Abstract
Correction for ‘Polariton chemistry: controlling molecular dynamics with optical cavities’ by Raphael F. Ribeiro et al., Chem. Sci., 2018, 9, 6325–6339, DOI: 10.1039/C8SC01043A.
The authors regret that incorrect values are reported in Table 1 of the original article. The corrected Table 1 is shown below.
Timescales relevant for the description of organic (J-aggregate) microcavity relaxation dynamics at room temperaturea.
| Process | Initial state(s) | Final state(s) | Timescale | Ref. in original article | Ref. in this Correction |
|---|---|---|---|---|---|
| Rabi oscillations | — | — | 15–80 fs (50–300 meV) | 93 | 1 |
| Cavity leakage | Cavity photon | — | 35–100 fs | 94–96 | 2–4 |
| Vibrational relaxation | UP | Dark states | ∼50 fs | 11 | 5 |
| Dark states | LP | ∼10 ps | 99 | 6 | |
| Photoluminescence | UP | — | ∼100 fs | 95 | 3 |
| LP | — | ∼100 fs | 95 | 3 | |
| Bare exciton | — | ∼1–100 ps | 94, 100 and 101 | 2, 7 and 8 |
a
In typical organic dyes, vibrational relaxation following electronic excitation occurs on the order of 10–1000 fs.9,10
The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
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