Tables 1 and 3 in the original Communication contain incorrectly transferred data for the calculations at the M06‐2x/def2‐TZVPP level of theory. The correct values are for Table 1: d(Te1–C1) 2.155 Å, d(Te1–C7) 2.160 Å, d(N1⋅⋅⋅Te1) 2.789 Å, α(N1⋅⋅⋅Te1–C1) 165.9°, α(C1–Te1–C7) 92.2° and for Table 3 d(Te1–C1) 2.112 Å, d(Te1–C7) 2.138 Å, α(C1–Te1–C7) 96.2°. The authors also noticed that parts of the Supporting Information to this Communication stem from an earlier version of the manuscript and contain an incorrect description of the gas electron‐diffraction experiment on page 32. In fact, a higher quality treatment of vibrational corrections (r e−r a) and amplitudes for interatomic distances than reported was applied. The treatment included anharmonic corrections calculated from molecular dynamics trajectories. In the refinements of the molecular structures, flexible restraints calculated at the PBE0‐D3BJ/def2‐TZVP level of theory were applied to the complete set of internal geometrical parameters. Full details are provided in the updated version of Supporting Information, which is available with this Corrigendum. The electron wavelengths on page 33 have also received slight corrections, and the gas‐diffraction intensity graphs in Figures S16–S18 and S20–S22 were replaced by more informative versions including intensity error bars. The numerical diffraction intensity data were added at the end of the Supporting information.
The authors sincerely apologize for the errors and state that the corrections do not affect the scientific conclusions of this Communication. They are grateful to Dr. Jan‐Michael Mewes, University of Bonn, who pointed out this issue.
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