Table 1.
Compound |
Void volume[a] [%] |
Crystal density[a [g cm−3] |
SA geo [b] [m2 g−1] |
SA BET [m2 g−1] |
V p [c] [cm3 g−1] |
---|---|---|---|---|---|
BN‐MOF‐1 |
68 |
0.52 |
3051 |
1096 |
0.48 |
BN‐MOF‐2 |
68 |
0.55 |
3509 |
12 (270[d]) |
0.008 (0.044[d]) |
C‐MOF‐1 |
63 |
0.65 |
2746 |
509 |
0.29 |
[a] Calculated with Platon with 1.2 Å radius probe. [b] Accessible geometric surface area calculated with Poreblazer_v3.0.2 with a nitrogen molecule size probe (diameter 3.72 Å), [c] Vp is the measured pore volume, [d] BET surface area and pore volume at P/P 0=0.028 calculated from CO2 isotherm.