Table 2.
Entry | Ionic Liquid | Styrene Carbonate Yield/% b |
---|---|---|
1 | [emim][N(CN)2] | 0.3 |
2 | [bmim][N(CN)2] | 4.9 |
3 | [emim][Cl] | 0.5 |
4 | [bmim][Cl] | 1.6 |
5 | [emim][NTf2] | 0.1 |
6 | [bmim][NTf2] | 0.3 |
a Reaction conditions: styrene epoxide (5 mmol), [Bu4N]Br (0.3% mol vs. epoxide), IL (2.5 mL), CO2 (8 bar), 24 h, 80 °C. b Yield determined by 1H NMR (internal standard method).