Table 1.
NO. | Compound | Molecular Formula | RT a | RI b | MF c | RMF d | Content (%) | Identification e |
---|---|---|---|---|---|---|---|---|
1 | α-Pinene | C10H16 | 3.70 | 930 | 953 | 954 | 26.00 | 1,2,3 |
2 | Camphene | C10H16 | 3.87 | 943 | 906 | 911 | 0.21 | 1,2 |
3 | 2,4-Thujadiene | C10H14 | 3.93 | 957 | 844 | 858 | 0.76 | 1,2 |
4 | β-Terpinene | C10H16 | 4.26 | 964 | 876 | 918 | 0.15 | 1,2 |
5 | l-β-Pinene | C10H16 | 4.31 | 969 | 926 | 935 | 0.38 | 1,2 |
6 | Epoxycyclooctane | C8H14O | 4.39 | 971 | 896 | 912 | 0.22 | 1,2 |
7 | 2,3-Dehydro-1,8-cineole | C10H16O | 4.50 | 1041 | 791 | 835 | 0.33 | 1,2 |
8 | 1,3,8-p-Menthatriene | C10H14 | 4.56 | 1042 | 872 | 913 | 0.25 | 1,2 |
9 | E,E-2,6-Dimethyl-1,3,5,7-octatetraene | C10H14 | 4.79 | 1049 | 902 | 915 | 0.27 | 1,2 |
10 | 4-Isopropenyltoluene | C10H12 | 4.87 | 1073 | 849 | 895 | 0.07 | 1,2 |
11 | o-Cymene | C10H14 | 5.10 | 1079 | 929 | 939 | 0.62 | 1,2 |
12 | Isosylvestrene | C10H16 | 5.27 | 1083 | 879 | 923 | 0.11 | 1,2 |
13 | γ-Terpinen | C10H16 | 5.83 | 1101 | 908 | 918 | 0.18 | 1,2 |
14 | trans-p-Mentha-2,8-dienol | C10H16O | 5.99 | 1111 | 746 | 747 | 1.30 | 1,2 |
15 | Berbenol | C10H16O | 6.16 | 1117 | 824 | 830 | 0.13 | 1,2 |
16 | Campholenal | C10H16O | 6.24 | 1119 | 854 | 875 | 0.10 | 1,2 |
17 | 4-Isopropenyltoluene | C10H12 | 6.31 | 1123 | 919 | 940 | 0.33 | 1,2 |
18 | Terpinolene | C10H16 | 6.40 | 1124 | 901 | 925 | 1.69 | 1,2,3 |
19 | Benzyl ethyl carbinol | C10H14O | 7.05 | 1131 | 761 | 799 | 0.35 | 1,2 |
20 | l-Pinocarveol | C10H16O | 7.24 | 1143 | 920 | 928 | 0.17 | 1,2 |
21 | cis-Verbenol | C10H16O | 7.32 | 1146 | 862 | 899 | 0.82 | 1,2 |
22 | d-Verbenol | C10H16O | 7.41 | 1149 | 917 | 919 | 4.11 | 1,2 |
23 | Pinocarvone | C10H14O | 7.54 | 1157 | 873 | 891 | 1.14 | 1,2 |
24 | l-Terpinen-4-ol | C10H18O | 8.00 | 1158 | 909 | 920 | 0.56 | 1,2 |
25 | p-Cymen-8-ol | C10H14O | 8.07 | 1160 | 906 | 920 | 0.61 | 1,2 |
26 | Myrtenal | C10H14O | 8.13 | 1169 | 927 | 933 | 0.07 | 1,2 |
27 | α-Terpineol | C10H18O | 8.19 | 1172 | 821 | 839 | 1.27 | 1,2,3 |
28 | Verbenone | C10H14O | 8.34 | 1198 | 908 | 917 | 7.40 | 1,2,3 |
29 | cis-Carveol | C10H16O | 8.76 | 1207 | 942 | 944 | 2.20 | 1,2 |
30 | l-Carveol | C10H16O | 8.95 | 1213 | 704 | 719 | 0.25 | 1,2 |
31 | Carvol | C10H14O | 9.02 | 1217 | 857 | 894 | 0.25 | 1,2 |
32 | Hotrienol | C10H16O | 9.10 | 1218 | 657 | 747 | 0.17 | 1,2 |
33 | 3,5-Diethylphenol | C10H14O | 9.17 | 1219 | 762 | 799 | 0.16 | 1,2 |
34 | trans-2-Caren-4-ol | C10H16O | 9.38 | 1224 | 734 | 750 | 0.19 | 1,2 |
35 | Bornyl acetate | C12H20O2 | 9.95 | 1259 | 887 | 892 | 0.72 | 1,2 |
36 | (−)-trans-Pinocarvyl acetate | C12H18O2 | 10.16 | 1264 | 742 | 754 | 0.15 | 1,2 |
37 | 4-Vinylguaiacol | C9H10O2 | 10.25 | 1271 | 818 | 845 | 0.25 | 1,2 |
38 | 1,4-p-Menthadien-7-ol | C10H16O | 10.65 | 1291 | 739 | 774 | 0.31 | 1,2 |
39 | Aromadendrene, dehydro- | C15H22 | 12.42 | 1407 | 747 | 778 | 0.25 | 1,2 |
40 | Calarene | C15H24 | 12.55 | 1412 | 903 | 930 | 5.27 | 1,2 |
41 | 4,5,9,10-dehydro-Isolongifolene | C15H20 | 12.91 | 1424 | 752 | 764 | 0.25 | 1,2 |
42 | 2-Tridecanone | C13H26O | 13.39 | 1439 | 885 | 896 | 0.33 | 1,2 |
43 | Bisabolene | C15H24 | 13.69 | 1450 | 896 | 912 | 0.52 | 1,2 |
44 | Cadina-3,9-diene | C15H24 | 13.86 | 1456 | 835 | 851 | 0.30 | 1,2 |
45 | Juniper camphor | C15H26O | 14.20 | 1467 | 790 | 801 | 0.30 | 1,2 |
46 | (−)-Spathulenol | C15H24O | 14.52 | 1478 | 842 | 849 | 0.51 | 1,2 |
47 | Caryophyllene oxide | C15H24O | 14.59 | 1480 | 661 | 689 | 0.18 | 1,2 |
48 | Isoaromadendrene epoxide | C15H24O | 14.90 | 1490 | 775 | 791 | 0.70 | 1,2 |
49 | cis-Lanceol | C15H24O | 15.00 | 1494 | 749 | 805 | 0.43 | 1,2 |
50 | 3,3,5,6,7-Pentamethyl-1-indanone | C14H18O | 15.35 | 1505 | 790 | 791 | 2.96 | 1,2 |
51 | Trans-Longipinocarveol | C15H24O | 16.09 | 1530 | 723 | 758 | 0.52 | 1,2 |
52 | Dehydro-cyclolongifolene oxide | C15H22O | 16.87 | 1556 | 740 | 752 | 4.81 | 1,2 |
53 | Tetradecanoic acid | C14H28O2 | 17.20 | 1567 | 701 | 778 | 0.15 | 1,2 |
54 | 9-Hexadecenoic acid | C16H30O2 | 19.40 | 1701 | 661 | 669 | 0.22 | 1,2 |
55 | Androst-2,16-diene | C19H28 | 19.62 | 1709 | 738 | 743 | 0.19 | 1,2 |
56 | Phellopterin | C17H16O5 | 19.77 | 1773 | 766 | 786 | 2.17 | 1,2 |
57 | Hexadecanoic acid | C16H32O2 | 19.84 | 1775 | 878 | 895 | 2.26 | 1,2 |
58 | Manoyl oxide | C20H34O | 20.12 | 1945 | 868 | 889 | 0.23 | 1,2 |
59 | Androstane-3,11-diol | C19H32O2 | 20.81 | 1985 | 711 | 736 | 0.32 | 1,2 |
60 | Methyl isopimarate | C21H32O2 | 21.35 | 1998 | 742 | 802 | 0.37 | 1,2 |
61 | Linoleic acid | C18H32O2 | 21.57 | 2008 | 793 | 847 | 1.00 | 1,2 |
62 | trans-Oleic acid | C18H34O2 | 21.65 | 2012 | 629 | 691 | 0.27 | 1,2 |
63 | Kaur-16-ene | C20H32 | 22.23 | 2037 | 852 | 872 | 3.51 | 1,2 |
64 | 16-Kauran-16-ol | C20H34O | 22.30 | 2040 | 870 | 888 | 1.65 | 1,2 |
75 | Kauran-16-ol | C20H34O | 22.43 | 2045 | 847 | 869 | 0.99 | 1,2 |
66 | Cryptopinon | C20H30O | 22.59 | 2052 | 769 | 798 | 0.29 | 1,2 |
67 | Pimaric acid | C20H30O2 | 23.71 | 2101 | 739 | 741 | 3.09 | 1,2 |
68 | Abietic acid | C20H30O2 | 24.26 | 2125 | 785 | 786 | 3.78 | 1,2 |
Pentadecane f | ||||||||
Total compounds | 92.07 | |||||||
Oxygenated monoterpenes | 54.65 | |||||||
Sesquiterpenoids | 22.73 | |||||||
Others | 14.69 |
a Peak time. b Retention indices relative to C9–C30 n-alkanes on the HP-INNOWax column. c Forward match. d Reverse match. e Methods of identification: 1, retention index; 2, mass spectrum; 3, co-injection with standard compound. f Internal standard.