Compound 3 in this Communication was prepared following the patent by Fontana et al.,1 which claimed to have produced the relative positioning of 1‐OR (R = H or Tf), 3‐adamantyl, 4‐bromo, 5‐methoxy around the arene. Re‐examination revealed that this assignment was incorrect and Fontana et al. instead made the 1‐OR‐2‐bromo‐4‐adamantyl‐5‐methoxy arene (R = H). Consequently, the correct structure of 3 and its C−Br coupling product are shown in the revised Scheme 1 b.
Scheme 1.
[b) Palladium(I) dimer performance in Negishi coupling of a challenging substrate.]
A revised supporting information is provided along with this Corrigendum. This change does not affect the conclusions of the study. The synthesis of the originally claimed isomer (i.e. 3‐adamantyl‐4‐bromo‐5‐methoxyphenyl triflate) and its ortho‐adamantyl C−C coupling diversification is described in Ref. [2].
Supporting information
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References
- 1.J. A. Fontana, M. Dawson, Z. Xia (Wayne State University, Sandford-Burnham Medical Research Institute), WO2011079305A1, 2011.
- 2.I. Kalvet, K. Deckers, I. Funes-Ardoiz, G. Magnin, T. Sperger, M. Kremer, F. Schoenebeck, Angew. Chem. Int. Ed. 2020, DOI: 10.1002/anie.202001326; Angew. Chem. 2020, DOI: . [DOI] [PMC free article] [PubMed]
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Supplementary Materials
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
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