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. 2020 Mar 28;25(7):1559. doi: 10.3390/molecules25071559

Table 4.

Apparent thermodynamic parameters [apparent standard enthalpy (ΔsolH0), apparent standard Gibbs energy (ΔsolG0) and apparent standard entropy (ΔsolS0)] and R2 values for ECT dissolution in various “PEG-400 + water” mixtures (m) b.

m ΔsolH0/kJ mol−1 ΔsolG0/kJ mol−1 ΔsolS0/J mol−1 K−1 R 2
0.0 14.35 11.91 7.94 0.9995
0.1 13.80 11.31 8.05 0.9956
0.2 13.72 10.67 9.90 0.9980
0.3 13.43 9.98 11.21 0.9975
0.4 13.35 9.25 13.30 0.9988
0.5 13.12 8.59 14.68 0.9992
0.6 12.79 7.94 15.75 0.9980
0.7 12.44 7.28 16.73 0.9984
0.8 12.27 6.65 18.24 0.9989
0.9 11.38 5.99 17.51 0.9976
1.0 11.75 5.32 20.86 0.9967

b Mean relative uncertainties are usolH0) = 0.07, usolG0) = 0.25 and usolS0) = 0.30.