Table 3.
NMR data of guaia-4(15)-en-11-ol and guaia-4-en-11-ol (isoguaiol B). NMR data were recorded on a 700 MHz spectrometer in C6D6 at 298 K. Coupling constants J are given in Hz and multiplicities are indicated by s = singlet, d = doublet, m = multiplet, br = broad.
| C | Guaia-4(15)-en-11-ol (1) | Guaia-4-en-11-ol (2) | ||
|---|---|---|---|---|
| 13C | 1H | 13C | 1H | |
| 1 | 52.34 (CH) | 1.18 (m) | 55.60 (CH) | 2.28 (m) |
| 2 | 32.42 (CH2) | 1.76 (m, Hα) 1.00 (m, Hβ) |
30.42 (CH2) | 1.92 (m) 1.51 (m) |
| 3 | 32.96 (CH2) | 2.32 (ddm, J = 15.9, 7.8, Hβ) 2.19 (m, Hα) |
36.60 (CH2) | 2.23 (m) 2.13 (m) |
| 4 | 159.08 (Cq) | – | 131.74 (Cq) | – |
| 5 | 46.33 (CH) | 2.15 (m) | 138.62 (Cq) | – |
| 6 | 34.56 (CH2) | 1.88 (ddd, J = 13.9, 9.2, 6.1, Hβ) 1.54 (ddd, J = 13.9, 11.3, 8.0, Hα) |
30.37 (CH2) | 2.67 (d, J = 15.2) 2.00 (m) |
| 7 | 49.56 (CH) | 1.41 (m) | 49.30 (CH) | 1.36 (m) |
| 8 | 26.71 (CH2) | 1.74 (m, Hα) 1.10 (m, Hβ) |
31.51 (CH2) | 1.90 (m) 1.00 (m) |
| 9 | 40.29 (CH2) | 1.77 (m, Hβ) 0.96 (m, Hα) |
40.26 (CH2) | 1.78 (m) 1.10 (m) |
| 10 | 42.32 (CH) | 1.06 (m) | 39.37 (CH) | 1.33 (m) |
| 11 | 73.26 (Cq) | – | 72.82 (Cq) | – |
| 12 | 27.75 (CH3) | 1.03 (s) | 26.89 (CH3) | 1.03 (s) |
| 13 | 25.78 (CH3) | 1.01 (s) | 26.66 (CH3) | 1.02 (s) |
| 14 | 21.58 (CH3) | 0.87 (d, J = 6.5) | 22.01 (CH3) | 0.93 (d, J = 6.6) |
| 15 | 104.24 (CH2) | 5.00 (m, HE) 4.91 (br, HZ) |
14.60 (CH3) | 1.63 (br s) |