Skip to main content
Nanomaterials logoLink to Nanomaterials
editorial
. 2020 Nov 22;10(11):2308. doi: 10.3390/nano10112308

Application of Novel Plasmonic Nanomaterials on SERS

Grégory Barbillon 1
PMCID: PMC7700451  PMID: 33266397

During these past two decades, the fabrication of ultrasensitive surface-enhanced Raman scattering (SERS) substrates has explosed by using novel plasmonic materials such bimetallic materials (e.g., Au/Ag) [1,2,3,4], hybrid materials (e.g., metal/semiconductor) [5,6,7,8], and also new designs of plasmonic nanostructures (e.g., nanoparticle self-assembly [9,10,11]). These novel plasmonic nanomaterials can allow a better confinement of the electric field and thus induce an enhancement of the SERS signal (electromagnetic contribution [12,13]) by adjusting, for instance, the size, shape, periodicity, nanoparticle self-assembly, and nanomaterials’ nature. These nanomaterials can also enhance the charge transfer (electrons; chemical contribution) to increase the SERS signal [14,15]. Furthermore, other materials are appeared for SERS applications such as metal oxides [16,17]. Other directions for the SERS field also emerged such as the SERS effect induced by high pressure [18,19], and the photo-induced enhanced Raman spectroscopy [20,21,22]. Thus, this special issue is dedicated to introducing recent advances and insights in these novel plasmonic nanomaterials applied to the fabrication of highly sensitive SERS substrates for chemical and biological sensing.

This special issue is formed of 5 research articles, and 1 review article. The first part of this latter is devoted to the novel methods of fabrication of plasmonic nanoparticles or nanostructures for SERS [23,24,25]. Dizajghrobani-Aghdam et al. demonstrated an alternative method of fabrication of metallic nanoparticles by employing pulsed laser ablation, and these hybrid plasmonic nanostructures have presented significant enhancements of the Raman signal [23]. Furthermore, Yang et al. presented the direct fabrication of SERS substrates by using an in situ photochemical method of reduction. High enhancements of the Raman signal were obtained with these SERS substrates [24]. To finish this first part, Chang et al. proposed a simpler method of electron beam lithography in order to realize SERS substrates by removing the photoresist lift-off step [25]. In the second part, the presented domain is devoted to the impact of long-range interactions and the surrounding medium on the SERS effect investigated by Ragheb et al. [26]. In the last part, the addressed domains are dedicated to novel plasmonic and non-plasmonic nanomaterials for SERS sensing [27,28]. Barbillon et al. demonstrated the enhancement of the Raman signal with hybrid nanostructures on a metallic film [27]. To finish this part and this special issue on novel plasmonic nanomaterials applied to the SERS field, Barbillon presented a short review on plasmonic and non-plasmonic nanomaterials for SERS sensing [28].

For performing the special issue entitled “Application of Novel Plasmonic Nanomaterials on SERS”, a couple of contributions has been obtained from excellent-quality authors originate from worldwide. I would like to acknowledge all these authors as well as the whole editorial office of the journal “Nanomaterials” for their great support and help in the management process of the article submissions and other associated tasks. To finish, I hope that you will find interesting this special issue devoted to novel plasmonic nanomaterials for the SERS field, which is targeted to the students or researchers who are or wish to imply in this field.

Funding

This research received no external funding.

Conflicts of Interest

The author declares no conflict of interest.

Footnotes

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

References

  • 1.Song J.B., Duan B., Wang C.X., Zhou J.J., Pu L., Fang Z., Wang P., Lim T.T., Duan D.W. SERS-Encoded Nanogapped Plasmonic Nanoparticles: Growth of Metallic Nanoshell by Templating Redox-Active Polymer Brushes. J. Am. Chem. Soc. 2014;136:6838–6841. doi: 10.1021/ja502024d. [DOI] [PubMed] [Google Scholar]
  • 2.Yang Y., Liu J., Fu Z.W., Qin D. Galvanic replacement-free deposition of Au on Ag for core-shell nanocubes with enhanced chemical stability and SERS activity. J. Am. Chem. Soc. 2014;136:8153–8156. doi: 10.1021/ja502472x. [DOI] [PubMed] [Google Scholar]
  • 3.Feng J.J., Wu X.L., Ma W., Kuang H., Xu L.G., Xu C.L. A SERS active bimetallic core-satellite nanostructure for the ultrasensitive detection of Mucin-1. Chem. Commun. 2015;51:14761–14763. doi: 10.1039/C5CC05255F. [DOI] [PubMed] [Google Scholar]
  • 4.Zhang Y., Yang P., Habeeb Muhammed M.A., Alsaiari S.K., Moosa B., Almalik A., Kumar A., Ringe E., Kashab N.M. Tunable and Linker Free Nanogaps in Core-Shell Plasmonic Nanorods for Selective and Quantitative Detection of Circulating Tumor Cells by SERS. ACS Appl. Mater. Interfaces. 2017;9:37597–37605. doi: 10.1021/acsami.7b10959. [DOI] [PubMed] [Google Scholar]
  • 5.Bryche J.-F., Bélier B., Bartenlian B., Barbillon G. Low-cost SERS substrates composed of hybrid nanoskittles for a highly sensitive sensing of chemical molecules. Sens. Actuators B. 2017;239:795–799. doi: 10.1016/j.snb.2016.08.049. [DOI] [Google Scholar]
  • 6.Wu J., Du Y., Wang C., Bai S., Zhang T., Chen T., Hu A. Reusable and long-life 3D Ag nanoparticles coated Si nanowire array as sensitive SERS substrate. Appl. Surf. Sci. 2019;494:583–590. doi: 10.1016/j.apsusc.2019.07.080. [DOI] [Google Scholar]
  • 7.Yang M.S., Yu J., Lei F.C., Zhou H., Wei Y.S., Man B.Y., Zhang C., Li C.H., Ren J.F., Yuan X.B. Synthesis of low-cost 3D-porous ZnO/Ag SERS-active substrate with ultrasensitive and repeatable detectability. Sens. Actuators B. 2018;256:268–275. doi: 10.1016/j.snb.2017.09.197. [DOI] [Google Scholar]
  • 8.Graniel O., Iatsunskyi I., Coy E., Humbert C., Barbillon G., Michel T., Maurin D., Balme S., Miele P., Bechelany M. Au-covered hollow urchin-like ZnO nanostructures for surface-enhanced Raman scattering sensing. J. Mater. Chem. C. 2019;7:15066–15073. doi: 10.1039/C9TC05929F. [DOI] [Google Scholar]
  • 9.Matricardi C., Hanske C., Garcia-Pomar J.L., Langer J., Mihi A., Liz-Marzan L.M. Gold Nanoparticle Plasmonic Superlattices as Surface-Enhanced Raman Spectroscopy Substrates. ACS Nano. 2018;12:8531–8539. doi: 10.1021/acsnano.8b04073. [DOI] [PubMed] [Google Scholar]
  • 10.Volk K., Fitzgerald J.P.S., Ruckdeschel P., Retsch M., König T.A.F., Karg M. Reversible Tuning of Visible Wavelength Surface Lattice Resonances in Self-Assembled Hybrid Monolayers. Adv. Opt. Mater. 2017;5:1600971. doi: 10.1002/adom.201600971. [DOI] [Google Scholar]
  • 11.Greybush N.J., Liberal I., Malassis L., Kikkawa J.M., Engheta N., Murray C.B., Kagan C.R. Plasmon Resonances in Self-Assembled Two-Dimensional Au Nanocrystal Metamolecules. ACS Nano. 2017;11:2917–2927. doi: 10.1021/acsnano.6b08189. [DOI] [PubMed] [Google Scholar]
  • 12.Itoh T., Yamamoto Y.S., Ozaki Y. Plasmon-enhanced spectroscopy of absorption and spontaneous emissions explained using cavity quantum optics. Chem. Soc. Rev. 2017;46:3904–3921. doi: 10.1039/C7CS00155J. [DOI] [PubMed] [Google Scholar]
  • 13.Ding S.-Y., You E.-M., Tian Z.-Q., Moskovits M. Electromagnetic theories of surface-enhanced Raman spectroscopy. Chem. Soc. Rev. 2017;46:4042–4076. doi: 10.1039/C7CS00238F. [DOI] [PubMed] [Google Scholar]
  • 14.Jensen L., Aikens C.M., Schatz G.C. Electronic structure methods for studying surface-enhanced Raman scattering. Chem. Soc. Rev. 2008;37:1061–1073. doi: 10.1039/b706023h. [DOI] [PubMed] [Google Scholar]
  • 15.Alessandri I., Lombardi J.R. Enhanced Raman Scattering with Dielectrics. Chem. Rev. 2016;116:14921–14981. doi: 10.1021/acs.chemrev.6b00365. [DOI] [PubMed] [Google Scholar]
  • 16.Cong S., Yuan Y., Chen Z., Hou J., Yang M., Su Y., Zhang Y., Li L., Li Q., Geng F., et al. Noble metal-comparable SERS enhancement from semiconducting metal oxides by making oxygen vacancies. Nat. Commun. 2015;6:7800. doi: 10.1038/ncomms8800. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 17.Liu W., Bai H., Li X., Li W., Zhai J., Li J., Xi G. Improved Surface-Enhanced Raman Spectroscopy Sensitivity on Metallic Tungsten Oxide by the Synergistic Effect of Surface Plasmon Resonance Coupling and Charge Transfer. J. Phys. Chem. Lett. 2018;9:4096–4100. doi: 10.1021/acs.jpclett.8b01624. [DOI] [PubMed] [Google Scholar]
  • 18.Sun H.H., Yao M.G., Song Y.P., Zhu L.Y., Dong J.J., Liu R., Li P., Zhao B., Liu B.B. Pressure-induced SERS enhancement in a MoS2/Au/R6G system by a two-step charge transfer process. Nanoscale. 2019;11:21493–21501. doi: 10.1039/C9NR07098B. [DOI] [PubMed] [Google Scholar]
  • 19.Barbillon G. Nanoplasmonics in High Pressure Environment. Photonics. 2020;7:53. doi: 10.3390/photonics7030053. [DOI] [Google Scholar]
  • 20.Ben-Jaber S., Peveler W.J., Quesada-Cabrera R., Cortés E., Sotelo-Vazquez C., Abdul-Karim N., Maier S.A., Parkin I.P. Photo-induced enhanced Raman spectroscopy for universal ultra-trace detection of explosives, pollutants and biomolecules. Nat. Commun. 2016;7:12189. doi: 10.1038/ncomms12189. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 21.Glass D., Cortés E., Ben-Jaber S., Brick T., Peveler W.J., Blackman C.S., Howle C.R., Quesada-Cabrera R., Parkin I.P., Maier S.A. Dynamics of Photo-Induced Surface Oxygen Vacancies in Metal-Oxide Semiconductors Studied Under Ambient Conditions. Adv. Sci. 2019;6:1901841. doi: 10.1002/advs.201901841. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 22.Barbillon G., Noblet T., Humbert C. Highly crystalline ZnO film decorated with gold nanospheres for PIERS chemical sensing. Phys. Chem. Chem. Phys. 2020;22:21000–21004. doi: 10.1039/D0CP03902K. [DOI] [PubMed] [Google Scholar]
  • 23.Dizajghorbani-Aghdam H., Miller T.S., Malekfar R., McMillan P.F. SERS-Active Cu Nanoparticles on Carbon Nitride Support Fabricated Using Pulsed Laser Ablation. Nanomaterials. 2019;9:1223. doi: 10.3390/nano9091223. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 24.Yang L., Yang J., Li Y., Li P., Chen X., Li Z. Controlling the Morphologies of Silver Aggregates by Laser-Induced Synthesis for Optimal SERS Detection. Nanomaterials. 2019;9:1529. doi: 10.3390/nano9111529. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 25.Chang Y.C., Huang B.-H., Lin T.-H. Surface-Enhanced Raman Scattering and Fluorescence on Gold Nanogratings. Nanomaterials. 2020;10:776. doi: 10.3390/nano10040776. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 26.Ragheb I., Braïk M., Lau-Trong S., Belkir A., Rumyantseva A., Kostcheev S., Adam P.-M., Chevillot-Biraud A., Lévi G., Aubard J., et al. Surface Enhanced Raman Scattering on Regular Arrays of Gold Nanostructures: Impact of Long-Range Interactions and the Surrounding Medium. Nanomaterials. 2020;10:2201. doi: 10.3390/nano10112201. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 27.Barbillon G., Ivanov A., Sarychev A.K. Hybrid Au/Si Disk-Shaped Nanoresonators on Gold Film for Amplified SERS Chemical Sensing. Nanomaterials. 2019;9:1588. doi: 10.3390/nano9111588. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 28.Barbillon G. Latest Novelties on Plasmonic and Non-Plasmonic Nanomaterials for SERS sensing. Nanomaterials. 2020;10:1200. doi: 10.3390/nano10061200. [DOI] [PMC free article] [PubMed] [Google Scholar]

Articles from Nanomaterials are provided here courtesy of Multidisciplinary Digital Publishing Institute (MDPI)

RESOURCES