Compounds 4 q and 4 r in this Communication arose from C−Br couplings of starting material that was prepared following the patent by Fontana et al.,1 which claimed to have produced the relative positioning of 1‐OR (R = H or Tf), 3‐adamantyl, 4‐bromo, 5‐methoxy around the arene. Re‐examination revealed that this assignment was incorrect and Fontana et al. instead made the 1‐OR‐2‐bromo‐4‐adamantyl‐5‐methoxy arene (R = H). Consequently, the correct structures of the coupling products 4 q and 4 r are as follows:
A revised supporting information is provided along with this Corrigendum. This change does not affect the conclusions of the study. The synthesis of the originally claimed isomer (i.e. 3‐adamantyl‐4‐bromo‐5‐methoxyphenyl triflate) and its ortho‐adamantyl C−C coupling diversification is described in Ref. [2].
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References
- 1.J. A. Fontana, M. Dawson, Z. Xia (Wayne State University, Sandford-Burnham Medical Research Institute), WO2011079305A1, 2011.
- 2.I. Kalvet, K. Deckers, I. Funes-Ardoiz, G. Magnin, T. Sperger, M. Kremer, F. Schoenebeck, Angew. Chem. Int. Ed. 2020, DOI: 10.1002/anie.202001326; Angew. Chem. 2020, DOI: . [DOI] [PMC free article] [PubMed]
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As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
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