Table 1.
Compounds a | RI b | % c | |
Hydrocarbons | |||
n-heneicosane | 2097 | tr | |
n-pentacosane | 2495 | tr | |
total | tr | ||
Alcohols | |||
hex-3-enol (Z/E configuration n.i.) | 853 | 0.8 | |
hex-2-enol (Z/E configuration n.i.) | 861 | tr | |
n-hexanol | 864 | 0.8 | |
oct-1-en-3-ol | 978 | tr | |
n-octanol | 1069 | m (1.3) | |
n-decanol | 1271 | tr | |
total | 2.9 | ||
Ketones | |||
isophorone | 1125 | tr | |
1-phenylbut-2-enone | 1312 | 0.3 | |
(Z)-jasmone | 1401 | tr | |
geranylacetone | 1452 | 0.2 | |
(E)-β-ionone | 1490 | 0.2 | |
6,10,14-trimethylpentadecan-2-one | 1843 | 1.1 | |
total | 1.8 | ||
Carboxylic acids | |||
isovaleric acid | 826 | tr | |
2-methylbutanoic acid | 837 | tr | |
hexanoic acid | 973 | 0.3 | |
benzoic acid | 1159 | tr | |
octanoic acid | 1167 | tr | |
dodecanoic acid | 1559 | 0.2 | |
tetradecanoic acid | 1759 | 0.7 | |
hexadecanoic acid | 1963 | 2.4 | |
total | 3.6 | ||
Esters | |||
isopentyl isovalerate | 1104 | 1.5 | |
n-hexyl butanoate | 1190 | tr | |
n-hexyl 2-methylbutanoate | 1236 | 0.4 | |
n-hexyl 3-methylbutanoate | 1239 | 2.3 | |
total | 4.2 | ||
Oxygenated monoterpenes | |||
trans-linalool oxide (furanoid) | 1074 | 0.1 | |
cis-linalool oxide (furanoid) | 1091 | tr | |
linalool | 1100 | 1.0 | |
terpinen-4-ol | 1182 | 0.4 | |
α-terpineol | 1195 | 0.3 | |
nerol | 1230 | 0.2 | |
geraniol | 1255 | tr | |
total | 2.0 | ||
Sesquiterpene hydrocarbons | |||
aromadendrene | 1449 | 0.2 | |
(E,E)-α-farnesene | 1508 | tr | |
δ-cadinene | 1530 | tr | |
α-calacorene | 1551 | tr | |
total | 0.2 | ||
Oxygenated sesquiterpenes | |||
(E)-nerolidol | 1565 | 0.2 | |
(Z)-dihydro-apofarnesol | 1579 | tr | |
spathulenol | 1588 | 0.5 | |
globulol | 1595 | 0.5 | |
viridiflorol | 1604 | 0.2 | |
epi-α-muurolol | 1658 | tr | |
α-cadinol | 1664 | 0.2 | |
(2E,6Z)-farnesol | 1744 | tr | |
total | 1.6 | ||
Oxygenated diterpenes | |||
isophytol | 1947 | tr | |
(1) | 2036 | 35.0 | |
phytol | 2111 | 0.5 | |
(2) + (3) | 2420 | m (16.0) | |
hardwickiic acid, methyl ester | 2431 | m (16.0) | |
total | 51.5 | ||
Aromatic compounds | |||
benzaldehyde | 963 | 0.1 | |
benzyl alcohol | 1035 | 1.8 | |
benzene acetaldehyde | 1045 | 0.1 | |
o-cresol | 1054 | 0.7 | |
acetophenone | 1068 | m (1.3) | |
phenylethyl alcohol | 1116 | tr | |
methyl salicylate | 1199 | 0.5 | |
4-vinyl phenol | 1218 | 0.1 | |
chavicol | 1254 | tr | |
p-anisaldehyde dimethyl acetal | 1256 | tr | |
p-ethylacetophenone | 1285 | tr | |
1-phenylbut-2-en-1-one | 1312 | 0.3 | |
2-methoxy-4-vinylphenol | 1317 | 0.5 | |
benzyl butanoate | 1346 | tr | |
eugenol | 1360 | 0.9 | |
methyl p-anisate | 1378 | tr | |
benzyl isovalerate | 1395 | 2.1 | |
vanillin | 1401 | tr | |
methyl eugenol | 1403 | 0.4 | |
2-methylbutyl benzoate | 1440 | 0.2 | |
ethyl vanillin | 1461 | tr | |
phenylethyl 3-methylbutanoate | 1493 | 0.5 | |
asaricin | 1500 | tr | |
isopentyl salicylate | 1539 | 0.1 | |
(3Z)-hexenyl benzoate | 1574 | 0.8 | |
n-hexyl benzoate | 1580 | 1.0 | |
(3Z)-hexenyl salicylate | 1673 | 0.2 | |
n-hexyl salicylate | 1681 | 0.2 | |
benzyl benzoate | 1771 | 0.6 | |
benzyl salicylate | 1877 | 0.5 | |
total | 12.9 | ||
Others | |||
7-methyl-1,6-dioxaspiro [4,5] decane (stereoisomer n.i.) | 1058 | 1.1 | |
vitispirane | 1286 | tr | |
total | 1.1 | ||
Total identified | 80.5 |
a n.i.: Non identified; b LRI: Linear retention index calculated on non-polar (SPB-5) column; c Relative percentage based on the peak area from the GC-MS analysis; tr: trace (<0.1%).