Table 2.
Compound Name | RRIexp | RRIlit | H2O | Fe2+ | Ag+ | Fe3+ | CaCl2 sat. 1 | Cu2+ | Na2SO4 anh. 2 |
---|---|---|---|---|---|---|---|---|---|
sinigrin potassium salt | |||||||||
(methyldisulfanyl)methane | 1068 | 1064 [15] | 317715 #,b | 69214 #,c | - | 5106 $,c | - | 2482 $,c | 419816 $,a |
hexanal | 1075 | 1082 [18] | 47284 $,b | 169473 #,b | - | 3789656 #,a | 42992 *,b | 233815 @,b | 61231 #,b |
pent-1-en-3-ol | 1141 | 1158 [18] | 5905 $,c | 119966 *,c | - | - | 70899 $,b | - | 187903 #,a |
(E)-hex-2-enal | 1218 | 1216 [18] | - | - | - | - | 13660 @,b | - | 36592 #,a |
2-pentylfuran | 1222 | 1232 [18] | - | 26154 *,b | - | 138788 #,a | - | 2988 #,c | 2493 $,c |
heptan-2-one | 1325 | 1182 [18] | - | - | - | 242172 *,a | - | - | - |
(Z)-hex-3-en-1-ol | 1364 | 1380 [18] | - | 10077 @,b | - | - | 102469 *,c | - | 58909 #,a |
(methyltrisulfanyl)methane | 1391 | 1376 [18] | 2974175 #,a | - | - | - | - | - | 83767 $,b |
benzaldehyde | 1530 | 1518 [18] | 46994 $,a | 1311 #,c | - | 25629 *,b | 16560 #,b | 2234#,c | - |
(E)-non-2-enal | 1539 | 1535 [18] | 20479 *,b | - | - | 147120 #,a | - | - | - |
glucotropaeolin potassium salt | |||||||||
(methyldisulfanyl)methane | 1068 | 1064 [15] | 615854 *,a | 93952 #,c | - | - | 3438 *,c | 3848 $,c | 342112 *,b |
hexanal | 1075 | 1082 [18] | 71835 #,b | 140440 $,b | - | 3789656 #,a | 27612 #,b | 202812 *,b | 57077 #,b |
pent-1-en-3-ol | 1141 | 1158 [18] | 9007 *,b | 100647 *,b | - | - | 190000 $,a | 2830 #,b, | 159107 $,a |
(E)-hex-2-enal | 1218 | 1216 [18] | - | - | - | - | 69644 #,a | - | 39481 $,a |
2-pentylfuran | 1222 | 1232 [18] | - | 10856 *,b | - | 138788 #,a | - | - | - |
heptan-2-one | 1325 | 1182 [18] | - | - | - | 242172 *,a | - | - | - |
(Z)-hex-3-en-1-ol | 1364 | 1380 [18] | - | 3675 $,b | - | - | 142612 #,a | - | 45657 $,b |
(methyltrisulfanyl)methane | 1391 | 1376 [18] | 3243687 #,a | - | - | - | - | - | 88756 $,b |
benzaldehyde | 1530 | 1518 [18] | 43684 #,a | 3781 *,c | - | 25629 *,b | 23531 #,b | 18571 *,bc | - |
(E)-non-2-enal | 1539 | 1535 [18] | 29224 *,b | - | - | 147120 #,a | - | - | - |
1: saturated solution of calcium chloride; 2: anhydrous sodium sulfate; RRIexp: relative retention index calculated by n-alkane series using the experimental value (Supelcowax-10 column); RRIlit: relative retention index calculated by n-alkane series using the literature value; relative standard deviation: *: RSD ≤ 10%, #: 10% < RSD ≤ 25%, $: 25% < RSD ≤ 50%, @: RSD > 50%; values express the mean peak area; a, b, bc, c: the result of statistical analysis (one-way ANOVA Duncan test as post-hoc), values followed by the same letter in a Duncan grouping are not significantly different (α = 0.05); (n = 3).