Table 1.

Components identified from the supercritical extract of P. ginseng (Russia).

№	Identity	Molecular Formula	Adducts	MS (m/z)	MS2 (m/z)	MS3 (m/z)
	Triterpene Glycosides (Dammarane Type)
1	Ginsenoside Rk3	C36H60O8	[M − H]−	619.21	421.22	229.06; 347.07; 403.19
2	Malonyl ginsenoside Rb1	C57H94O26	[M − H]−	1149.81	1107.65	459.31; 621.44; 783.46; 945.52
3	Malonyl ginsenoside Rb1 isomer	C57H94O26	[M − H]−	1193.7	1151.72	604.33; 826.59; 946.58; 1109.59
4	Ginsenoside Rg1	C42H72O14	[M − H + HCOOH]−	845.79	799.65	475.45; 637.61
5	Ginsenoside Rd isomer	C48H82O18	[M − H + HCOOH]−	991.83	945.73	391.43; 475.5; 637.62; 783.68
6	Ginsenoside Rg6	C42H70O12	[M + Na]+	765.41	405.39	171.07; 281.12
7	Acetyl ginsenoside Rg1 isomer	C44H74O15	[M + Na]+	841.55	661.5	481.53; 573.28; 643.32
8	Ginsenoside Rf	C42H72O14	[M − H]−	846.81	799.65	391.34; 475.46; 545.54; 637.55
9	(Yesanchinoside d isomer	C44H74O15	[M + Na]+	841.62	661.47	481.48; 541.46; 571.59; 601.27; 643.42
10	Ginsenoside Rb1	C54H92O23	[M − H]−	1107.88	783.7	621.57; 460.52
	Ginsenoside Rb1	C54H92O23	[M + Na]+	1131.63	789.55	245.03; 365.10; 627.52; 705.44
11	Ginsenoside Rd	C48H82O18	[M − H]−	945.93	783.65	621.63; 459.39
12	Ginsenoside 20-glc-Rf	C48H82O19	[M − H]−	961.84	915.76	292.31; 375.99; 459.51; 621.51; 783.75
13	Ginsenoside 25-OH-Rh4	C36H62O9	[M − H]−	637.6	239.14
14	Ginsenoside 20(R)-Rh1	C36H62O9	[M − H]−	683.65	475.4	375.38
15	Ginsenoside 20(S)-Rh1	C36H62O9	[M − H]−	683.64	637.59	375.42; 475.48; 549.31
16	Ginsenoside Rc	C53H90O22	[M − H]−	1077.86	783.59	621.66
17	Ginsenoside Rb2	C53H90O22	[M + Na]+	1101.69	789.60	245.07; 365.09
18	Ginsenoside 20(S)-Rf	C42H72O14	[M + Na]+	800.94	782.93	474.96; 307.83
19	Ginsenoside Rk2	C42H72O15	[M + Na]+	663.20	543.26	287.04; 367.26; 499.21
20	3$\beta$,12$\beta$-dihydroxydammar-20(22)E,24-diene-6-o-$\beta$-d-xylopyranosyl-(1$\to$2)-O-$\beta$-d-glucopyranoside (DHDXG)	C42H70O12	[M + Na]+	751.19	631.31	243.08; 367.12; 455.2; 587.21
21	Ginsenoside Rg9	C42H72O13	[M + Na]+	781.79	707.44	377.14; 671.18
	Oleanolic Acid Pentaterpene Glycosides
22	Ro	C48H76O19	[M − H]−	955.57	793.41	455.29; 613.38; 731.42
23	Methyl ester Ro	C49H78O19	[M + Na]+	969.48	364.96	304.95
24	Chikusetsusaponin IVA	C42H66O14	[M − H]−	793.36	334.97	274.94
25	Methyl ester chikusetsusaponin IVA	C42H66O14	[M + Na]+	807.38	627.34	203.05; 285.14; 361.77; 488.93
26	Silphioside G	C42H66O14	[M − H]−	793.7	613.49	483.3
27	Zingibroside R1	C42H66O14	[M − H]−	793.56	481.43	275.07