Correction: Rhodium-catalysed selective C–C bond activation and borylation of cyclopropanes

Abstract

Correction for ‘Rhodium-catalysed selective C–C bond activation and borylation of cyclopropanes’ by Yandong Wang et al., Chem. Sci., 2021, DOI: 10.1039/d0sc06186g.

The authors regret that there were a few errors in Fig. 3 of the original article. The correct version of Fig. 3 is shown below.

Fig. 3. Free energy diagram of hydroboration of CPAs using PPh₃ as the ligand and DFT-computed four transition states for the σ-CAM pathways. Energies are in kcal mol⁻¹.

On pages 6–7 of the original manuscript, the sentences from “The enamide I is the kinetically favoured product” to the end of this paragraph should be corrected to “Finally, the catalytic species A is regenerated via dissociation of 12 or 13-E from the Rh center. The enamide 13-E is the kinetically favoured product, which supports the observation of 13 in Scheme 3A-3, where HBpin is not added.”

These changes do not alter the scientific conclusions of the manuscript.

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.