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. 2020 May 8;26(33):7405–7415. doi: 10.1002/chem.201905561

Table 2.

Cyclohexene cyclic carbonate synthesis from cyclohexene oxide catalysed by A and [Bu4N]Br.[a]

graphic file with name CHEM-26-7405-g013.jpg

Entry

Catalyst

[mol %]

T

[°C]

p

[bar][b]

t

[h]

Conv.

[%][c]

Chemoselectivity

11 [%][c]

1

A (2)+[Bu4N]Br (3)

120

75

4

97

84

2

A (2)

120

75

4

78

69

3

[Bu4N]Br (3)

120

75

4

60

88

4

none

120

75

4

0

[a] Reaction conditions: 10 (6.3 mmol), biphenyl (10 mol %) as an internal standard. [b] Pressure of CO2 at 40 °C. [c] Derived from quantitative 1H NMR spectroscopy.