10.1038/lsa.2013.68. [DOI] [Google Scholar]
  • 61.Xiong J., Li Z., Chen J., Zhang S., Wang L.Z., Dou S.X. Facile synthesis of highly efficient one-dimensional plasmonic photocatalysts through Ag@Cu2O core-shell heteronanowires. ACS Appl. Mater. Interfaces. 2014;6:15716–15725. doi: 10.1021/am502516s. [DOI] [PubMed] [Google Scholar]
  • 62.Zhuo X.L., Yip H.K., Cui X.M., Wang J.F., Lin H.Q. Colour routing with single silver nanorods. Light Sci. Appl. 2019;8:39. doi: 10.1038/s41377-019-0150-1. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 63.Li D., Sun X., Jia Y., Stockman M.I., Paudel H.P., Song H., Jiang H., Li Z. Direct observation of localized surface plasmon field enhancement by Kelvin probe force microscopy. Light Sci. Appl. 2017;6:e17038. doi: 10.1038/lsa.2017.38. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 64.Huang J.F., Vongehr S., Tang S., Lu H., Shen J., Meng X. Ag dendrite-based Au/Ag bimetallic nanostructures with strongly enhanced catalytic activity. Langmuir. 2009;25:11890–11896. doi: 10.1021/la9015383. [DOI] [PubMed] [Google Scholar]
  • 65.Das R., Sypu V.S., Paumo H.K., Bhaumik M., Maharaj V., Maity A. Silver decorated magnetic nanocomposite (Fe3O4@PPy-MAA/Ag) as highly active catalyst towards reduction of 4-nitrophenol and toxic organic dyes. Appl. Catal. B Environ. 2019;244:546–558. doi: 10.1016/j.apcatb.2018.11.073. [DOI] [Google Scholar]

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