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. 2021 Apr 3;26(7):2052. doi: 10.3390/molecules26072052

Table 5.

Structures and thermal properties of isohexide-based ILs.

Physical State Tg(°C) Tonset(°C) Td5%(°C) Td10%(°C) Tpeak(°C) Ref.
78a Glass −21 1,2 --- --- 231 3 --- [68]
78b Viscous material −68 1,2 --- --- 232 3 --- [68]
78c Viscous material −51 1,2 --- --- 229 3 --- [68]
78d Viscous material −60 1,2 --- --- 245 3 --- [68]
80a Glass −8 1,2 --- --- 238 3 --- [68]
80b Viscous material −27 1,2 --- --- 250 3 --- [68]
80c Viscous material −37 1,2 --- --- 251 3 --- [68]
80d Viscous material −58 1,2 --- --- 269 3 --- [68]
83a Yellow solid --- 219.6 4,5
336.5 4,6 		218.3 4 226.9 4 238.6 4,5
363.5 4,6 		[70]
83b Orange solid --- 222.3 4,5 223.0 4 228.7 4 277.1 4,5
349.5 4,6 		[70]
84a Yellow solid --- 181.8 4,5
227.4 4,6 		192.2 4 228.4 4 192.2 4,5
246.1 4,6
353.1 4,7 		[70]
84b Brick red solid 79.9 8 233.7 4 216.1 4 228.9 4 288.8 4 [70]
85a Yellow orange glassy solid 49.3 8 370.7 4 358.3 4 370.8 4 391.7 4 [70]
85b Pale yellow glassy solid 31.4 8 354.3 4 347.8 4 357.03 4 366.4 4,5
382.4 4,6 		[70]
86a Brick red glassy solid 48.1 8 370.1 4 362.5 4 372.2 4 394.8 4 [70]
86b Pale brown glassy solid 28.4 8 370.5 4 356.7 4 376.6 4 387.5 4 [70]

1 DSC conditions: 20 °C/min, He; 2 Measured during the second heating cycle; 3 TGA conditions: 20 °C/min to 600 °C, N2; 4 TGA conditions: 10 °C/min from 40 °C to 900 °C, N2, Pt pan (100 μL). Every sample was dried in the furnace at 60 °C for 10 min under an N2 atmosphere prior to measurement; 5 Referred to the first degradation event; 6 Referred to the second degradation event; 7 Referred to the third degradation event; 8 DSC conditions: The samples were heated to the maximal temperature (10 °C/min) to remove thermal history, then cooled to −90 °C (5 °C/min) and heated from −90 °C to the maximal temperature (10 °C/min) (the two heating ramps lead to the same results), dry N2 (30 cm3/min), 1.44–7.21 mg, aluminum pan with a pinhole on the cap, the maximal temperature was 180 °C for 83a,b, 84a,b, 300 °C for 83c and 84c, 250 °C for 83d and 210 °C for 84d.